Synthesis and Characterization of Yttrium Iron Garnet (YIG) Nanoparticles Activated by Electromagnetic Wave in Enhanced Oil Recovery

2016 ◽  
Vol 38 ◽  
pp. 40-46 ◽  
Author(s):  
Hassan Soleimani ◽  
Noor Rasyada Ahmad Latiff ◽  
Noorhana Yahya ◽  
Maziyar Sabet ◽  
Leila Khodapanah ◽  
...  

Due to the geographical location and technological limitation, various novel enhanced oil recovery (EOR) methods has been proposed to recover the remaining oil from a depleted oil reservoir. Research on application of nanoparticles either on its own or coupled with other stimulating agents has been growing enormously and some of them have shown a promising future. In high temperature and high pressure reservoirs, thermal degradation will cause failure to the conventional chemicals. In this work, temperature-stable YIG magnetic nanoparticles with an electromagnetic wave has been proposed as a new candidate for reservoir stimulating agent. The purpose of nanoparticle injection is to increase the sweep efficiency in the reservoir by increasing the viscosity of displacing fluid. In this research, Yttrium iron garnet (YIG) nanoparticles have been injected into a waterflooded oil saturated porous medium to recover the remaining oil in the presence of an electromagnetic wave. At the sintering temperature 1200°C, a mixture of hematite and YIG was obtained, suggesting a higher temperature for single phase YIG. From VSM analysis, the average magnetic saturation, coercivity and remanence are 18.17 emu/g, 21.73 Oe and 2.38 emu/g, respectively. 1.0 wt% of YIG nanofluid was prepared and subsequently injected into the pre-saturated porous medium in the presence of square electromagnetic wave of 13.6 MHz. As much as 43.64% of the remaining oil in place (ROIP) was recovered following the injection of 2 pore volume of YIG nanofluid.

Author(s):  
Ahmed Ragab ◽  
Eman M. Mansour

The enhanced oil recovery phase of oil reservoirs production usually comes after the water/gas injection (secondary recovery) phase. The main objective of EOR application is to mobilize the remaining oil through enhancing the oil displacement and volumetric sweep efficiency. The oil displacement efficiency enhances by reducing the oil viscosity and/or by reducing the interfacial tension, while the volumetric sweep efficiency improves by developing a favorable mobility ratio between the displacing fluid and the remaining oil. It is important to identify remaining oil and the production mechanisms that are necessary to improve oil recovery prior to implementing an EOR phase. Chemical enhanced oil recovery is one of the major EOR methods that reduces the residual oil saturation by lowering water-oil interfacial tension (surfactant/alkaline) and increases the volumetric sweep efficiency by reducing the water-oil mobility ratio (polymer). In this chapter, the basic mechanisms of different chemical methods have been discussed including the interactions of different chemicals with the reservoir rocks and fluids. In addition, an up-to-date status of chemical flooding at the laboratory scale, pilot projects and field applications have been reported.


Energies ◽  
2019 ◽  
Vol 12 (20) ◽  
pp. 3806 ◽  
Author(s):  
Zhen Yin Lau ◽  
Kean Chuan Lee ◽  
Hassan Soleimani ◽  
Hoe Guan Beh

Applications of nanoparticles (NPs) in the Enhanced oil recovery (EOR) method has become a major research field as nanoparticles are found to be able to interfere with the interfacial tension and wettability of multiphase fluids within the reservoir formation with or without the irradiance of the electromagnetic (EM) waves. For future EOR usage, a material with high temperature stability and low losses under oscillating wave is recommended, Yttrium Iron Garnet (YIG). This paper describes the synthesis of rare-earth doped YIG (RE-YIG, RE = (Lanthanum (La), Neodymium (Nd) and Samarium (Sm)) and the roles of rare-earth in alteration of magnetic properties. These magnetic properties are believed to have direct relation with the change in wettability, viscosity and interfacial tension of YIG nanofluids. Here we prepared the Y2.8R0.2Fe5O12 (R = La, Nd, Sm) NPs using the sol-gel auto-combustion technique and further annealed at 1000 °C for 3 h. The Field Emission Scanning Electron Microscope (FESEM) images reveal the particles having grain size ranging from 100–200 nm with high crystallinity and X-ray Powder Diffraction (XRD) shows varying shift of the peak position due to the bigger size of the rare-earth ions which resulted in structural distortion. The wettability of the nanofluid for all samples shows overall reduction under the influence of EM waves. On the other hand, the interfacial tension (IFT) and viscosity of RE-YIG nanofluids has lower value than the pure YIG nanofluids and decreases when the ionic radius of rare-earth decreases. Sm-YIG has the highest magnitude in IFT and magnetization saturation of 23.54 emu/g which suggests the increase in magnetization might contribute to higher surface tension of oil-nanofluid interface.


Author(s):  
J.Y. Laval

The exsolution of magnetite from a substituted Yttrium Iron Garnet, containing an iron excess may lead to a transitional event. This event is characterized hy the formation of a transitional zone at the center of which the magnetite nucleates (Fig.1). Since there is a contrast between the matrix and these zones and since selected area diffraction does not show any difference between those zones and the matrix in the reciprocal lattice, it is of interest to analyze the structure of the transitional zones.By using simultaneously different techniques in electron microscopy, (oscillating crystal method microdiffraction and X-ray microanalysis)one may resolve the ionic process corresponding to the transitional event and image this event subsequently by high resolution technique.


1997 ◽  
Vol 07 (C1) ◽  
pp. C1-283-C1-286
Author(s):  
P. Novák ◽  
J. Englich ◽  
H. Stepánková ◽  
J. Kohout ◽  
H. Lütgemeier ◽  
...  

1971 ◽  
Vol 32 (C1) ◽  
pp. C1-200-C1-201 ◽  
Author(s):  
P. HANSEN ◽  
W. TOLKSDORF

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