scholarly journals Synthesis, characterization, and photocatalytic efficiency of a new smart PdO oxide nanomaterials for using in the recycling and sustainable wastewater treatment

2021 ◽  
Vol 35 (1) ◽  
pp. 107-118
Author(s):  
M. S. Refat ◽  
H. A. Saad ◽  
A. A. Gobouri ◽  
M. Alsawat ◽  
K. Belgacem ◽  
...  

Nanostructured PdO materials with promising catalytic properties were successfully synthesized by the controlled thermal decomposition in air of three Pd(II) complexes containing Pd(II) ion, ofloxacin drug and amino acid. The Pd(II) complexes which were used as precursors were [Pd(OFL)(Gly)]Cl, [Pd(OFL)(Ala)]Cl, and [Pd(OFL)2]Cl2, where Gly is glycine amino acid, Ala is alanine amino acid, and OFL is ofloxacin. Structural and morphological properties of the synthesized PdO materials were obtained using FTIR, XRD, SEM, and EDX techniques. The XRD results confirm the tetragonal structure of PdO. The obtained PdO materials were tested as a catalyst for the heterogeneous degradation of H2O2 solution. The results revealed that PdO could effectively degrade H2O2.                     KEY WORDS: PdO, Nanoparticles, Photocatalytic efficiency, Wastewater treatment   Bull. Chem. Soc. Ethiop. 2021, 35(1), 107-118. DOI: https://dx.doi.org/10.4314/bcse.v35i1.9

2021 ◽  
Vol 13 (14) ◽  
pp. 8057
Author(s):  
Mostafa Ghasemi ◽  
Mehdi Sedighi ◽  
Yie Hua Tan

In this paper, we reported the fabrication, characterization, and application of carbon nanotube (CNT)-platinum nanocomposite as a novel generation of cathode catalyst in microbial fuel cells (MFCs) for sustainable energy production and wastewater treatment. The efficiency of the carbon nanocomposites was compared by platinum (Pt), which is the most effective and common cathode catalyst. This nanocomposite is utilized to benefit from the catalytic properties of CNTs and reduce the amount of required Pt, as it is an expensive catalyst. The CNT/Pt nanocomposites were synthesized via a chemical reduction technique and the electrodes were characterized by field emission scanning electron microscopy, electronic dispersive X-Ray analysis, and transmission electron microscopy. The nanocomposites were applied as cathode catalysts in the MFC to obtain polarization curve and coulombic efficiency (CE) results. The catalytic properties of electrodes were tested by linear sweep voltammetry. The CNT/Pt at the concentration of 0.3 mg/cm2 had the highest performance in terms of CE (47.16%), internal resistance (551 Ω), COD removal (88.9%), and power generation (143 mW/m2). In contrast, for the electrode with 0.5 mg/L of Pt catalyst, CE, internal resistance, COD removal, and power generation were 19%, 810 Ω, 96%, and 84.1 mW/m2, respectively. So, it has been found that carbon nanocomposite cathode electrodes had better performance for sustainable clean energy production and COD removal by MFC.


2003 ◽  
Vol 48 (1) ◽  
pp. 77-85 ◽  
Author(s):  
X.-D. Hao ◽  
M.C.M. van Loosdrecht

Water problems have to be solved in an integrated way, and sustainability has become a major issue. For this reason, developing more sustainable wastewater treatment processes is needed. New discoveries and good understanding on microbial conversions of nitrogen and phosphorus make more sustainable processes possible. New options for decentralized sustainable sanitation are generally compared to conventional sewage systems, we think that for a proper comparison also innovative centralized treatment schemes should be evaluated. In this article, a more sustainable WWTP is proposed for municipal wastewater treatment, mainly based on the principles of denitrifying dephosphatation and anaerobic ammonium oxidation (ANAMMOX). The proposed system consists of a first stage of the A/B process in which maximal sludge production is achieved. In this way, COD is regained as sludge for methanation. The following BCFS® and CANON processes can remove N and P with minimal or no COD need. As a potential fertiliser, struvite can easily be removed from the sludge water by adding magnesium compounds. A case study is done on the basis of the mass balance over the proposed plant. The effluent from the system has a good quality to be recycled. This could also make a contribution to meeting the world's water needs and lessening the impact on the world's water environment. Since all the separate units are already applied or tested on pilot-scale, no problems for technical implementation are foreseen.


2018 ◽  
Vol 290 ◽  
pp. 38-45 ◽  
Author(s):  
Li-Zhi Huang ◽  
Yifeng Zhang ◽  
Xin-Ming Hu ◽  
Hans Christian B. Hansen ◽  
Steen Uttrup Pedersen ◽  
...  

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