Cadmium removal from aqueous solution by iron oxide coated sepiolite: preparation, characterization and batch adsorption studies

2019 ◽  
Vol 146 ◽  
pp. 245-256
Author(s):  
İlker Kıpçak ◽  
Ceren Akın
2015 ◽  
Vol 43 (3) ◽  
pp. 277-281 ◽  
Author(s):  
M Rahman ◽  
S Gul ◽  
M Ajmal ◽  
A Iqbal ◽  
Akk Achakzai

Removal of cadmium from aqueous solution was studied by using Quetta pine (Pinus halepensis Mill.) leaves. Batch adsorption experiments were performed as a function of appropriate equilibrium time, pH, concentration of adsorbate and amount of adsorbent. The optimum pH required for maximum adsorption was found to be 7.0 and the maximum contact time for the equilibrium was 30 minutes at adsorbent dose of 10 g. The maximum adsorption efficiency of cadmium removal was 98.50%. The results were better fitted by Langmuir than Freundlich isotherm. The separation factor of equilibrium 0.12 and 0.67 showed that Quetta pine leaves are good adsorbent of cadmium from aqueous solution DOI: http://dx.doi.org/10.3329/bjb.v43i3.21598 Bangladesh J. Bot. 43(3): 277-281, 2014 (December)


2017 ◽  
Vol 2017 ◽  
pp. 1-11 ◽  
Author(s):  
Aamir Abbas ◽  
Basim Ahmed Abussaud ◽  
Ihsanullah ◽  
Nadhir A. H. Al-Baghli ◽  
Halim Hamid Redhwi

Multiwall carbon nanotubes (CNTs) and iron oxide impregnated carbon nanotubes (CNTs-iron oxide) were investigated for the adsorption of hazardous toluene and paraxylene (p-xylene) from aqueous solution. Pure CNTs were impregnated with iron oxides nanoparticles using wet impregnation technique. Various characterization techniques including thermogravimetric analysis, scanning electron microscopy, elemental dispersion spectroscopy, X-ray diffraction, and nitrogen adsorption analysis were used to study the thermal degradation, surface morphology, purity, and surface area of the materials. Batch adsorption experiments show that iron oxide impregnated CNTs have higher degree of removal of p-xylene (i.e., 90%) compared with toluene (i.e., 70%), for soaking time 2 h, with pollutant initial concentration 100 ppm, at pH 6 and shaking speed of 200 rpm at 25°C. Pseudo-second-order model provides better fitting for the toluene and p-xylene adsorption. Langmuir and Freundlich isotherm models demonstrate good fitting for the adsorption data of toluene and p-xylene.


2017 ◽  
Vol 17 (6) ◽  
pp. 296-305 ◽  
Author(s):  
Mohamed El-Sherif Goher ◽  
Mostafa Mahmoud Emara ◽  
Mohamed Hassan Abdo ◽  
Nesrine Mohamed Refaat Mah ◽  
Amaal Mansour Abdel-Sata ◽  
...  

Our Nature ◽  
2013 ◽  
Vol 11 (1) ◽  
pp. 11-16 ◽  
Author(s):  
N. Gandhi ◽  
D. Sirisha ◽  
K.B. Chandra Sekhar

The presence of toxic heavy metals such as chromium (VI) contaminants in aqueous streams, arising from the discharge of untreated metal containing effluents into water bodies, is one of the most important environmental problems. Adsorption is one of the effective techniques for chromium (VI) removal from wastewater. In the present study, adsorbent was prepared from low cost adsorbents and studies were carried out for chromium (VI) removal. Batch adsorption studies demonstrated that the adsorbents had significant capacity to adsorb the chromium from aqueous solution. It was found that the adsorption increased with increase in contact time and adsorbent dosage. An attempt was made to study mixed algae as an adsorbent for removal of chromium (VI).DOI: http://dx.doi.org/10.3126/on.v11i1.8238 Our Nature Vol.11(1) 2013: 11-16?


2017 ◽  
Vol 2017 ◽  
pp. 1-10 ◽  
Author(s):  
Muhammad I. Qureshi ◽  
Faheemuddin Patel ◽  
Nadhir Al-Baghli ◽  
Basim Abussaud ◽  
Bassam S. Tawabini ◽  
...  

The present study reports the use of raw, iron oxide, and aluminum oxide impregnated carbon nanotubes (CNTs) for the adsorption of hexavalent chromium (Cr(VI)) ions from aqueous solution. The raw CNTs were impregnated with 1% and 10% loadings (weight %) of iron oxide and aluminum oxide nanoparticles using wet impregnation technique. The synthesized materials were characterized using scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). Batch adsorption experiments were performed to assess the removal efficiency of Cr(VI) ions from water and the effects of pH, contact time, adsorbent dosage, and initial concentration of the Cr(VI) ions were investigated. Results of the study revealed that impregnated CNTs achieved significant increase in the removal efficiency of Cr(VI) ions compared to raw CNTs. In fact, both CNTs impregnated with 10% loading of iron and aluminum oxides were able to remove up to 100% of Cr(VI) ions from aqueous solution. Isotherm studies were carried out using Langmuir and Freundlich isotherm models. Adsorption kinetics of Cr(VI) ions from water was found to be well described by the pseudo-second-order model. The results suggest that metallic oxide impregnated CNTs have very good potential application in the removal of Cr(VI) ions from water resulting in better environmental protection.


2016 ◽  
Vol 27 (1) ◽  
pp. 84-95 ◽  
Author(s):  
Geetha Varma V. ◽  
Anil K. Misra

The potential of papaya leaf powder and paddy straw powder for copper(II) removal was evaluated from aqueous solution via column and batch adsorption studies. Batch adsorption studies were performed to determine the contact time effects, biosorbent dosage, pH and initial concentration of metal ion on adsorption capacity. Results showed approximately 90% to 95% of copper removal using both the adsorbents from the solution. As the amount of biosorbent increases, the biosorption capacity also increases. Findings indicate that pH is an important factor for metal ion biosorption and 7.0 is the optimum pH for copper removal. For explaining the mechanism of copper distribution into the solid and liquid phases in batch studies, Freundlich isotherm and Langmuir adsorption isotherm model are used and findings illustrate that adsorption phenomenon is better represented by Freundlich isotherm. Maximum adsorption capacity of copper was calculated as 24.63 mg/g and 37.17 mg/g for papaya powder and for paddy straw powder, respectively, by using Langmuir model. The adsorption phenomenon complies with the pseudo-second-order rate equation. Using packed bed column, the biosorbents’ ability of copper(II) ions removal from aqueous solution was also examined and an S shape profile was obtained for the breakthrough curve. For practical applications, both the adsorbents can be effectively used for wastewater treatment owing to their high capacity of adsorption of heavy metals at very low cost.


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