Deterioration of Cathodic Protection Action of Zinc-Rich Paint Coatings in Atmospheric Exposure

CORROSION ◽  
2001 ◽  
Vol 57 (7) ◽  
pp. 591-597 ◽  
Author(s):  
S. Feliu ◽  
M. Morcillo ◽  
S. Feliu
Author(s):  
M. Morcillo ◽  
J. Simancas ◽  
J. M. Bastidas ◽  
S. Feliu ◽  
C. Blanco ◽  
...  

2018 ◽  
Vol 7 (3.12) ◽  
pp. 333 ◽  
Author(s):  
Hirudayasamy Dolli ◽  
Andiappan Kavitha ◽  
Jeevarose .

This paper presents the results of performance of sacrificial protection in preventing the rebar corrosion in chloride contaminated and chloride free concrete. In this present study, the effectiveness of sacrificial protection of embedded steel rebars has been evaluated on chloride contaminated and chloride free concrete slabs using ribbon type Zinc anodes with ion conductive polymer backfill over a period of 250 days of exposure. The results showed that the ribbon type zinc sacrificial anodes with the navel electrochemical interface (Ion conductive polymer backfill) can confer effective corrosion protection of embedded steel in concrete on preventing corrosion initiation in chloride contaminated as well as chloride free concretes slabs. The cathodic protection criteria evaluated on concrete unit slab showed that 100-150mV is necessary in the atmospheric exposure and 160-200mV under alternate wetting & drying conditions. 


Author(s):  
M Pal

The marine environment is hostile to most engineering materials, a combination of in-service wear and exposure to marine environment leads to an accelerated material degradation.  Insufficient or poor protection of the substrates further assists the accelerated material degradation in marine environment. There is a direct relationship between the material-state of a ship and its operational capability, readiness, and service life.  The current state-of-the-art practice is to use paint-based coatings to maintain the material-state of ships.  However, the protection offered by paint coatings is usually brief due to inherent permeability and low damage tolerance of these coatings.  For this reason, the paint coatings require renewal at regular intervals, typically less than 5-years, to maintain a minimum level of protection from the marine environment.  The need for regular painting of ships results in a significant negative impact on the through-life availability, operational capability/readiness, and the cost of maintenance/operation of naval ships.  Therefore, the fleet owners and operators should look beyond the conventional paint-based coatings to achieve significant breakthrough improvements in maintaining and enhancing the material-state of naval ships. Metallic coatings, if selected and applied appropriately, will outperform the paint coatings in the marine environment.  Historically, the cost and performance of metallic coatings, mainly thermal metal spray (TMS) coatings, prevented their widespread use in the marine industry.  The TMS coatings also have their own inherent application and performance related limitations that are widely reported in the literature.  However, the cold metal spray (CMS) coating process can overcome the application and performance related limitations that are typically associated with the TMS coatings, therefore creating an opportunity for widespread use of metallic coatings in shipbuilding and fleet upkeep/maintenance. In this paper, the ability of low-pressure (LP-CMS) coatings to repair and reclaim damaged marine components, and application of functional coatings to improve in-service damage tolerance of the damaged/new components is investigated.  The results of the investigation show that two LP-CMS coatings, Al-alloy and CuZn-alloy, can be used to repair and preserve both new and damaged components.  The accelerated salt-spray and natural immersion corrosion testing of the LP-CMS coatings showed that each coating will be better suited to a particular operational environment, i.e. CuZn-alloy coating performed well in both immersion and atmospheric corrosion environments, whereas Al-alloy coating performed well only in atmospheric corrosion environment. 


2018 ◽  
Vol 2 (10) ◽  
pp. 460-465
Author(s):  
Joshua Omowanle ◽  
◽  
Gbekeayo Ayo ◽  
James Habila

2019 ◽  
Vol 24 (4) ◽  
pp. 51-58
Author(s):  
Le Hong Quan ◽  
Nguyen Van Chi ◽  
Mai Van Minh ◽  
Nong Quoc Quang ◽  
Dong Van Kien

The study examines the electrochemical properties of a coating based on water sodium silicate and pure zinc dust (ZSC, working title - TTL-VN) using the Electrochemical Impedance Spectra (EIS) with AutoLAB PGSTAT204N. The system consists of three electrodes: Ag/AgCl (SCE) reference electrode in 3 M solution of KCl, auxiliary electrode Pt (8x8 mm) and working electrodes (carbon steel with surface treatment up to Sa 2.5) for determination of corrosion potential (Ecorr) and calculation of equivalent electric circuits used for explanation of impedance measurement results. It was shown that electrochemical method is effective for study of corrosion characteristics of ZSC on steel. We proposed an interpretation of the deterioration over time of the ability of zinc particles in paint to provide cathodic protection for carbon steel. The results show that the value of Ecorr is between -0,9 and -1,1 V / SCE for ten days of diving. This means that there is an electrical contact between the zinc particles, which provides good cathodic protection for the steel substrate and most of the zinc particles were involved in the osmosis process. The good characteristics of the TTL-VN coating during immersion in a 3,5% NaCl solution can also be explained by the preservation of corrosive zinc products in the coating, which allows the creation of random barrier properties.


Sign in / Sign up

Export Citation Format

Share Document