Influence of Hydrogen Concentration on TiO2 Nanoparticles Prepared by Gaseous Detonation

2011 ◽  
Vol 694 ◽  
pp. 278-283
Author(s):  
Hong Hao Yan ◽  
Xian Chao Huang ◽  
Shu Xiong Xi

This article is mainly introduced the detonation method to prepare TiO2 nanoparticles which use hydrogen-oxygen gas mixture as the explosion source and the titanium tetrachloride as the precursor. It studied TiO2 nanoparticles influenced by different hydrogen concertration. And analyzed the character of prepared TiO2 nanoparticles by XRD and TEM. The results show that the powders are mixed crystal of Rutile and Anatase. It is also found that the relative content of rutile grows larger and the size of grain becomes smaller (about 30~100nm) as the hydrogen content increases, and the TiO2 nanoparticles are mostly spherical. But the dispersion is becomes slightly worse, and the agglomeration appear.

2020 ◽  
Vol 28 (6) ◽  
pp. 1566-1581
Author(s):  
Bahador Akbari ◽  
Asghar Lashanizadegan ◽  
Parviz Darvishi ◽  
Abdolrasoul Pouranfard
Keyword(s):  

2021 ◽  
Vol 57 (6) ◽  
pp. 77-86
Author(s):  
T.-J. Zhao ◽  
X.-H. Wang ◽  
S. Kang ◽  
Z.-F. Wang ◽  
H.-H. Yan

1996 ◽  
Vol 438 ◽  
Author(s):  
Y. Cheong ◽  
H. Du ◽  
S. P. Withrow

AbstractThe role of aluminum in negating the adverse effect of alkali species on the oxidation resistance of Si3N4 ceramics was investigated by exposing unimplanted and aluminum-implanted (1 and 5 at.%) Si3N4 samples to a sodium nitrate (95 ppm)-dry oxygen gas mixture at 1. atm and at 900°1100°C. Oxidation of unimplanted Si3N4 was rapid and linear with an activation energy of 57 kJ/mol. In contrast, samples implanted with aluminum exhibited a considerably reduced oxide growth which was parabolic in nature with activation energies of 103–112 kJ/mol. The morphological characteristics of the oxide layer also showed marked improvement as the aluminum concentration increased.


2011 ◽  
Vol 317-319 ◽  
pp. 410-413
Author(s):  
Zhi Qin Chen ◽  
Shan Shan Luo ◽  
Xiang Liang Chen ◽  
Ze Hua Zhou ◽  
Wen Kui Li

The different crystal (rutile, rutile-anntase-brookite, anatase, amorphous) titania were prepared by the hydrolysis of titanium tetrachloride (TiCl4) in the absence or presence of HCl or NaOH. The mixture solution was processed in microwave hydrothermal autoclave at 120oC for 1.5 h and then at 180oC for 1 h to precipitate titania. HCl acted as inhibitor, which could control the crystal and shape of the precipitate of titania. NaOH was used to adjust the pH to the required value. As a result, the mixture of rutile (majority), anatase and brookite (minor) was obtained from the aqueous TiCl4 solution without any addition, shuttle-like and well-dispersed nanocrystalline rutile appeared in the presence of HCl from the aqueous TiCl4-HCl solution. Single phase anatase was obtained in the presence of NaOH with pH=7, and when pH=9, the product was quite amorphous. The products were analyzed using XRD and TEM.


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