Preparation and Adsorption Properties of Fe/Chitosan/Fly Ash Composite

Fly ash (FA), a kind of fine-powder solid waste, was utilized to prepare a novel Fe/chitosan/FA composite (Fe/CTS/FA) by the calcination and solution reaction with chitosan (CTS) and ferric iron. In combination with the adsorption for reactive turquoise blue KN-G (RTB KN-G) and direct sky blue 5B (DSB 5B) dyes, the main conditions of preparation and adsorption of Fe/CTS/FA were investigated. The composite was characterized with SEM, EDS, particle-size distribution and N2-gas adsorption-desorption technology. The results show that: (1) Fe/CTS/FA prepared by calcining FA at 500°C and further mixing reaction with CTS and FeCl3⋅6H2O solution according to the mass ratio of m(FA):m(CTS):m(Fe)=10:1:0.34 has excellent adsorption properties. The amount of adsorption is mainly affected by solution pH and reaches the equilibrium in 60 min for high-concentration RTB KN-G and DSB 5B dye wastewater with adsorption capacities of 892.95 mg/g and 615.65 mg/g, which are 16.28 and 32.56 times larger than those of FA, respectively. (2) The characterization results of Fe/CTS/FA indicate that CTS and iron hydroxides have been successfully loaded on FA. The surface morphology of Fe/CTS/FA is significantly changed, and the particle-size distribution is obviously smaller than that of FA.

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Modelling of pulverized coal combustion with respect to fly ash particle size distribution

Fuel ◽

10.1016/0016-2361(90)90030-t ◽

1990 ◽

Vol 69 (6) ◽

pp. 690-695 ◽

Cited By ~ 1

Author(s):

Luis Can̄adas ◽

Luis Salvador ◽

Vicente Cortés

Keyword(s):

Particle Size ◽

Fly Ash ◽

Particle Size Distribution ◽

Size Distribution ◽

Coal Combustion ◽

Pulverized Coal ◽

Pulverized Coal Combustion

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Modelling Particle Size Distribution of Residual Fly Ash from Pulverized Biomass Combustion

Journal of Biobased Materials and Bioenergy ◽

10.1166/jbmb.2021.2038 ◽

2021 ◽

Vol 15 (1) ◽

pp. 75-82

Author(s):

Mingzi Xu ◽

Changdong Sheng

Keyword(s):

Particle Size ◽

Fly Ash ◽

Simple Model ◽

Particle Size Distribution ◽

Size Distribution ◽

Particle Shape ◽

Great Influence ◽

Biomass Combustion ◽

Ash Formation ◽

Residual Ash

The present work aims to develop a simple model for describing the particle size distribution (PSD) of residual fly ash from pulverized biomass combustion. The residual ash formation was modelled considering the mechanism of fragmentation and coalescence. The influences of particle shape and stochastic fragmentation on model description of the PSD of the fly ash were investigated. The results showed that biomass particle shape has a great influence on the model prediction, and a larger fragmentation number is required for cylindrical particles than that for spherical particles to get the same PSD of fly ash, and the fragment number of the particles increases with the shape factor increasing. For pulverized biomass with a wide size distribution, the model predicted ash PSD considering the stochastic fragmentation is very similar to that assuming uniform fragmentation. It implies that the simple model assuming uniform fragmentation is applicable for predicting fly ash size distribution in practical processes where biomass particles have a wide range of sizes. For the fuel with a narrower initial PSD, the stochastic fragmentation model generally predicts a coarser PSD of the residual ash than assuming uniform fragmentation. It means the stochastic fragmentation is of great influence to be considered for accurate description of ash formation from the fuel with a narrow PSD.

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Influence of Particle Size Distribution of High Calcium Fly Ash on HVFA Mortar Properties

Civil Engineering Dimension ◽

10.9744/ced.20.2.51-56 ◽

2018 ◽

Vol 20 (2) ◽

pp. 51

Author(s):

Antoni . ◽

Hendra Surya Wibawa ◽

Djwantoro Hardjito

Keyword(s):

Particle Size ◽

Compressive Strength ◽

Fly Ash ◽

Particle Size Distribution ◽

Size Distribution ◽

Setting Time ◽

High Volume ◽

High Volume Fly Ash ◽

High Calcium ◽

High Calcium Fly Ash

This study evaluates the effect of particle size distribution (PSD) of high calcium fly ash on high volume fly ash (HVFA) mortar characteristics. Four PSD variations of high calcium fly ash used were: unclassified fly ash and fly ash passing sieve No. 200, No. 325 and No. 400, respectively. The fly ash replacement ratio of the cementitious material ranged between 50-70%. The results show that with smaller fly ash particles size and higher levels of fly ash replacement, the workability of the mixture was increased with longer setting time. There was an increase in mortar compressive strength with finer fly ash particle size, compared to those with unclassified ones, with the highest strength was found at those with fly ash passing mesh No. 325. The increase was found due to better compactability of the mixture. Higher fly ash replacement reduced the mortar’s compressive strength, however, the rate was reduced when finer fly ash particles was used.

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