Tris(trimethylsilyl) phosphite (TMSPi) as an electrolyte additive for LiNi0.5Co0.2Mn0.3O2 cathode materials at elevated voltage and temperature

Electrolyte additive tris(trimethylsilyl) phosphite (TMSPi) was used to promote the electrochemical performances of LiNi[Formula: see text]Co[Formula: see text]Mn[Formula: see text]O2 (NCM523) at elevated voltage (4.5 V) and temperature (55[Formula: see text]C). The NCM523 in 2.0 wt.% TMSPi-added electrolyte exhibited a much higher capacity (166.8 mAh/g) than that in the baseline electrolyte (118.3 mAh/g) after 100 cycles under 4.5 V at 30[Formula: see text]C. Simultaneously, the NCM523 with 2.0 wt.% TMSPi showed superior rate capability compared to that without TMSPi. Besides, after 100 cycles at 55[Formula: see text]C under 4.5 V, the discharge capacity retention reached 87.4% for the cell with 2.0 wt.% TMSPi, however, only 24.4% of initial discharge capacity was left for the cell with the baseline electrolyte. A series of analyses (TEM, XPS and EIS) confirmed that TMSPi-derived solid electrolyte interphase (SEI) stabilized the electrode/electrolyte interface and hindered the increase of interface impedance, resulting in obviously enhanced electrochemical performances of NCM523 cathode materials under elevated voltage and/or temperature.

Time Evolution of the Skin–Electrode Interface Impedance under Different Skin Treatments

A low and stable impedance at the skin–electrode interface is key to high-fidelity acquisition of biosignals, both acutely and in the long term. However, recording quality is highly variable due to the complex nature of human skin. Here, we present an experimental and modeling framework to investigate the interfacial impedance behavior, and describe how skin interventions affect its stability over time. To illustrate this approach, we report experimental measurements on the skin–electrode impedance using pre-gelled, clinical-grade electrodes in healthy human subjects recorded over 24 h following four skin treatments: (i) mechanical abrasion, (ii) chemical exfoliation, (iii) microporation, and (iv) no treatment. In the immediate post-treatment period, mechanical abrasion yields the lowest initial impedance, whereas the other treatments provide modest improvement compared to untreated skin. After 24 h, however, the impedance becomes more uniform across all groups (<20 kΩ at 10 Hz). The impedance data are fitted with an equivalent circuit model of the complete skin–electrode interface, clearly identifying skin-level versus electrode-level contributions to the overall impedance. Using this model, we systematically investigate how time and treatment affect the impedance response, and show that removal of the superficial epidermal layers is essential to achieving a low, long-term stable interface impedance.

Impedance Modelling of All-Solid-State Thin Film Batteries: Influence of the Reaction Kinetics

Understanding the effect of material properties on the interface impedance is crucial for high energy all-solid-state thin film lithium-ion battery design. Nevertheless, reaction kinetics determined by the free enthalpy difference...

An Interference Suppression Method for Non-Contact Bioelectric Acquisition

For non-contact bioelectrical acquisition, a new interference suppression method, named ‘noise neutralization method’, is proposed in this paper. Compared with the traditional capacitive driven-right-leg method, the proposed method is characterized with that there is an optimal gain to achieve the minimum interference output whatever for the electrode interface impedance mismatch caused by body motion and is more effective for smaller reference electrode areas. The performance of traditional capacitive driven-right-leg method is analyzed and the difficulty to suppress interference in the case of the interface impedance mismatch is pointed out. Therefore, a noise neutralization method is proposed by applying the reference electrode and a 50 Hz band-pass filter to obtain the interference of the human body and adapting the gains to neutralize the interference inputs of two acquisition electrodes and achieve the minimum interference output. The performance of the proposed method is theoretically analyzed and verified by the experiment results, which shows that the proposed method has similar performance to that of the traditional capacitive driven-right-leg method with electrode interface impedance match, while has better interference suppression ability with electrode interface impedance mismatch caused by body motion. It is suggested that the proposed method can be preferred in the case of limited reference electrode area or interface impedance mismatch.

Surface Discharges and Flashover Modelling of Solid Insulators in Gases

The aim of this paper is the presentation of an analytical model of insulator flashover and its application for air at atmospheric pressure and pressurized SF6 (Sulfur Hexafluoride). After a review of the main existing models in air and compressed gases, a relationship of flashover voltage based on an electrical equivalent circuit and the thermal properties of the discharge is developed. The model includes the discharge resistance, the insulator impedance and the gas interface impedance. The application of this model to a cylindrical resin-epoxy insulator in air medium and SF6 gas with different pressures gives results close to the experimental measurements.