Solid Oxide Fuel Cell - A Future Source of Power and Heat Generation

2013 ◽  
Vol 757 ◽  
pp. 217-241 ◽  
Author(s):  
Pankaj Kalra ◽  
Rajeev Garg ◽  
Ajay Kumar

Fuel cells are devices for electrochemically converting the chemical energy of a fuel gas into electrical energy and heat without the need for direct combustion as an intermediate step. The main advantages of fuel cells are that they rely on the high conversion efficiency and low environmental impact than traditional energy conversion systems. One promising fuel cell type, Solid oxide Fuel Cell, has all the components in the solid phase utilises nano-ceramic composite materials and operates at elevated temperatures in the range 500-1000°C. It has suitable perspectives to replace their classical counterparts for the distributed generation of electrical energy with small and medium power sources. The inherent advantages of such high temperature fuel cells are internal reforming of methane and waste heat production at high temperatures which lower the demands on the fuel processing system and lead to higher efficiency compared with low temperature fuel cells. Using natural gas as feed, an electric efficiency of more than 88% has been predicted. On the other hand, considerable research is going on to reduce the operating temperatures between 600°C to 800°C to increase life-time and thereby reduce costs. These can be achieved only by using electrolytes with proper ionic conductivity at the intermediate temperatures. In addition, this technology does not produce significant amounts of pollutants such as nitrogen oxides compared with internal combustion engines. Solid oxide fuel cells are seen as ideal energy sources in transport, stationary, and distributed power generators.

2005 ◽  
Vol 127 (1) ◽  
pp. 86-90 ◽  
Author(s):  
Eric A. Liese ◽  
Randall S. Gemmen

Solid Oxide Fuel Cell (SOFC) developers are presently considering both internal and external reforming fuel cell designs. Generally, the endothermic reforming reaction and excess air through the cathode provide the cooling needed to remove waste heat from the fuel cell. Current information suggests that external reforming fuel cells will require a flow rate twice the amount necessary for internal reforming fuel cells. The increased airflow could negatively impact system performance. This paper compares the performance among various external reforming hybrid configurations and an internal reforming hybrid configuration. A system configuration that uses the reformer to cool a cathode recycle stream is introduced, and a system that uses interstage external reforming is proposed. Results show that the thermodynamic performance of these proposed concepts are an improvement over a base-concept external approach, and can be better than an internal reforming hybrid system, depending on the fuel cell cooling requirements.


2021 ◽  
Vol 9 ◽  
Author(s):  
Utkarsh Shikhar ◽  
Kas Hemmes ◽  
Theo Woudstra

Fuel cells are electrochemical devices that are conventionally used to convert the chemical energy of fuels into electricity while producing heat as a byproduct. High temperature fuel cells such as molten carbonate fuel cells and solid oxide fuel cells produce significant amounts of heat that can be used for internal reforming of fuels such as natural gas to produce gas mixtures which are rich in hydrogen, while also producing electricity. This opens up the possibility of using high temperature fuel cells in systems designed for flexible coproduction of hydrogen and power at very high system efficiency. In a previous study, the flowsheet software Cycle-Tempo has been used to determine the technical feasibility of a solid oxide fuel cell system for flexible coproduction of hydrogen and power by running the system at different fuel utilization factors (between 60 and 95%). Lower utilization factors correspond to higher hydrogen production while at a higher fuel utilization, standard fuel cell operation is achieved. This study uses the same basis to investigate how a system with molten carbonate fuel cells performs in identical conditions also using Cycle-Tempo. A comparison is made with the results from the solid oxide fuel cell study.


2021 ◽  
Vol 10 (6) ◽  
pp. 2929-2942
Author(s):  
Wandercleiton Cardoso ◽  
Renzo Di Felice ◽  
Raphael Colombo Baptista

Solid oxide fuel cells (SOFC) are the most efficient devices for directly converting the chemical energy of a fuel into electrical energy. This is one of the main reasons why these fuel cells have received a lot of attention from the scientific community and from several developers who have invested in the use of this technology in various applications. Biogas is one of the products of anaerobic decomposition (absence of gaseous oxygen) of organic matter, which occurs due to the action of certain types of bacteria. Biogas is mainly composed of methane (CH4) and carbon dioxide (CO2) and its use in solid oxide fuel cells has been investigated since Biogas is a renewable biofuel. The aim of this paper was to perform mathematical modeling of a solid oxide fuel cell operating on biogas. The results confirmed that the overall efficiency of the system is above 94% and the largest irreversibilities of the system are related to heat exchangers.


RSC Advances ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 7-14
Author(s):  
Cheng Cheng Wang ◽  
Mortaza Gholizadeh ◽  
Bingxue Hou ◽  
Xincan Fan

Strontium segregation in a La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) electrode reacts with Cr and S in a solid oxide fuel cell (SOFC), which can cause cell performance deterioration.


2017 ◽  
Vol 10 (4) ◽  
pp. 964-971 ◽  
Author(s):  
Yu Chen ◽  
Yan Chen ◽  
Dong Ding ◽  
Yong Ding ◽  
YongMan Choi ◽  
...  

A hybrid catalyst coating dramatically enhances the electrocatalytic activity and durability of a solid oxide fuel cell cathode.


2005 ◽  
Vol 2 (2) ◽  
pp. 136-140 ◽  
Author(s):  
Eric S. Greene ◽  
Maria G. Medeiros ◽  
Wilson K. S. Chiu

A one-dimensional model of chemical and mass transport phenomena in the porous anode of a solid-oxide fuel cell, in which there is internal reforming of methane, is presented. Macroscopically averaged porous electrode theory is used to model the mass transfer that occurs in the anode. Linear kinetics at a constant temperature are used to model the reforming and shift reactions. Correlations based on the Damkohler number are created to relate anode structural parameters and thickness to a nondimensional electrochemical conversion rate and cell voltage. It is shown how these can be applied in order to assist the design of an anode.


2019 ◽  
Vol 131 ◽  
pp. 1032-1051 ◽  
Author(s):  
Maciej Chalusiak ◽  
Michal Wrobel ◽  
Marcin Mozdzierz ◽  
Katarzyna Berent ◽  
Janusz S. Szmyd ◽  
...  

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