Synthesis and Second-Order Optical Nonlinearity of Inorganic-Organic Hybrid Films Bearing Y-Type NLO Active Chromophore

In order to achieve a large hyperpolarizability (β) value and thermal stability, a novel Y-type silicon precursor ICTES-DBPNPI was synthesized. By the sol-gel process, the new organic-inorganic materials having organic chromophore were prepared.

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Synthesis and Second-Order Optical Nonlinearity of Inorganic-Organic Hybrid Films Bearing Y-Type NLO Active Chromophore

Key Engineering Materials - High-Performance Ceramics IV ◽

10.4028/0-87849-410-3.552 ◽

2007 ◽

pp. 552-554

Author(s):

Xiao Nan Mei ◽

Hai Yao Lin ◽

Yuan Jing Cui ◽

Ping Lv ◽

Guo Dong Qian

Keyword(s):

Optical Nonlinearity ◽

Second Order ◽

Hybrid Films ◽

Organic Hybrid

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Template Recognition in Inorganic−Organic Hybrid Films Prepared by the Sol−Gel Process

Chemistry of Materials ◽

10.1021/cm9801136 ◽

1998 ◽

Vol 10 (9) ◽

pp. 2440-2445 ◽

Cited By ~ 109

Author(s):

Rajendra Makote ◽

Maryanne M. Collinson

Keyword(s):

Sol Gel ◽

Hybrid Films ◽

Organic Hybrid ◽

Sol Gel Process

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Preparation and second-order optical nonlinearity of inorganic–organic hybrid films

Journal of Non-Crystalline Solids ◽

10.1016/j.jnoncrysol.2007.02.091 ◽

2008 ◽

Vol 354 (12-13) ◽

pp. 1211-1215 ◽

Cited By ~ 3

Author(s):

Yuanjing Cui ◽

Lujian Chen ◽

Guodong Qian ◽

Minquan Wang

Keyword(s):

Optical Nonlinearity ◽

Second Order ◽

Hybrid Films ◽

Organic Hybrid

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Stable second-order nonlinear optical poly(amide-imide)/inorganic materials via simultaneous sequential self-repetitive reaction and sol-gel process

Polymers for Advanced Technologies ◽

10.1002/pat.1065 ◽

2008 ◽

Vol 19 (8) ◽

pp. 984-992 ◽

Cited By ~ 12

Author(s):

Hsun-Lien Lin ◽

Tsung-Yi Chao ◽

Yeng-Fong Shih ◽

Shenghong A. Dai ◽

Wen-Chiung Su ◽

...

Keyword(s):

Nonlinear Optical ◽

Sol Gel ◽

Second Order ◽

Inorganic Materials ◽

Sol Gel Process

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Second-Order Nonlinearity of Organic/Inorganic Hybrid Materials Doped with Organic Chromophore by All-Optical Poling

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.217-218.533 ◽

2011 ◽

Vol 217-218 ◽

pp. 533-538

Author(s):

Yun Long Liu ◽

Wen Jun Wang ◽

Juan Wang ◽

Xue Xi Gao ◽

Hui Li

Keyword(s):

Hybrid Material ◽

Nonlinear Optical ◽

Sol Gel ◽

Second Order ◽

Poling Temperature ◽

Sol Gel Process ◽

All Optical ◽

Organic Chromophore ◽

Different Thickness ◽

Second Order Nonlinearity

A kind of hybrid material was synthesized via sol-gel process with PMMA and TEOS as reactants, and 4’-Iodo-4-dimethylaminoazobenzene (IDMA) as nonlinear optical organic chromophore. The second order nonlinear optical properties of hybrid material in thin films were investigated by using All-optical poling technique, and the influences of films thickness, structure and poling temperature on SHG properties were discussed. The experimental results indicated that the absorption spectrum of PMMA/SiO2/IDMA film was wider than the spectrum of PMMA/IDMA film. As a consequence of the experiment, we found that different thickness films had different SHG saturation values, there was an optimum thickness for the films. In addition, the higher the sample temperature is, the smaller the SHG intensity is. We also found that the existence of SiO2 network in the film significantly improved the azo orientation stability.

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Synthesis and Intermolecularly Mediated Assembly of Organic Pigment in Hybrid Coating Films

MRS Proceedings ◽

10.1557/proc-519-103 ◽

1998 ◽

Vol 519 ◽

Author(s):

Y. Yan ◽

Z. Duan ◽

D.-G. Chen ◽

S. Ray Chaudhuri

Keyword(s):

Sol Gel ◽

Hybrid Coating ◽

Hypsochromic Shift ◽

Hybrid Films ◽

Coating Films ◽

Organic Pigment ◽

Inorganic Hybrid ◽

Matrix Interactions ◽

Sol Gel Process

AbstractThe insoluble, strongly hydrogen bonded organic pigment of 3,6-bis-(4-chlorphenyl)-l,4- diketopyrrolo [3,4-c] pyrrole was transiently blocked by adding carbamate groups, and consequently incorporated into organic-inorganic hybrid matrices by a sol-gel process. The homo- (pigment-pigment) and hetero-intermolecular (pigment-matrix) interactions were found to control both the assembly and dispersion of pigment molecules in the hybrid coating films. A weaker interaction between matrices and pigment molecules results in aggregation of the carbamate pigment in the methyl-silicate films. A stronger interaction forms a homogenous dispersion and coloration of the phenyl-silicate films. The as-prepared methyl- and phenylsilicate films doped with the organic pigment were distinguished by a morphology change and a blue (hypsochromic) shift in absorption from 550 to 460 nm. Thermal treatment can remove the carbamate groups and in-situ form the organic pigment in the hybrid films.

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The preparation of poly(methylsilsesquioxane) network-polyimide hybrid materials by the sol-gel process and their properties

High Performance Polymers ◽

10.1088/0954-0083/6/1/005 ◽

1994 ◽

Vol 6 (1) ◽

pp. 43-52 ◽

Cited By ~ 24

Author(s):

Yoshitake Iyoku ◽

Masa-aki Kakimoto ◽

Yoshio Imai

Keyword(s):

Hybrid Materials ◽

Sol Gel ◽

Tensile Modulus ◽

Hybrid Films ◽

Elongation At Break ◽

Dimethyl Acetamide ◽

Flexible Films ◽

Sol Gel Process ◽

Heating Up ◽

Silicone Content

Poly(methylsilsesquixoane) network (silicone)-polyimide hybrid materials were successfully prepared by the sol-gel reaction of methyltriethoxysilane (MTES). The ethoxysilyl group in MTES was hydrolyzed and polycondensed in the solution of the polyamic acid, derived from pyromellitic dianhydride and bis(4-aminophenyl)ether, in N,N-dimethyl-acetamide (DMAc). The hybrid films were obtained by casting the reaction mixture, followed by heating up to 300°C. The hybrid materials containing 0-60wt% of silicone afforded flexible films. The films containing less than 7 wt% silicone were yellow and transparent, whereas the films with higher silicone content were yellow and opaque. Silicone particles with a diameter of around 1-10 μm were observed in the fracture surface of the hybrid films by scanning electron microscopy. Although the tensile strength and tensile modulus of the films obtained decreased with increasing silicone content. the value of the elongation at break remained at 60% up to 30% silicone content.

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