scholarly journals Comparisons of CH<sub>4</sub> ground-based FTIR measurements near Saint Petersburg with GOSAT observations

2014 ◽  
Vol 7 (4) ◽  
pp. 1003-1010 ◽  
Author(s):  
N. M. Gavrilov ◽  
M. V. Makarova ◽  
A. V. Poberovskii ◽  
Yu. M. Timofeyev

Abstract. Atmospheric column-average methane mole fractions measured with ground-based Fourier-transform spectroscopy near Saint Petersburg, Russia (59.9° N, 29.8° E, 20 m a.s.l.) are compared with similar data obtained with the Japanese GOSAT (Greenhouse gases Observing SATellite) in the years 2009–2012. Average CH4 mole fractions for the GOSAT data version V01.xx are −15.0 ± 5.4 ppb less than the corresponding values obtained from ground-based measurements (with the standard deviations of biases at 13.0 ± 4.2 ppb). For the GOSAT data version V02.xx, the average values of the differences are −1.9 ± 1.8 ppb with standard deviations of 14.5 ± 1.3 ppb. This verifies that FTIR (Fourier transform infrared) spectroscopic observations near Saint Petersburg have similar biases with GOSAT satellite data as FTIR measurements at other ground-based networks and aircraft CH4 estimations.

2013 ◽  
Vol 6 (4) ◽  
pp. 7041-7062 ◽  
Author(s):  
N. M. Gavrilov ◽  
M. V. Makarova ◽  
A. V. Poberovskii ◽  
Yu. M. Timofeyev

Abstract. Atmospheric methane column-mean mole fractions measured with ground-based Fourier-transform spectroscopy near Saint-Petersburg, Russia (59.9° N, 29.8° E) are compared with similar data obtained with the Japanese GOSAT satellite in years 2009–2012. Average CH4 mole fractions for the GOSAT data version V01.xx are by −13 ppb less than the corresponding values obtained from ground-based measurements on the same date (with standard deviation ~ 26 ppb). For the GOSAT data version V02.xx the average difference is ~ 4 ppb and standard deviation ~ 15 ppb. This shows that FTIR spectroscopic observations near Saint-Petersburg could agree with GOSAT satellite data.


1996 ◽  
Vol 79 (3) ◽  
pp. 711-717 ◽  
Author(s):  
Dominique Lefier ◽  
Remy Grappin ◽  
Sylvie Pochet

Abstract The accuracy of fat, crude protein (CP), true protein (TP), and lactose determinations of raw milk by Fourier transform infrared (FTIR) spectroscopy and by analysis with a conventional filter-based milk analyzer was assessed in 6 trials performed over a 10-month period. At each trial, 30 bulk milk samples collected from 15 European countries and 11 reconstituted milks made from raw milk components were analyzed. When calibrations were performed with reconstituted milks at each trial, accuracy standard deviations for fat, CP, TP, and lactose were, respectively, 0.050,0.048,0.035, and 0.076 g/100 g for the filter instrument and 0.047, 0.046,0.042, and 0.065 g/100 g for the FTIR instrument. When a single calibration was made instead of calibrations at each trial, accuracy standard deviations increased for the filter instrument to 0.130, 0.119,0.121, and 0.083 for fat, CP, TP, and lactose, respectively, and for the FTIR instrument to 0.082, 0.053,0.044, and 0.084 g/100 g. Because the FTIR instrument provides more spectral information related to milk composition than does the filter instrument, single-calibration FTIR analysis of milk samples collected in different seasons is more accurate. Using reconstituted milks, prepared such that there is no correlation between fat, CP, and lactose, provides a more robust calibration than using genuine bulk milk, especially when milks with unusual composition are analyzed.


2005 ◽  
Vol 2 (2-3) ◽  
pp. 283-293 ◽  
Author(s):  
M. De Mazière ◽  
A. Rockmann ◽  
C. Vigouroux ◽  
T. Gardiner ◽  
M. Coleman ◽  
...  

1999 ◽  
Vol 38 (33) ◽  
pp. 6801 ◽  
Author(s):  
Hirokazu Kobayashi ◽  
Akiro Shimota ◽  
Kayoko Kondo ◽  
Eisuke Okumura ◽  
Yoshihiko Kameda ◽  
...  

Author(s):  
John A. Reffner ◽  
William T. Wihlborg

The IRμs™ is the first fully integrated system for Fourier transform infrared (FT-IR) microscopy. FT-IR microscopy combines light microscopy for morphological examination with infrared spectroscopy for chemical identification of microscopic samples or domains. Because the IRμs system is a new tool for molecular microanalysis, its optical, mechanical and system design are described to illustrate the state of development of molecular microanalysis. Applications of infrared microspectroscopy are reviewed by Messerschmidt and Harthcock.Infrared spectral analysis of microscopic samples is not a new idea, it dates back to 1949, with the first commercial instrument being offered by Perkin-Elmer Co. Inc. in 1953. These early efforts showed promise but failed the test of practically. It was not until the advances in computer science were applied did infrared microspectroscopy emerge as a useful technique. Microscopes designed as accessories for Fourier transform infrared spectrometers have been commercially available since 1983. These accessory microscopes provide the best means for analytical spectroscopists to analyze microscopic samples, while not interfering with the FT-IR spectrometer’s normal functions.


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