Synthesis of MDI-50 and Tung Oil-Based Non-Ionic Waterborne Polyurethanes

2016 ◽  
Vol 848 ◽  
pp. 160-166
Author(s):  
Bai Xia Ren ◽  
Hua Fen Wang ◽  
Zhi Yong Ren ◽  
Wen Tao Liu ◽  
Lei Jiang ◽  
...  
Keyword(s):  
Surface Tension ◽  
Soft Segment ◽  
Waterborne Polyurethane ◽  
Lower Surface ◽  
Molecular Structures ◽  
Proton Nuclear Magnetic Resonance ◽  
Feed Ratio ◽  
Tung Oil ◽  
Waterborne Polyurethanes ◽  
Polyurethane Dispersions

A series of MDI-50 based non-ionic waterborne polyurethane dispersions (MDI-NPUD) were prepared by the mixing of 2,4’-diphenylmethane diisocianate (2,4’-MDI) and 4,4’-MDI (MDI-50) which reacted with hydroxylated tung oil (HTO) and polyethylene glycol-800 (PEG-800), Fourier Transform Infrared Spectroscopy (FTIR) and Proton-Nuclear Magnetic Resonance (1H-NMR) were used to characterize and analyze their molecular structures. The results indicated that MDI-50 and HTO were introduced as hard segment while PEG acted as soft segment. The surface tension, Hydrophile-Lipophile Balance (HLB) and stability were investigated. All MDI-NPUDs had much lower surface tension than the dicyclohexyl methane diisocyanate (HMDI) based NPUD (HMDI-NPUD). By changing the feed ratio of MDI-NPUD, the properties of MDI-NPUD could be controlled

Preparation and Application of Undecylenate Based Diol for Bio-Based Waterborne Polyurethane Dispersion

2014 ◽  
Vol 955-959 ◽  
pp. 88-91 ◽  
Author(s):  
Zhe Yang ◽  
Yan Bin Zhu ◽  
Fang Peng ◽  
Chang Qing Fu
Keyword(s):  
Castor Oil ◽  
Room Temperature ◽  
Click Reaction ◽  
Waterborne Polyurethane ◽  
Chain Extender ◽  
Proton Nuclear Magnetic Resonance ◽  
Isophorone Diisocyanate ◽  
Polyurethane Dispersion ◽  
Waterborne Polyurethanes ◽  
Ft Ir

The undecylenate based diol (UAD) has been synthesized from undecylenate by esterification and thiol-ene click reaction sequently, and then it was used as a diol to prepare bio-based waterborne polyurethane (WPU) reacting with isophorone diisocyanate (IPDI) and castor oil-based carboxyl hydrophilic chain extender. The structure of undecylenate based diol was verified by hydrogen proton nuclear magnetic resonance (1H NMR). Fourier transform infrared spectroscopy (FT-IR) was used to characterize the structure of WPU film. Furthermore, particle size and viscosity were used to character apparent properties of the bio-based waterborne polyurethane dispersion. The result shows that: bio-based waterborne polyurethane dispersion is transparent and very stable under room temperature. This work provides a simple and efficient method for the preparation of fatty acids based polyols and bio-based waterborne polyurethanes.

Study on the Modification of Waterborne Polyurethane by Tung Oil Anhydride-Ester Polyol

2015 ◽  
Vol 1088 ◽  
pp. 460-466 ◽  
Author(s):  
Jin Hua Zhou ◽  
Jing Yang ◽  
Wen Jie Ma ◽  
Ni Li ◽  
Han Zhou Sun
Keyword(s):  
Particle Size ◽  
Tensile Test ◽  
Soft Segment ◽  
Waterborne Polyurethane ◽  
Particle Size Analysis ◽  
Size Analysis ◽  
Tung Oil ◽  
Weight Content ◽  
Emulsion Film ◽  
Emulsion Particle

Waterborne polyurethane (WPU) emulsions were prepared with Tung oil anhydride-ester polyol (TOAEP) as modifier via the acetone process. The structure, morphology, emulsion particle size, thermal property and mechanical property of the Modified WPU were investigated by FT-IR, SEM, Laser particle size analysis, TG and tensile test, respectively. The experimental results show that the modified WPU emulsion particle size increases along with the growth of weight content of TOAEP. Compared with the unmodified WPU emulsion film, water and toluene absorption of the modified WPU emulsion film have decreased significantly, indicating that water and solvent resistance are remarkably improved after the modification. Tensile test shows that the tensile strength of the modified WPU emulsion film increases with the content of TOAEP while the reverse is true for the elongation at break. The characteristic thermo-decomposition temperatures of WPU have been increased notably after modification by the introduction of TOAEP which indicates that the heat resistance has been improved after modification. Morphology analysis shows that the soft segment phase and hard segment phase in the WPU are more compatible after modification.

Preparation and Characterization of Castor Oil-Based Cationic Waterborne Polyurethane

2015 ◽  
Vol 1090 ◽  
pp. 3-7
Author(s):  
Kai Liu ◽  
Song Ping Zhang ◽  
Zhi Guo Su ◽  
Guang Hui Ma
Keyword(s):  
Castor Oil ◽  
Hard Segment ◽  
Waterborne Polyurethane ◽  
Gravimetric Analysis ◽  
Waterborne Polyurethanes ◽  
Hard Segment Content ◽  
Ir Analysis ◽  
Hard Segments ◽  
Polyurethane Dispersions

A variety of castor oil-based cationic polyurethane dispersions (PUDs) were synthesized. The effects of hard segment content on the properties of PUDs and the resulting polyurethane films were investigated by mastersizer, Fourier transform infrared (IR), thermal gravimetric analysis (TGA) and stress-strain test. As the hard segment content increased from 37.1 to 45.6 wt %, the particle size of the PUDs increased from 10 to 190 nm. IR analysis showed that hydrogen bonding between hard segments enhanced with the increase of hard segment content. For this enhancement the films had an increased tensile strength from 2.0 to 9.4 MPa and an improved glass transition temperature (Tg) from 48oC to 75oC. TGA showed the films were thermally stable up to 200oC and had biphasic degradation at around 330oC and 440oC. The versatile castor oil-based cationic waterborne polyurethanes are promising in applications as adhesives and coatings.

The Structure and Properties of UV-Curable Cationic Waterborne Polyurethane Acrylate

2015 ◽  
Vol 1090 ◽  
pp. 31-37
Author(s):  
Yi Ding Meng ◽  
Hong Wei Li
Keyword(s):  
Soft Segment ◽  
Waterborne Polyurethane ◽  
Decomposition Temperature ◽  
Particle Size Analysis ◽  
Size Analysis ◽  
Uv Curable ◽  
High Elongation ◽  
Polyurethane Dispersions ◽  
High Degree ◽  
Cationic Waterborne Polyurethane

A series of stable double-terminated UV reactive cationic waterborne polyurethane dispersions was synthesized, while the structure was confirmed by infrared spectroscopy,laser particle size analysis and free NCO root titration; modified by co-monomerhydroxyethyl acrylate with the UV radiation fast curing, the influence of hydroxyethyl acrylate proportion and the polyurethane’s nNCO/nOH(R value) to the thermal properties, mechanical properties and yellowing of the product was investigated. The investigation illustrated the UV-curable cationic waterborne polyurethaneacrylate film effectively forming a semi-interpenetrating network system to achieve rapid curing coating.The results showedthe product cured by WPU dispersion of R=1.5 mixed with equimolar HEA obtained lowyellowing, the maximum breaking strength, high elongation at break, high thermal decomposition temperature, high crystallization temperature of hard segment, low glass transition temperature of soft segment, high degree of phase separation, better overall performance.

Investigation of Hyperbranced Polyesters with Different Generation and their Application in Waterborne Polyurethanes

2012 ◽  
Vol 152-154 ◽  
pp. 91-96 ◽  
Author(s):  
Dong Ya Yang ◽  
Li Han ◽  
Han Qing Zhang ◽  
Feng Xian Qiu
Keyword(s):  
Experimental Data ◽  
Mechanical Properties ◽  
Crosslinking Agent ◽  
Waterborne Polyurethane ◽  
Hyperbranched Polyester ◽  
Aqueous Dispersions ◽  
Hyperbranched Polyesters ◽  
Waterborne Polyurethanes ◽  
Lower Viscosity ◽  
Polyurethane Dispersions

The 1st, 2nd and 3rd generations of hydroxyl-terminated hyperbranched polyesters (HBPE-1, HBPE-2, and HBPE-3) were synthesized. A3rd generation hyperbranched polyester (HBPE-3) was used as original crosslinking agent to prepared hyperbranched waterborne polyurethane dispersions (HPU). FTIR spectra confirmed that this reaction really took place. The experimental data indicated that, compared with the linear one, the hyperbranched HPU aqueous dispersions exhibited lower viscosity, and larger particle size. For the hyperbranched HPU films, mechanical properties were obviously enhanced.

scholarly journals Investigation about wetting ability (surface tension) of water used for preparation of pesticide solutions

2021 ◽  
Vol 117 (3) ◽  
pp. 1
Author(s):  
Donyo Hristov GANCHEV
Keyword(s):  
Surface Tension ◽  
Water Source ◽  
Lower Surface ◽  
Flow Rates ◽  
Wetting Ability ◽  
Lower Resistance ◽  
Wax Content ◽  
Lower Surface Tension ◽  
Plant Surfaces

<p class="042abstractstekst">The investigation about surface tension of water used for preparation of pesticide solutions reveals it is quite diverse and changeable without any logical correlation towards location, time, and type of water source. Moreover, spraying with solutions with lower surface tension give bigger flow rates due to the lower resistance of fluid to the nozzles. The conducted trials show that plant surfaces with more rough texture require to be sprayed with pesticide solutions with lower surface tension. The wax content of the surfaces has no significant impact on surface tension requirement.</p><p> </p>

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