Vertical profile of the clear-sky aerosol direct radiative effect in an Alpine valley, by the synergy of ground-based measurements and radiative transfer simulations

Atmospheric aerosols play an important role in Earth’s radiative balance, directly interacting with solar radiation or influencing cloud formation and properties. In order to assess their radiative impact, it is necessary to accurately characterise their optical properties, together with their spatial and vertical distribution. The information on aerosol vertical profile is often scarce, in particular in mountainous, complex terrains. This study presents the first attempt to evaluate the shortwave aerosol direct radiative effect in the Aosta Valley, a mountainous region in the Northwestern Italian Alps. Ground-based, remote sensing instruments (a sky radiometer and an Automated Lidar Ceilometer) are used to derive two descriptions of the aerosol properties and vertical distribution: a first, more accurate description, which includes the whole spectral information about the aerosol extinction coefficient, phase function and single scattering albedo; a second, more approximate one, which only relies on spectrally constant values of aerosol single scattering albedo and asymmetry factor. This information is used as input for radiative transfer simulations, which allow to estimate, in cloudless conditions, the shortwave aerosol direct radiative effect and the vertical profile of the instantaneous heating rates in the lower layers of the atmosphere. The simulations obtained with the two descriptions do not differ significantly: they highlight a strong surface dimming (between − 25 and − 50 W m− 2) due to the presence of aerosol, with a considerable radiative absorption inside the atmospheric column (around + 30 W m− 2), and an overall small cooling effect for the Earth-atmospheric system. The absorption of solar radiation within the atmospheric column due to aerosol leads to instantaneous heating rates up to 1.5 K day− 1 in the tropospheric layers below 6 km a.s.l. These results show that, in some conditions, the shortwave aerosol direct radiative effect can be considerable even in this Alpine environment, usually considered as relatively pristine (yearly average PM10 concentration about 20 μg m− 3).

Is the Air Too Polluted for Outdoor Activities? Check by Using Your Photovoltaic System as an Air-Quality Monitoring Device

Over the past few decades, the concentrating photovoltaic systems, a source of clean and renewable energy, often fully integrated into the roof structure, have been commonly installed on private houses and public buildings. The purpose of those panels is to transform the incoming solar radiation into electricity thanks to the photovoltaic effect. The produced electric power is affected, in the first instance, by the solar panel efficiency and its technical characteristics, but it is also strictly dependent on site elevation, the meteorological conditions and on the presence of the atmospheric constituents, i.e., clouds, hydrometeors, gas molecules and sub-micron-sized particles suspended in the atmosphere that can scatter and absorb the incoming shortwave solar radiation. The Aerosol Optical Depth (AOD) is an adimensional wavelength-dependent atmospheric column variable that accounts for aerosol concentration. AOD can be used as a proxy to evaluate the concentration of surface particulate matter and atmospheric column turbidity, which in turn affects the solar panel energy production. In this manuscript, a new technique is developed to retrieve the AOD at 550 nm through an iterative process: the atmospheric optical depth, incremented in steps of 0.01, is used as input together with the direct and diffuse radiation fluxes computed by Fu–Liou–Gu Radiative Transfer Model, to forecast the produced electric energy by a photovoltaic panel through a simple model. The process will stop at that AOD value (at 550 nm), for which the forecast electric power will match the real produced electric power by the photovoltaic panel within a previously defined threshold. This proof of concept is the first step of a wider project that aims to develop a user-friendly smartphone application where photovoltaic panel owners, once downloaded it on a voluntary basis, can turn their photovoltaic system into a sunphotometer to continuously retrieve the AOD, and more importantly, to monitor the air quality and detect strong air pollution episodes that pose a threat for population health.

Hydrodynamics of Regional and Seasonal Variations in Congo Basin Precipitation

The processes that determine the seasonality of precipitation in the Congo Basin are examined using the atmospheric column moisture budget. Studying the fundamental determinants of Congo Basin precipitation seasonality supports process-based studies of variations on all time scales, including those associated with greenhouse gas-induced global warming. Precipitation distributions produced by the ERA5 reanalysis provide sufficient accuracy for this analysis, which requires a consistent dataset to relate the atmospheric dynamics and moisture distribution to the precipitation field. The Northern and Southern Hemisphere regions of the Congo Basin are examined separately to avoid the misconception that Congo Basin rainfall is primarily bimodal. While evapotranspiration is indispensable for providing moisture to the atmospheric column to support precipitation in the Congo Basin, its seasonal variations are small and it does not drive precipitation seasonality. During the equinoctial seasons, precipitation is primarily supported by meridional wind convergence in the moist environment in the 800 hPa to 500 hPa layer where moist air flows into the equatorial trough. Boreal fall rains are stronger than boreal spring rains in both hemispheres because low-level moisture divergence develops in boreal spring in association with the developing Saharan thermal low. The moisture convergence term also dominates the moisture budget during the summer season in both hemispheres, with meridional convergence in the 850-600 hPa layer as cross-equatorial flow interacts with the cyclonic flow about the Angola and Sahara thermal lows. Winter precipitation is low because of dry air advection from the winter hemisphere subtropical highs over the continent.

Towards Possible Laminar Channels through Turbulent Atmospheres in a Multifractal Paradigm

In this paper, developments are made towards simulating complex atmospheric behavior using turbulent energy cascade staging models developed through scale relativity theories. Such theoretical considerations imply gauges that describe atmospheric parameters as multifractal functions undertaking scale symmetry breaking at each stage of the turbulent energy cascade. It is found that gauges of higher complexity (in this case, a Riccati-type gauge) can exhibit more complex behavior accordingly, such as both dilation and contraction, but properly parameterizing the solutions formed by these gauges in terms of turbulent staging can be challenging given the multiple constants and parameters. However, it is found that a logistic-type approximation of the multifractal equations of motion that describe turbulent atmospheric entities can be coupled with a model produced by a simpler gauge, and this combination can reveal instances of laminar, or otherwise non-chaotic, behavior in a given turbulent flow at certain scales. Employing the theory with elastic lidar data, quasi-laminar behavior is found in the vicinity of the planetary boundary layer height, and laminar channels are revealed throughout an atmospheric column—these might be used to reveal complex vertical transport behavior in the atmospheric column.

Diurnal evolution of total column and surface atmospheric ammonia in the megacity of Paris, France, during an intense springtime pollution episode

Ammonia (NH3) is a key precursor for the formation of atmospheric secondary inorganic particles, such as ammonium nitrate and sulfate. Although the chemical processes associated with the gas-to-particle conversion are well known, atmospheric concentrations of gaseous ammonia are still scarcely characterized. However, this information is critical, especially for processes concerning the equilibrium between ammonia and ammonium nitrate, due to the semivolatile character of the latter. This study presents an analysis of the diurnal cycle of atmospheric ammonia during a pollution event over the Paris megacity region in spring 2012 (5 d in late March 2012). Our objective is to analyze the link between the diurnal evolution of surface NH3 concentrations and its integrated column abundance, meteorological variables and relevant chemical species involved in gas–particle partitioning. For this, we implement an original approach based on the combined use of surface and total column ammonia measurements. These last ones are derived from ground-based remote sensing measurements performed by the Observations of the Atmosphere by Solar Infrared Spectroscopy (OASIS) Fourier transform infrared observatory at an urban site over the southeastern suburbs of the Paris megacity. This analysis considers the following meteorological variables and processes relevant to the ammonia pollution event: temperature, relative humidity, wind speed and direction, and the atmospheric boundary layer height (as indicator of vertical dilution during its diurnal development). Moreover, we study the partitioning between ammonia and ammonium particles from concomitant measurements of total particulate matter (PM) and ammonium (NH4+) concentrations at the surface. We identify the origin of the pollution event as local emissions at the beginning of the analyzed period and advection of pollution from Benelux and western Germany by the end. Our results show a clearly different diurnal behavior of atmospheric ammonia concentrations at the surface and those vertically integrated over the total atmospheric column. Surface concentrations remain relatively stable during the day, while total column abundances show a minimum value in the morning and rise steadily to reach a relative maximum in the late afternoon during each day of the spring pollution event. These differences are mainly explained by vertical mixing within the boundary layer, provided that this last one is considered well mixed and therefore homogeneous in ammonia concentrations. This is suggested by ground-based measurements of vertical profiles of aerosol backscatter, used as tracer of the vertical distribution of pollutants in the atmospheric boundary layer. Indeed, the afternoon enhancement of ammonia clearly seen by OASIS for the whole atmospheric column is barely depicted by surface concentrations, as the surface concentrations are strongly affected by vertical dilution within the rising boundary layer. Moreover, the concomitant occurrence of a decrease in ammonium particle concentrations and an increase in gaseous ammonia abundance suggests the volatilization of particles for forming ammonia. Furthermore, surface observations may also suggest nighttime formation of ammonium particles from gas-to-particle conversion, for relative humidity levels higher than the deliquescence point of ammonium nitrate.

Aerosol Direct Radiative Effects under Cloud-Free Conditions over Highly-Polluted Areas in Europe and Mediterranean: A Ten-Years Analysis (2007–2016)

This study investigates changes in aerosol radiative effects on two highly urbanized regions across the Euro-Mediterranean basin with respect to a natural desert region as Sahara over a decade through space-based lidar observations. The research is based on the monthly-averaged vertically-resolved aerosol optical depth (AOD) atmospheric profiles along a 1∘×1∘ horizontal grid, obtained from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) instrument measurements aboard the Cloud-Aerosol lidar and Infrared Pathfinder Satellite Observation (CALIPSO). To assess the variability of the anthropogenic aerosols on climate, we compared the aerosol vertical profile observations to a one-dimensional radiative transfer model in two metropolitan climate sensible hot-spots in Europe, namely the Po Valley and Benelux, to investigate the variability of the aerosol radiative effects and heating rate over ten years. The same analysis is carried out as reference on the Sahara desert region, considered subject just to natural local emission. Our findings show the efficacy of emission reduction policies implemented at government level in strongly urbanized regions. The total atmospheric column aerosol load reduction (not observed in Sahara desert region) in Po Valley and Benelux can be associated with: (i) an increase of the energy flux at the surface via direct effects confirmed also by long term surface temperature observations, (ii) a general decrease of the atmospheric column heating rate, and likely (iii) an increase in surface temperatures during a ten-year period. Summarizing, the analysis, based on the decade 2007–2016, clearly show an increase of solar irradiation under cloud-free conditions at the surface of +3.6 % and +16.6% for the Po Valley and Benelux, respectively, and a reduction of −9.0% for the Sahara Desert.

Development and Validation of an End-to-End Simulator and Gas Concentration Retrieval Processor Applied to the MERLIN Lidar Mission

In the context of MERLIN (MEthane Remote LIdar missioN), a French–German spatial lidar mission dedicated to monitoring the atmospheric methane content, two software programs have been developed: LIDSIM (LIDar SIMulator) and PROLID (PROcessor LIDar). The objectives are to assess whether the instrument design meets the performance requirements and to study the sensitivity of this performance to geophysical parameters. LIDSIM is an end-to-end mission simulator and PROLID is a retrieval processor that provides mole fractions of methane in dry air, averaged over an atmospheric column. These two tools are described in this paper. Results of the validation tests and the first full orbit simulations are reported. Merlin target performance does not seem to be reachable but breakthrough performance is reached.

Cost effective meter of moisture integral parameters of the atmospheric column

Continuous remote monitoring of the atmospheric physical parameters is an urgent task for solving the issues related to meteorology, climatology, artificial influence on clouds, studying the physical parameters of cloud cover etc. In the developed countries such issues are solved using science-driven technologies of millimeter wave range radiometry. They allow, in particular, quick restoration of the values of total content and effective temperature of droplet and vaporous moisture in the atmospheric column, and distinguishing the areas with crystalline, droplet or vaporous water phases. This work aims at substantiating, by calculation and experiment, the possibility of large-scale solving the problems of continuous remote monitoring of the studied atmospheric moisture parameters using the method of centimetre wavelength range radiometry. To determine the best pair of frequencies for restoring the atmospheric moisture parameters based on radiometric data of remote sensing the linear absorption coefficients were calculated for clear atmosphere, for cloudy atmosphere depending on the temperature of drops and for rainfalls of various intensities for 4, 12, 20, 40 and 94 GHz frequencies. In order to calculate these data, we used a well-known MPM model (Atmospheric Millimeter-Wave Propagation Model). At the same time, calculation of the altitude profiles of the atmospheric meteorological parameters was carried out based on the ERA-15 model. Comparison of the data obtained by calculation, taking into account the progress of the technical parameters of the serial element base, indicated a possibility of solving the above problems in the centimetre wavelength as well. The research presents a description of the diagram and technical solutions, as well as the appearance of a two-frequency radiometric system with 1.5 cm and 2.5 cm ranges created at the National Aerospace University (KhAI) on the basis of an easily accessible modern element base and full-scale tests' results. The budget-friendly focus of the described product allows for radiophysical measurement with a sensitivity of radiometers exceeding 0.01 K while ensuring the cost of small-scale production of the radio technical part of the system, comparable to the cost of TV converters commonly used in everyday life.