Photodecomposition of sodium dodecyl sulfate under high-intensity pulsed UV radiation of continuous spectrum and hydrogen peroxide

2020 ◽  
Vol 195 ◽  
pp. 131-136
Author(s):  
Nikita Levichev ◽  
Yuliia Lagunova ◽  
Aleksandr F. Seliverstov ◽  
Sergey G. Kireev ◽  
Konstantin Tumashevich ◽  
...  
1999 ◽  
Vol 64 (5-6) ◽  
pp. 359-364
Author(s):  
Ivana Jankovic ◽  
Miram Cakar ◽  
Jovan Nedeljkovic

The influence of the anionic surfactant sodium dodecyl sulfate on the rate of the reaction between the cationic form of Nile Blue A and hydrogen peroxide was investigated in the pH range from 5 to 8.5. A retardation of the oxidation of Nile Blue A with hydrogen peroxide of three orders of magnitude was observed at pH 8.5 in the presence of anionic micelles compared to the kinetic data in water. The retardation effect was less pronounced at lower pH values. These effects were explained by the electrostatic interaction of the species involved in the reaction with the negatively charged micellar surface and their effective separation in the vicinity of the micellar surface.


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