Partial Oxidation of Natural Gas Using Internal Combustion Engines

Author(s):  
M. Ghaffarpour ◽  
A. Lock ◽  
M. Shojaeefard
Energy ◽  
2008 ◽  
Vol 33 (2) ◽  
pp. 248-255 ◽  
Author(s):  
C.D. Rakopoulos ◽  
M.A. Scott ◽  
D.C. Kyritsis ◽  
E.G. Giakoumis

Author(s):  
Daniel B. Olsen ◽  
Bryan D. Willson

Formaldehyde is a hazardous air pollutant (HAP) that is typically emitted from natural gas-fired internal combustion engines as a product of incomplete combustion. The US Environmental Protection Agency (EPA) is currently developing national emission standards to regulate HAP emissions, including formaldehyde, from stationary reciprocating internal combustion engines under Title III of the 1990 Clean Air Act Amendments. This work investigates the effect that variations of engine operating parameters have on formaldehyde emissions from a large bore natural gas engine. The subject engine is a Cooper-Bessemer GMV-4TF two-stroke cycle engine with a 14″ (36 cm) bore and a 14″ (36 cm) stroke. Engine parameter variations investigated include load, boost, ignition timing, inlet air humidity ratio, air manifold temperature, jacket water temperature, prechamber fuel supply pressure, exhaust backpressure, and speed. The data analysis and interpretation is performed with reference to possible formaldehyde formation mechanisms and in-cylinder phenomena.


Author(s):  
Michael G. Waller ◽  
Mark R. Walluk ◽  
Thomas A. Trabold

The Environmental Protection Agency (EPA) has estimated that 5% of air pollutants originate from small internal combustion engines (ICE) used in non-automotive applications. While there have been significant advances towards developing more sustainable systems to replace large ICEs, few designs have been implemented with the capability to replace small ICEs such as those used in the residential sector for lawn and garden equipment. Replacing these small residential internal combustion engines presents a unique opportunity for early market penetration of fuel cell technologies. This paper describes the initial efforts to build an innovative residential-scale fuel cell system using propane as its fuel source, and the deployment of this technology in a commonly used device found throughout the U.S. There are three main components to this program, including the development of the propane reforming system, fuel cell operation, and the overall system integration. This paper presents the reforming results of propane catalytic partial oxidation (cPOx). The primary parameters used to evaluate the reformer in this experiment were reformate composition, carbon concentration in the effluent, and reforming efficiency as a function of catalyst temperature and O2/C ratio. When including the lower heating value (LHV) for product hydrogen and carbon monoxide, maximum efficiencies of 84% were achieved at an O2/C ratio of 0.53 and a temperature of 940°C. Significant solid carbon formation was observed at catalyst temperatures below 750°C.


Energies ◽  
2020 ◽  
Vol 13 (14) ◽  
pp. 3734
Author(s):  
Javier Monsalve-Serrano ◽  
Giacomo Belgiorno ◽  
Gabriele Di Blasio ◽  
María Guzmán-Mendoza

Notwithstanding the policies that move towards electrified powertrains, the transportation sector mainly employs internal combustion engines as the primary propulsion system. In this regard, for medium- to heavy-duty applications, as well as for on- and off-road applications, diesel engines are preferred because of the better efficiency, lower CO2, and greater robustness compared to spark-ignition engines. Due to its use at a large scale, the internal combustion engines as a source of energy depletion and pollutant emissions must further improved. In this sense, the adoption of alternative combustion concepts using cleaner fuels than diesel (e.g., natural gas, ethanol and methanol) presents a viable solution for improving the efficiency and emissions of the future powertrains. Particularly, the methane–diesel dual-fuel concept represents a possible solution for compression ignition engines because the use of the low-carbon methane fuel, a main constituent of natural gas, as primary fuel significantly reduces the CO2 emissions compared to conventional liquid fuels. Nonetheless, other issues concerning higher total hydrocarbon (THC) and CO emissions, mainly at low load conditions, are found. To minimize this issue, this research paper evaluates, through a new and alternative approach, the effects of different engine control parameters, such as rail pressure, pilot quantity, start of injection and premixed ratio in terms of efficiency and emissions, and compared to the conventional diesel combustion mode. Indeed, for a deeper understanding of the results, a 1-Dimensional spray model is used to model the air-fuel mixing phenomenon in response to the variations of the calibration parameters that condition the subsequent dual-fuel combustion evolution. Specific variation settings, in terms of premixed ratio, injection pressure, pilot quantity and combustion phasing are proposed for further efficiency improvements.


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