Preparation and Electrochemical Properties of LiMnPO4 Nanoparticles by Polyol Method

Plate-like LiMnPO4particles were prepared by polyol method. The chemical and physical properties of plate-like LiMnPO4particles were characterized by XRD and SEM. The thickness of plate-like LiMnPO4particles was approximately 35 nm. XRD pattern of plate-like LiMnPO4was good agreement with orthorhombic olivine structure. The first discharge capacity of C/LiMnPO4cathode was approximately 95 mAh/g. 99.9 % of initial discharge capacity was maintained after 100 cycles.

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Synthesis and Electrochemical Properties of C/LiMnPO4 Cathode Materials by Complex Polymerized Method

Key Engineering Materials ◽

10.4028/www.scientific.net/kem.485.115 ◽

2011 ◽

Vol 485 ◽

pp. 115-118

Author(s):

Atsushi Fujita ◽

Fuminari Isobe ◽

Takayuki Kodera ◽

Takashi Ogihara

Keyword(s):

Thermogravimetric Analysis ◽

Electrochemical Properties ◽

Carbon Content ◽

Discharge Capacity ◽

Cathode Materials ◽

Type Structure ◽

Initial Discharge Capacity ◽

Initial Discharge ◽

Differential Thermogravimetric Analysis

C/LiMnPO4 materials were synthesized by the complex polymerized method. An orthorhombic olivine type structure was obtained by calcination at temperatures over 973 K under an argon/hydrogen (5%) atmosphere. Differential thermogravimetric analysis showed that the carbon content of C/LiMnPO4 was about 65 wt%. The initial discharge capacity of C/LiMnPO4 calcined at 973 K was 135 mAh/g at 0.1 C and 60 mAh/g at 1 C.

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Improved electrochemical properties of (1 − x)LiFePO4·xLi3V2(PO4)3/C composites prepared by a novel sol–gel method

New Journal of Chemistry ◽

10.1039/c5nj01328c ◽

2015 ◽

Vol 39 (11) ◽

pp. 8971-8977 ◽

Cited By ~ 8

Author(s):

Yuanchang Si ◽

Zhi Su ◽

Yingbo Wang ◽

Ting Ma ◽

Juan Ding

Keyword(s):

Electrochemical Properties ◽

Discharge Capacity ◽

Sol Gel ◽

Initial Discharge Capacity ◽

Gel Method ◽

Sol Gel Method ◽

Initial Discharge

0.8LiFePO4·0.2Li3V2(PO4)3/C composites were synthesized by a new sol–gel method, which delivered an initial discharge capacity of 158.7 mA h g−1 at 0.1C.

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Synthesis and Characterization of LiFePO4 Prepared by Sol-Gel Technique

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.430-432.937 ◽

2012 ◽

Vol 430-432 ◽

pp. 937-940

Author(s):

Heng Wang ◽

Yan Li Ruan ◽

Zhe Chi Shi

Keyword(s):

Discharge Capacity ◽

Sol Gel ◽

Synthesis And Characterization ◽

Initial Discharge Capacity ◽

Orthorhombic Structure ◽

Xrd Pattern ◽

Initial Discharge ◽

N2 Atmosphere ◽

Gel Technique

LiFePO4 material was synthesized at 650°C in an N2 atmosphere using a sol-gel method. This material showed a well developed XRD pattern (orthorhombic structure, Pnma) without peaks at 2θ=41°, indicating the absence of FeP or metallic Fe2P impurities. The Li/LiFePO4 cell showed a high initial discharge capacity of more than 140mAh/g and no capacity decrease until the 50th cycle (>99.0%).

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Solvothermal synthesis and electrochemical properties of S-doped Bi2Se3 hierarchical microstructure assembled by stacked nanosheets

RSC Advances ◽

10.1039/c6ra01301e ◽

2016 ◽

Vol 6 (44) ◽

pp. 38228-38232 ◽

Cited By ~ 10

Author(s):

Fangxin Mao ◽

Jing Guo ◽

Shaohua Zhang ◽

Fan Yang ◽

Qiao Sun ◽

...

Keyword(s):

Energy Storage ◽

Electrochemical Properties ◽

Lithium Ion Battery ◽

Discharge Capacity ◽

Solvothermal Synthesis ◽

Lithium Ion ◽

Initial Discharge Capacity ◽

Hierarchical Microstructure ◽

Initial Discharge

Hierarchical S-doped Bi2Se3 microspheres assembled by stacked nanosheets were successfully synthesized as the anode of a lithium ion battery, which shows an initial discharge capacity of 771.3 mA h g−1 with great potential in energy storage.

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Synthesis and Electrochemical Properties of Cathode Material LiNi0.8Co0.1Mn0.1O2 via Li, Mg, Al Dopping

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.1058.302 ◽

2014 ◽

Vol 1058 ◽

pp. 302-306 ◽

Cited By ~ 4

Author(s):

Sha Yuan ◽

Liang Bin Liu ◽

Yan Ping Tang ◽

Jian Hua Wang ◽

Yu Zhong Guo

Keyword(s):

Cathode Material ◽

Electrochemical Properties ◽

Discharge Capacity ◽

High Efficiency ◽

Lithium Ion ◽

Initial Discharge Capacity ◽

Capacity Loss ◽

Initial Discharge ◽

Result Show ◽

Properties Of Materials

Coprecipitation method is adopted to prepare LiNi0.8Co0.1Mn0.1O2, to discuss the factors of affecting electrochemical properties and structure at lithium ion battery cathode material LiNi0.8Co0.1Mn0.1O2. In order to improve the electrochemical properties of materials, LiNi0.8Co0.1Mn0.1O2 materials were modified by doping the cation of Li or Mg or Al. Through the charge-discharge tests in the range of 2.5~4.3V, the result show that doped Mg samples with a discharge capacity and high efficiency as well as the lowest capacity loss, the initial discharge capacity is 205.9mA.h/g, after 20 cycles the discharge capacity reached 142.4mA.h/g.

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Effect of sulfur doping on structural reversibility and cycling stability of a Li2MnSiO4 cathode material

Dalton Transactions ◽

10.1039/c8dt02226g ◽

2018 ◽

Vol 47 (35) ◽

pp. 12337-12344 ◽

Cited By ~ 3

Author(s):

Xia Wu ◽

Shi-Xi Zhao ◽

Lü-Qiang Yu ◽

Jin-Lin Yang ◽

Ce-Wen Nan

Keyword(s):

Cathode Material ◽

Discharge Capacity ◽

Cycling Stability ◽

Initial Discharge Capacity ◽

Sulfur Doping ◽

Initial Discharge ◽

Excellent Cycling Stability

Sulfur has been successfully employed into Li2MnSiO4 and results in a high initial discharge capacity and excellent cycling stability.

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An inorganic–organic nanocomposite calix[4]quinone (C4Q)/CMK-3 as a cathode material for high-capacity sodium batteries

Inorganic Chemistry Frontiers ◽

10.1039/c7qi00453b ◽

2017 ◽

Vol 4 (11) ◽

pp. 1806-1812 ◽

Cited By ~ 21

Author(s):

Shibing Zheng ◽

Jinyan Hu ◽

Weiwei Huang

Keyword(s):

Cathode Material ◽

Discharge Capacity ◽

High Capacity ◽

Initial Discharge Capacity ◽

Capacity Retention ◽

Initial Discharge ◽

Sodium Batteries

A novel high-capacity cathode material C4Q/CMK-3 for SIBs shows an initial discharge capacity of 438 mA h g−1 and a capacity retention of 219.2 mA h g−1 after 50 cycles.

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Tris(trimethylsilyl) phosphite (TMSPi) as an electrolyte additive for LiNi0.5Co0.2Mn0.3O2 cathode materials at elevated voltage and temperature

Functional Materials Letters ◽

10.1142/s1793604721510449 ◽

2021 ◽

Author(s):

Xiao Yu ◽

Zhiyong Yu ◽

Jishen Hao ◽

Hanxing Liu

Keyword(s):

Discharge Capacity ◽

Cathode Materials ◽

Solid Electrolyte Interphase ◽

Rate Capability ◽

Electrochemical Performances ◽

Initial Discharge Capacity ◽

Capacity Retention ◽

Electrolyte Additive ◽

Interface Impedance ◽

Initial Discharge

Electrolyte additive tris(trimethylsilyl) phosphite (TMSPi) was used to promote the electrochemical performances of LiNi[Formula: see text]Co[Formula: see text]Mn[Formula: see text]O2 (NCM523) at elevated voltage (4.5 V) and temperature (55[Formula: see text]C). The NCM523 in 2.0 wt.% TMSPi-added electrolyte exhibited a much higher capacity (166.8 mAh/g) than that in the baseline electrolyte (118.3 mAh/g) after 100 cycles under 4.5 V at 30[Formula: see text]C. Simultaneously, the NCM523 with 2.0 wt.% TMSPi showed superior rate capability compared to that without TMSPi. Besides, after 100 cycles at 55[Formula: see text]C under 4.5 V, the discharge capacity retention reached 87.4% for the cell with 2.0 wt.% TMSPi, however, only 24.4% of initial discharge capacity was left for the cell with the baseline electrolyte. A series of analyses (TEM, XPS and EIS) confirmed that TMSPi-derived solid electrolyte interphase (SEI) stabilized the electrode/electrolyte interface and hindered the increase of interface impedance, resulting in obviously enhanced electrochemical performances of NCM523 cathode materials under elevated voltage and/or temperature.

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The displacement reaction mechanism of the CuV2O6 nanowire cathode for rechargeable aqueous zinc ion batteries

Dalton Transactions ◽

10.1039/c9dt04226a ◽

2020 ◽

Vol 49 (4) ◽

pp. 1048-1055 ◽

Cited By ~ 5

Author(s):

Xin Yu ◽

Fang Hu ◽

Fuhan Cui ◽

Jun Zhao ◽

Chao Guan ◽

...

Keyword(s):

Reaction Mechanism ◽

Cathode Material ◽

Discharge Capacity ◽

Current Density ◽

Zinc Ion ◽

Cycle Performance ◽

Displacement Reaction ◽

Initial Discharge Capacity ◽

Initial Discharge ◽

A Current

CuV2O6 nanowires as a cathode material for Zn-ion batteries display an initial discharge capacity of 338 mA h g−1 at a current density of 100 mA g−1 and an excellent cycle performance after 1200 cycles at 5 A g−1.

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