Microwave Dielectric Characteristics of Butyl Rubber- Barium Titanate Composites

2012 ◽  
Vol 2012 (CICMT) ◽  
pp. 000428-000435
Author(s):  
J. Chameswary ◽  
M. T. Sebastian

Butyl rubber-micron barium titanate (BR/BT) and butyl rubber-nano barium titanate (BR/nBT) composites were prepared by sigma mixing followed by hot pressing. The tensile tests show that both the composites were mechanically flexible. The microwave dielectric properties of both BR/BT and BR/nBT composites were investigated as a function of ceramic loading and were found to be improved with filler content. The butyl rubber has relative permittivity (εr) of 2.4 and loss tangent (tan δ) of 0.0017 at 5 GHz. At a filler loading of 0.24 volume fraction (vf) of micron sized barium titanate (BaTiO3) powder loading, the composite attained a εr of 7 and tan δ of 0.014 and for the same filler content of nano BaTiO3 the composite have εr of 8.9 and tan δ of 0.019 at 5 GHz. The thermal stability of the relative permittivity of both the composites was investigated. The experimental values of εr of both BR/BT and BR/nBT composites were compared with theoretical models.

2014 ◽  
Vol 136 (3) ◽  
Author(s):  
Dhanesh Thomas ◽  
Mailadil T. Sebastian

Polymer–ceramic composites have been prepared by dispersing Ca4La6(SiO4)4(PO4)2O2 (CLSP) ceramic filler in high density polyethylene (HDPE) matrix through melt mixing. Scanning electron micrographs reveal the extent of filler dispersion. The dielectric properties at 1 MHz and 5 GHz have been investigated as a function of filler content. The relative permittivity increases with filler loading, maintaining a low dielectric loss. The composite with highest filler loading of 0.4 volume fraction shows a relative permittivity of 5.1 and dielectric loss of 2.3 × 10−3 at 5 GHz. Experimentally observed values of relative permittivity at 5 GHz have been compared with the values calculated using various theoretical models. Both the coefficient of linear thermal expansion and tensile strength have been observed to decrease with filler loading, reaching a minimum value of 117 ppm/ °C and 20.7 MPa, respectively, at 0.4 volume fraction of filler. The composite with maximum filler loading of 0.4 volume fraction shows the highest thermal conductivity (TC) and is 1.2 W m−1 K−1.


2021 ◽  
Author(s):  
Srinivas Pattipaka ◽  
Pamu D ◽  
Pundareekam Goud J ◽  
James Raju K C ◽  
Gbinda Pradhan ◽  
...  

Abstract Herein, we have investigated the optical and microwave dielectric properties of Bi 0.5 Na 0.5 TiO 3 (BNT) thin films grown under different oxygen pressure ( P O2 ) using pulsed laser deposition (PLD) technique. The X-ray diffraction measurements confirms the single phase of BNT along with secondary phase and further reduction in secondary phase and increase in BNT phase with P O2 , signifies the close relation between the crystal structure and oxygen content. The shift of Raman-active TO1, TO2 and TO3 modes towards higher wavelengths and increase in mode intensity with P O2 indicating the films degree of crystallinity. The local roughness ( α loc ) of all films obtained as ~ 0.85, and the interface width ( w ) and lateral correlation length ( ξ ) of films varies with P O2 . Also, the films exhibit the increase in refractive index and reduction in optical bandgap of due to improvement in crystallinity and reduction in the oxygen vacancies. The microwave dielectric properties show a strong P O2 depends with higher dielectric constant ( ε r = 336) with lower loss (tan δ = 0.0093) at 5 GHz which show the potential applications in high frequency devices.


2013 ◽  
Vol 22 ◽  
pp. 148-152
Author(s):  
DHANESH THOMAS ◽  
M. T. SEBASTIAN

Butyl rubber — Ca 4 La 6( SiO 4)4( PO 4)2 O 2 — composites have been prepared by sigma mixing and hot pressing. The relative permittivity of the composites varies from 3 to 5.3 at 1 MHz. All the composites show low dielectric loss of the order of 10−3 at 1 MHz. The experimentally observed values of relative permittivity are correlated with those calculated using various theoretical models. The composites show good temperature stability of relative permittivity.


2003 ◽  
Vol 86 (3) ◽  
pp. 511-513 ◽  
Author(s):  
Antonio Feteira ◽  
Kumaravinothan Sarma ◽  
Neil McN. Alford ◽  
Ian M. Reaney ◽  
Derek C. Sinclair

2016 ◽  
Vol 840 ◽  
pp. 8-13
Author(s):  
Hidayani Jaafar ◽  
Zainal Arifin Ahmad ◽  
Mohd Fadzil Ain

The structure and dielectric properties of Barium Zinc Tantalate (BZT) doped by copper oxide (CuO) with a variety of values of mol% doping from 0, 0.1, 0.25, 1.0, 1.5 and 2.5 were prepared using a solid state method. The addition of CuO did not disturb the 1:2 ordering structure of the BZT ceramic. The grain size increased when the addition of doping increased. A small amount of doping elements increased the relative density. The dielectric constant (ɛr) value of the BZT significantly improved with the addition of the CuO for the specimens sintered at 1250°C and it could be explained by the increase of the relative density. The tan δ of the CuO doped with BZT ceramics is lower than pure BZT ceramics, and decreases as the CuO content increases. Meanwhile, for the percentage of bandwidth (%BW) it is shown that the best result is produced when it is doped with 0.25 mol% CuO and sintered at 1250°C. The best microwave dielectric properties obtained were ɛr=70.28, tan δ = 0.024, %BW = 7.83 which occurred for the 0.25 mol% doped CuO and when sintered at 1250°C/4 h.


2011 ◽  
Vol 01 (02) ◽  
pp. 209-213 ◽  
Author(s):  
S. GEORGE ◽  
V. K. SAJITH ◽  
M. T. SEBASTIAN ◽  
S. RAMAN ◽  
P. MOHANAN

The comparison of the low temperature sintering and the microwave dielectric properties of Li2MgSiO4 (LMS) ceramics prepared by citrate gel (CG) route and solid state (SS) ceramic route are discussed in this paper. The LMS prepared using CG route sintered at 1175°C/2 h has εr = 5.3 and tan δ = 1 × 10−3 at 9 GHz. The sintering temperature of LMS is lowered to 950°C with the addition of 5 wt% lithium magnesium zinc borosilicate glass and has εr = 5.6 and tan δ = 2 × 10-3 at 9 GHz. The amount of glass required to lower the sintering temperature of ceramics prepared using CG are slightly higher than that of SS ceramic route. The LMS ceramics prepared using SS ceramic route shows excellent microwave dielectric properties with low sintering temperature compared to CG route.


Author(s):  
Changzhi Yin ◽  
Zezong Yu ◽  
Longlong Shu ◽  
Laijun Liu ◽  
Yan Chen ◽  
...  

AbstractA melilite Ba2CuGe2O7 ceramic was characterized by low sintering temperature and moderate microwave dielectric properties. Sintered at 960 °C, the Ba2CuGe2O7 ceramic had a high relative density 97%, a low relative permittivity (εr) 9.43, a quality factor (Q×f) of 20,000 GHz, and a temperature coefficient of resonance frequency (τf) −76 ppm/°C. To get a deep understanding of the relationship between composition, structure, and dielectric performances, magnesium substitution for copper in Ba2CuGe2O7 was conducted. Influences of magnesium doping on the sintering behavior, crystal structure, and microwave dielectric properties were studied. Mg doping in Ba2CuGe2O7 caused negligible changes in the macroscopic crystal structure, grain morphology, and size distribution, while induced visible variation in the local structure as revealed by Raman analysis. Microwave dielectric properties exhibit a remarkable dependence on composition. On increasing the magnesium content, the relative permittivity featured a continuous decrease, while both the quality factor and the temperature coefficient of resonance frequency increased monotonously. Such variations in dielectric performances were clarified in terms of the polarizability, packing fraction, and band valence theory.


2011 ◽  
Vol 124 (4) ◽  
pp. 3426-3433 ◽  
Author(s):  
Chameswary Janardhanan ◽  
Dhanesh Thomas ◽  
Ganesanpotti Subodh ◽  
Soumya Harshan ◽  
Jacob Philip ◽  
...  

ChemInform ◽  
2003 ◽  
Vol 34 (27) ◽  
Author(s):  
Antonio Feteira ◽  
Kumaravinothan Sarma ◽  
Neil McN. Alford ◽  
Ian M. Reaney ◽  
Derek C. Sinclair

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