scholarly journals Structural Relation between the X-Phase and other Phases in Ni2MnGa

2009 ◽  
Vol 635 ◽  
pp. 49-54 ◽  
Author(s):  
Tomoyuki Kakeshita ◽  
Takashi Fukuda ◽  
Tomoyuki Terai ◽  
Toyotaka Osakabe ◽  
Kazuhisa Kakurai

We have investigated stress and temperature dependences of the structure of the X-phase in Ni2MnGa to understand structural relation between the X-phase and other phases. Position and intensity of satellites of the X-phase are different from those of the intermediate (I-) phase under compressive stress, but they approach those of the I-phase with decreasing stress. That is, the structure change associated with the I → X transformation is discontinuous under a compressive stress, while it is continuous under zero stress. In addition, the transformation from the X-phase to the L21-type parent phase is continuous regardless of applied stress. These results strongly suggest the existence of multi-critical point in Ni2MnGa. On the other hand, the transformation from the X-phase to the martensite phase is discontinuous regardless of applied stress.

1993 ◽  
Vol 58 (9) ◽  
pp. 1989-1996 ◽  
Author(s):  
Ladislav Kosa ◽  
Ivan Nerád ◽  
Jozef Strečko ◽  
Ivo Proks ◽  
Katarína Adamkovičová

Differential enthalpies of solution of components in binary systems 2 CaO . Al2O3 . SiO2-CaO . Al2O3 . 2 SiO2, CaO . SiO2-CaO . Al2O3 . 2 SiO2 and CaO . SiO2-2 CaO . Al2O3 . SiO2 as the function of composition and temperature were determined on the base of isothermal composition dependences of enthalpies of mixing and temperature dependences of heats of fusion of their pure components. From the values of the first differential heat of solution of CaO . Al2O3 . 2 SiO2 and 2 CaO . Al2O3 . SiO2 in CaO . SiO2 over temperature range considered we can conclude that the reactions were closed chains of SiO4 tetrahedra in CaO . SiO2 melt break, are exothermic. On the other hand positive values of this quantity for CaO . SiO2 in CaO . Al2O3 . 2 SiO2 and 2 CaO . Al2O3 . SiO2 led us to the conclusion that the progressive breaking originally closed chains in CaO . SiO2 melt has endothermic character.


2005 ◽  
Vol 475-479 ◽  
pp. 3463-3466
Author(s):  
Shan Qing Xu ◽  
Zheng Hong Guo ◽  
T.Y. Hsu

The possibility of Al2Cu( q) precipitation in nanosized Al-4wt%Cu alloy is predicted based on the theory of homogeneous nucleation. The result indicates that the initial concentration of Cu in parent phase has little influence on the nucleation event when the grain size is larger than a critical size. On the other hand, when the grain size is smaller than the critical size, the formation of a stable Al2Cu nucleus will be prohibited completely due to the insufficient initial concentration of Cu.


1992 ◽  
Vol 20 (4) ◽  
pp. 254-264 ◽  
Author(s):  
X. W. Du ◽  
W. Qu ◽  
Z. M. Wan ◽  
H. Ma ◽  
M. Yao ◽  
...  

Abstract Whether polymer cords embedded in rubber under compression have a reinforcing function is still an important question in the analysis of tire structures. In this paper, on the basis of experimental results, it is confirmed that polymer cords embedded in rubber present some stiffness, thus playing a reinforcing role to a certain extent. When the cord volume fraction in the cord-rubber composite is sufficiently large, the reinforcing function of the polymer cords is so significant that the properties of the cord-rubber composite are mainly influenced by those of the cord. When the compressive stress reaches a certain value, the cord-rubber composite specimen yields by buckling if the cord volume fraction is large enough and the cord angle is within a certain small range. The buckling stress, which may be considered to be a failure stress, decreases with an increase in temperature. On the other hand, the effect of the cord angle on the buckling stress is found to be insignificant.


2019 ◽  
Vol 16 (1) ◽  
pp. 0111
Author(s):  
Anmar Hashim Jasim

This paper contains an equivalent statements of a pre-  space, where  are considered subsets of with the product topology. An equivalence relation between the preclosed set  and a pre-  space, and a relation between a pre-  space and the preclosed set  with some conditions on a function  are found. In addition, we have proved that the graph  of  is preclosed in if  is a pre-  space, where the equivalence relation  on  is open.      On the other hand, we introduce the definition of a pre-stable ( pre-stable) set by depending on the concept of a pre-neighborhood, where we get that every stable set is pre-stable. Moreover, we obtain that a pre-stable ( pre-stable) set is positively invariant (invariant), and we add a condition on this set to prove the converse. Finally, a relationship between, (i) a pre-stable ( pre-stable) set and its component (ii) a pre- space and a (positively critical point) critical point, are gotten.


2013 ◽  
Vol 738-739 ◽  
pp. 33-37 ◽  
Author(s):  
Fei Xiao ◽  
Kaname Yashima ◽  
Takashi Fukuda ◽  
Tomoyuki Kakeshita

We have investigated superelastic behavior of an Fe-30.8Pd (at.%) alloy. This alloy transforms from a FCC parent phase to a FCT martensite phase at 255 K with a latent heat of 38 J/mol. When a compressive stress is applied in the [001] direction above the transformation temperature, the specimen exhibits a large elastic-like strain of more than 3% under relatively small stress of 100 MPa. The large elastic-like strain mainly comes from the elastic strain of the parent and martensite phases. The transformation strain also contributes to the strain, but it decreases linearly with increasing temperature and stress. The transformation strain || is extrapolated to be about 1.4 % under zero stress, and 0 % under 100 MPa. Probably a critical point, at which first order nature of the transformation disappears, exists for the FCC to FCT transformation in Fe-Pd alloys.


2007 ◽  
Vol 22 (12) ◽  
pp. 3501-3506 ◽  
Author(s):  
S.J. Suresha ◽  
R. Gunda ◽  
V. Jayaram ◽  
S.K. Biswas

The intercolumnar fracture strength of a columnar TiN film was deconvoluted by nanoindentation load-displacement curves. The columnar boundary strength of such films strongly depends on the amount of residual stress present in the film. The residual stress of the coating was modified by plastically stretching the substrate. Indentation studies on the columnar TiN coating as a function of residual stress reveals that the column sliding stress diminishes with residual stress, suggesting that the presence of a high compressive stress substantially improves the fracture strength of a columnar TiN film. True film hardness on the other hand does not change.


2009 ◽  
Vol 642 ◽  
pp. 15-48 ◽  
Author(s):  
GUENTER AHLERS ◽  
BERND DRESSEL ◽  
JAECHUL OH ◽  
WERNER PESCH

Measurements of fluctuations and convection patterns in horizontal layers of fluid heated from below and near the onset of Rayleigh–Bénard convection (RBC) are reported under conditions where the fluid properties vary strongly over the temperature range ΔT = Tb − Tt (Tb and Tt are the temperatures at the bottom and top of the sample, respectively). To facilitate a comparison with the data, the theory of Busse (J. Fluid Mech., vol. 30, 1967, p. 625) of these so called non-Oberbeck–Boussinesq (NOB) effects, which applies to the case of relatively weak (and linear) temperature dependences, was extended to arbitrary variations with temperature. It is conceptually useful to divide the variations with temperature of the fluid properties into two disjunct parts. One part is chosen so that it preserves the reflection symmetry of the system about the horizontal midplane, while the remainder breaks that symmetry. The latter, exclusively considered by Busse, leads (in contrast to the formation of the typical convection rolls in RBC) to hexagons immediately above the transition to convection at the critical temperature difference ΔTc. The symmetric part, on the other hand, does not prevent the bifurcation to rolls, but may become very important for the determination of ΔTc. In the experiment the fluid was sulfur hexafluoride at temperatures above but close to the gas–liquid critical point, where all fluid properties vary strongly with temperature. All measurements were done along isobars by varying ΔT. Patterns were observed above onset (ΔT ≳ ΔTc), while for the conduction state at ΔT < ΔTc there were only fluctuations induced by Brownian motion. When the mean temperature Tm = (Tb + Tt)/2 was such that the density ρ at Tm was equal to the critical density ρ*, the mirror symmetry about the horizontal midplane of the sample was essentially preserved. In that case, as expected, we found a direct transition to rolls and the critical temperature difference ΔTc was considerably shifted compared to the critical value ΔTc,OB in the absence of NOB effects. When, on the other hand, Tm was not located on the critical isochore, the NOB effects broke the reflection symmetry and led to a hysteretic transition from fluctuations to hexagonal patterns. In this latter case the hexagonal pattern, the observed hysteresis at onset and the transition from hexagons to rolls at larger ΔT were consistent with the ‘classical’ predictions by Busse.


1995 ◽  
Vol 403 ◽  
Author(s):  
D. J. Srolovitz ◽  
W. Yang ◽  
M. G. Goldiner

AbstractThis paper provides a thermodynamic analysis of hole and hillock growth in stressed thin films in simplified geometries. Two limiting cases were considered. In the first, matter is transported to (from) the growing hillock (hole) from (to) the surface of the film. In the second case, the material transported to (from) the growing hillock (hole) comes from (goes to) the interior of the film in the vicinity of the hillock (hole). When bulk relaxation is dominant, hillock growth is favored by a compressive stress in the film and hole growth is enhanced when the film is in tension. This is the commonly observed situation. On the other hand, when surface relaxation effects dominate, hillocks and holes can grow in either tension or compression.


1999 ◽  
Vol 173 ◽  
pp. 249-254
Author(s):  
A.M. Silva ◽  
R.D. Miró

AbstractWe have developed a model for theH2OandOHevolution in a comet outburst, assuming that together with the gas, a distribution of icy grains is ejected. With an initial mass of icy grains of 108kg released, theH2OandOHproductions are increased up to a factor two, and the growth curves change drastically in the first two days. The model is applied to eruptions detected in theOHradio monitorings and fits well with the slow variations in the flux. On the other hand, several events of short duration appear, consisting of a sudden rise ofOHflux, followed by a sudden decay on the second day. These apparent short bursts are frequently found as precursors of a more durable eruption. We suggest that both of them are part of a unique eruption, and that the sudden decay is due to collisions that de-excite theOHmaser, when it reaches the Cometopause region located at 1.35 × 105kmfrom the nucleus.


Author(s):  
A. V. Crewe

We have become accustomed to differentiating between the scanning microscope and the conventional transmission microscope according to the resolving power which the two instruments offer. The conventional microscope is capable of a point resolution of a few angstroms and line resolutions of periodic objects of about 1Å. On the other hand, the scanning microscope, in its normal form, is not ordinarily capable of a point resolution better than 100Å. Upon examining reasons for the 100Å limitation, it becomes clear that this is based more on tradition than reason, and in particular, it is a condition imposed upon the microscope by adherence to thermal sources of electrons.


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