scholarly journals Porous Solids for Adsorption and Separation of Gas and Vapor Mixtures

Author(s):  
Eduardo Pérez Botella
Keyword(s):  
2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.


2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.


2018 ◽  
Author(s):  
Julia Miguel-Donet ◽  
Javier López-Cabrelles ◽  
Nestor Calvo Galve ◽  
Eugenio Coronado ◽  
Guillermo Minguez Espallargas

<p>Modification of the magnetic properties in a solid-state material upon external stimulus has attracted much attention in the recent years for their potential applications as switches and sensors. Within the field of coordination polymers, gas sorption studies typically focus on porous solids, with the gas molecules accommodating in the channels. Here we present a 1D non-porous coordination polymer capable of incorporating HCl gas molecules, which not only causes a reordering of its atoms in the solid state but also provokes dramatic changes in the magnetic behaviour. Subsequently, a further solid-gas transformation can occur with the extrusion of HCl gas molecules causing a second structural rearrangement which is also accompanied by modification in the magnetic path between the metal centres. Unequivocal evidence of the two-step magnetostructural transformation is provided by X-ray single-crystal diffraction.</p>


Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1205
Author(s):  
Hai Qiu ◽  
Ying Li ◽  
Tianfu Guo ◽  
Shan Tang ◽  
Zhaoqian Xie ◽  
...  

Structural topology and loading condition have important influences on the mechanical behaviors of porous soft solids. The porous solids are usually set to be under uniaxial tension or compression. Only a few studies have considered the biaxial loads, especially the combined loads of tension and compression. In this study, porous soft solids with oblique and square lattices of circular voids under biaxial loadings were studied through integrated experiments and numerical simulations. For the soft solids with oblique lattices of circular voids, we found a new pattern transformation under biaxial compression, which has alternating elliptic voids with an inclined angle. This kind of pattern transformation is rarely reported under uniaxial compression. Introducing tensile deformation in one direction can hamper this kind of pattern transformation under biaxial loading. For the soft solids with square lattices of voids, the number of voids cannot change their deformation behaviors qualitatively, but quantitatively. In general, our present results demonstrate that void morphology and biaxial loading can be harnessed to tune the pattern transformations of porous soft solids under large deformation. This discovery offers a new avenue for designing the void morphology of soft solids for controlling their deformation patterns under a specific biaxial stress-state.


Langmuir ◽  
2017 ◽  
Vol 33 (34) ◽  
pp. 8420-8427 ◽  
Author(s):  
Amirfarrokh Farzaneh ◽  
Robert F. DeJaco ◽  
Lindsay Ohlin ◽  
Allan Holmgren ◽  
J. Ilja Siepmann ◽  
...  

1995 ◽  
Vol 51 (14) ◽  
pp. 8709-8714 ◽  
Author(s):  
S. J. Sze ◽  
T. Y. Lee

1980 ◽  
Vol 38 (2) ◽  
pp. 251-252
Author(s):  
D. Dollimore
Keyword(s):  

2000 ◽  
pp. 1351-1352 ◽  
Author(s):  
S. N. Ghanashyam Acharya ◽  
K. Venkatesan ◽  
Santanu Bhattacharya ◽  
R. Srinivasa Gopalan ◽  
G. U. Kulkarni

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