scholarly journals Particle Shape Control of Zn-Al Composite Oxides by Using Composite Hydroxides as a Precursor

2020 ◽  
Vol 67 (2) ◽  
pp. 73-79
Author(s):  
Kohei YAMAZAKI ◽  
Mitsuaki MATSUOKA ◽  
Norihiro MURAYAMA
2018 ◽  
Vol 2018 (0) ◽  
pp. J0440002
Author(s):  
Yuji ICHIKAWA ◽  
Ryotaro TOKORO ◽  
Kazuhiro OGAWA

RSC Advances ◽  
2017 ◽  
Vol 7 (29) ◽  
pp. 17577-17585 ◽  
Author(s):  
Yalu Liu ◽  
Huijie Lu ◽  
Wenxiao Pan ◽  
Qianqian Li ◽  
Guijin Su ◽  
...  

Generated PeCNs to MoCNs congeners during the degradation of CN-27 over Fe–Al mixed composite oxides suggest the occurrence of successive hydrodechlorination and side chlorination pathways.


Materials ◽  
2020 ◽  
Vol 13 (13) ◽  
pp. 3036
Author(s):  
Feng Yu ◽  
Shinan Bi ◽  
Tonghui Liu ◽  
Dahai Pan ◽  
Shuwei Chen ◽  
...  

Ordered mesoporous Zr-Al composite oxide materials (denoted as OMZA-x) with different Zr contents have been synthesized by a solvent evaporation-inducing self-assembly procedure associated with a thermal treatment at 100 °C. A cooperative co-assembly process of amphiphilic triblock copolymer F127 molecules and inorganic hydroxyl species originated from the hydrolysis of Zr and Al precursors was proposed to explain the synthesis of OMZA-x. Compared to ordered mesoporous alumina prepared without introducing Zr species, the resultant OMZA-x exhibited a much more ordered mesostructure combined with a distinct increase in the pore volume and specific surface area. The highly homogenous doping of Zr into the mesopore walls together with the formation of Zr-O-Al bonds can effectively enhance the thermal and hydrothermal stability of OMZA-x. For instance, the ordered mesostructure and excellent textural properties of OMZA-6 prepared with the optimum atomic ratio of Al to Zr of 6 could be well maintained even after a high-temperature treatment at 1000 °C for 1 h or a hydrothermal treatment at 100 °C for 6 h.


2019 ◽  
Vol 10 (19) ◽  
pp. 2415-2423 ◽  
Author(s):  
Eun Ji Kim ◽  
Jae Man Shin ◽  
YongJoo Kim ◽  
Kang Hee Ku ◽  
Hongseok Yun ◽  
...  

An approach to blend AB-type block copolymers and C-type copolymers within the emulsion droplet is an efficient particle shape-engineering strategy.


1999 ◽  
Vol 14 (3) ◽  
pp. 866-875 ◽  
Author(s):  
Jooho Moon ◽  
Melanie L. Carasso ◽  
Henrik G. Krarup ◽  
Jeffrey A. Kerchner ◽  
James H. Adair

Phase-pure perovskite lead titanate with various morphologies has been synthesized by a hydrothermal method at 150 °C. Particle shapes include cubic, tabular, and aggregated platelike shapes. The feedstock concentration greatly influences particle morphology of the hydrothermally derived PbTiO3. At a concentration of 0.05 M, the tabular particles form while cubic particles are produced at 0.1 M. Aggregated plateletlike particles are synthesized at 0.125 M. It was observed that both tabular and cubic particles directly precipitate from the coprecipitated precursor gel. In contrast, the plateletlike shaped intermediate phase appears during the initial stage of reaction at 0.125 M and in situ transforms into perovskite PbTiO3 during further hydrothermal treatment. The intermediate phase preserves its particle shape during transformation and, acting as a template, gives rise to the final tabular PbTiO3 particles. It is demonstrated that only base reagents such KOH and NaOH, which provide a highly basic condition (i.e., pH > 14), promote transformation of the coprecipitated gel into the perovskite PbTiO3. A Hancock and Sharp kinetic analysis in conjunction with microstructural evidence suggests that the formation mechanism is dissolution and recrystallization in which the degree of supersaturation plays an important role in dictating the crystallographic particle phase and morphology of the particles. An experimentally constructed solubility diagram indicates that an excess lead condition is necessary to compensate for loss of lead species and to increase supersaturation to expedite precipitation of PbTiO3 at highly alkaline conditions.


ACS Nano ◽  
2018 ◽  
Vol 12 (9) ◽  
pp. 9186-9195 ◽  
Author(s):  
Alberto Leonardi ◽  
Michael Engel

2015 ◽  
Vol 22 (5) ◽  
pp. 1153-1160 ◽  
Author(s):  
Xingfu Shang ◽  
Xueguang Wang ◽  
Xiujing Zou ◽  
Xionggang Lu ◽  
Weizhong Ding

Author(s):  
Masaru OTANI ◽  
Tomoyuki UCHIYAMA ◽  
Hironori MINOSHIMA ◽  
Kunio SHINOHARA ◽  
Kunihito TAKAYASHIKI ◽  
...  

2019 ◽  
Vol 49 (11) ◽  
pp. 385-394
Author(s):  
Wenqing Ma ◽  
Wei Zhang ◽  
Yuantao Chen ◽  
Yunsheng Wang ◽  
Fang Yu ◽  
...  

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