scholarly journals Organic matter mineralization and trace element post-depositional redistribution in Western Siberia thermokarst lake sediments

2011 ◽  
Vol 8 (11) ◽  
pp. 3341-3358 ◽  
Author(s):  
S. Audry ◽  
O. S. Pokrovsky ◽  
L. S. Shirokova ◽  
S. N. Kirpotin ◽  
B. Dupré
Keyword(s):  
Trace Elements ◽  
Organic Matter ◽  
Organic Carbon ◽  
Lake Sediments ◽  
Water Column ◽  
Western Siberia ◽  
Ecosystem Development ◽  
Thermokarst Lake ◽  
Fe And Mn ◽  
The Impact

Abstract. This study reports the very first results on high-resolution sampling of sediments and their porewaters from three thermokarst (thaw) lakes representing different stages of ecosystem development located within the Nadym-Pur interfluve of the Western Siberia plain. Up to present time, the lake sediments of this and other permafrost-affected regions remain unexplored regarding their biogeochemical behavior. The aim of this study was to (i) document the early diagenesic processes in order to assess their impact on the organic carbon stored in the underlying permafrost, and (ii) characterize the post-depositional redistribution of trace elements and their impact on the water column. The estimated organic carbon (OC) stock in thermokarst lake sediments of 14 ± 2 kg m−2 is low compared to that reported for peat soils from the same region and denotes intense organic matter (OM) mineralization. Mineralization of OM in the thermokarst lake sediments proceeds under anoxic conditions in all the three lakes. In the course of the lake development, a shift in mineralization pathways from nitrate and sulfate to Fe- and Mn-oxyhydroxides as the main terminal electron acceptors in the early diagenetic reactions was suggested. This shift was likely promoted by the diagenetic consumption of nitrate and sulfate and their gradual depletion in the water column due to progressively decreasing frozen peat lixiviation occurring at the lake's borders. Trace elements were mobilized from host phases (OM and Fe- and Mn-oxyhydroxides) and partly sequestered in the sediment in the form of authigenic Fe-sulfides. Arsenic and Sb cycling was also closely linked to that of OM and Fe- and Mn-oxyhydroxides. Shallow diagenetic enrichment of particulate Sb was observed in the less mature stages. As a result of authigenic sulfide precipitation, the sediments of the early stage of ecosystem development were a sink for water column Cu, Zn, Cd, Pb and Sb. In contrast, at all stages of ecosystem development, the sediments were a source of dissolved Co, Ni and As to the water column. However, the concentrations of these trace elements remained low in the bottom waters, indicating that sorption processes on Fe-bounding particles and/or large-size organo-mineral colloids could mitigate the impact of post-depositional redistribution of toxic elements on the water column.

scholarly journals Organic matter mineralization and trace element post-depositional redistribution in Western Siberia thermokarst lake sediments

2011 ◽  
Vol 8 (4) ◽  
pp. 8845-8894
Author(s):  
S. Audry ◽  
O. S. Pokrovsky ◽  
L. S. Shirokova ◽  
S. N. Kirpotin ◽  
B. Dupré
Keyword(s):  
Trace Elements ◽  
Organic Matter ◽  
Organic Carbon ◽  
Lake Sediments ◽  
Water Column ◽  
Western Siberia ◽  
Ecosystem Development ◽  
Thermokarst Lake ◽  
Fe And Mn ◽  
The Impact

Abstract. This study reports the very first results on high-resolution sampling of sediments and their porewaters from three thermokarst (thaw) lakes representing different stages of ecosystem development located within the Nadym-Pur interfluve of the Western Siberia plain. Up to present time, the lake sediments of this and other permafrost-affected regions remain unexplored regarding their biogeochemical behavior. The aim of this study was to (i) document the early diagenesic processes in order to assess their impact on the organic carbon stored in the underlying permafrost, and (ii) characterize the post-depositional redistribution of trace elements and their impact on the water column. The estimated organic carbon (OC) stock in thermokarst lake sediments of 14 ± 2 kg m−2 is low compared to that reported for peat soils from the same region and denotes intense organic matter (OM) mineralization. Mineralization of OM in the thermokarst lake sediments proceeds under anoxic conditions in all the three lakes. In the course of the lake development, a shift in mineralization pathways was evidenced from nitrate and sulfate to Fe- and Mn-oxyhydroxides as the main terminal electron acceptors in the early diagenetic reactions. This shift was promoted by the diagenetic consumption of nitrate and sulfate and their gradual depletion in the water column due to progressively decreasing frozen peat lixiviation occurring at the lake's borders. Trace elements were mobilized from host phases (OM and Fe- and Mn-oxyhydroxides) and partly sequestered in the sediment in the form of authigenic Fe-sulfides. Arsenic and Sb cycling was also closely linked to that of OM and Fe- and Mn-oxyhydroxides. Shallow diagenetic enrichment of particulate Sb was observed in the less mature stages. As a result of authigenic sulfide precipitation, the sediments of the early stage of ecosystem development were a sink for water column Cu, Zn, Cd, Pb and Sb. In contrast, at all stages of ecosystem development, the sediments were a source of dissolved Co, Ni and As to the water column. However, the concentrations of these trace elements remained low in the bottom waters, indicating that sorption processes on Fe-bounding particles and/or large-size organo-mineral colloids could mitigate the impact of post-depositional redistribution of toxic elements on the water column.

scholarly journals Seasonal dynamics of organic carbon and metals in thermokarst lakes from the discontinuous permafrost zone of western Siberia

2015 ◽  
Vol 12 (2) ◽  
pp. 1975-2019
Author(s):  
R. M. Manasypov ◽  
S. N. Vorobyev ◽  
S. V. Loiko ◽  
I. V. Kritzkov ◽  
L. S. Shirokova ◽  
...  
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Water Column ◽  
Permafrost Zone ◽  
Ice Formation ◽  
Thermokarst Lakes ◽  
Dissolved Carbon ◽  
Thermokarst Lake ◽  
Discontinuous Permafrost ◽  
Lake Waters

Abstract. Western Siberia's thermokarst (thaw) lakes extend over a territory spanning over a million km2; they are highly dynamic hydrochemical systems that receive chemical elements from the atmosphere and surrounding peat soil and vegetation, and exchange greenhouse gases with the atmosphere, delivering dissolved carbon and metals to adjacent hydrological systems. This work describes the chemical composition of ~ 130 thermokarst lakes of the size range from a few m2 to several km2, located in the discontinuous permafrost zone. Lakes were sampled during spring floods, just after the ice break (early June), the end of summer (August), the beginning of ice formation (October) and during the full freezing season in winter (February). Dissolved organic carbon (DOC) and the major and trace elements do not appreciably change their concentration with the lake size increase above 1000 m2 during all seasons. On the annual scale, the majority of dissolved elements including organic carbon increase their concentration from 30 to 500%, with a statistically significant (p < 0.05) trend from spring to winter. The maximal increase in trace element (TE) concentration occurred between spring and summer and autumn and winter. The ice formation in October included several stages: first, surface layer freezing followed by crack (fissure) formation with unfrozen water from the deeper layers spreading over the ice surface. This water was subsequently frozen and formed layered ice rich in organic matter. As a result, the DOC and metal concentrations were the highest at the beginning of the ice column and decreased from the surface to the depth. A number of elements demonstrated the accumulation, by more than a factor of 2, in the surface (0–20 cm) of the ice column relative to the rest of the ice core: Mn, Fe, Ni, Cu, Zn, As, Ba and Pb. The main consequences of discovered freeze-driven solute concentrations in thermokarst lake waters are enhanced colloidal coagulation and the removal of dissolved organic matter and associated insoluble metals from the water column to the sediments. The measured distribution coefficient of TE between amorphous organo-ferric coagulates and lake water (< 0.45 μm) were similar to those reported earlier for Fe-rich colloids and low molecular weight (< 1 kDa) fractions of thermokarst lake waters, suggesting massive co-precipitation of TE with amorphous Fe oxy(hydr)oxide stabilized by organic matter. Although the concentration of most elements is lowest in spring, this period of maximal water coverage of land creates a significant reservoir of DOC and soluble metals in the water column that can be easily mobilized to the hydrological network. The highest DOC concentration observed in the smallest (< 100 m2) water bodies in spring suggests their strongly heterotrophic status and, therefore, elevated CO2 flux from the lake surface to the atmosphere.

The relationship between sediment and water quality, and riverine sediment loads in the wave-dominated estuaries of south-west Western Australia

2004 ◽  
Vol 55 (6) ◽  
pp. 581 ◽  
Author(s):  
L. C. Radke ◽  
I. P. Prosser ◽  
M. Robb ◽  
B. Brooke ◽  
D. Fredericks ◽  
...  
Keyword(s):  
Water Quality ◽  
Organic Matter ◽  
Soil Erosion ◽  
Organic Carbon ◽  
Water Column ◽  
Nitrogen And Phosphorus ◽  
Weathering Index ◽  
Sediment Loads ◽  
The Impact ◽  
Column Total

We examine surface sediment and water column total nutrient and chlorophyll a concentrations for 12 estuaries with average water depths <4 m, and calculated sediment loads ranging from 0.2 to 10.8 kg m−2 year−1. Sediment total nitrogen, phosphorus and organic carbon concentrations vary inversely with sediment loads due to: (i) the influx of more mineral-rich sediment into the estuaries; and (ii) increasing sediment sulfidation. Sediment total organic carbon (TOC) : total sulfur (TS) and TS : Fe(II) ratios correlated to sediment loads because enhanced sedimentation increases burial, hence the importance of sulfate reduction in organic matter degradation. Curvilinear relationships were found between a weathering index and organic matter δ13C in sediment, and sediment load. The rising phase of the curve (increasing weathering, lighter isotopic values) at low to intermediate loads relates to soil erosion, whereas regolith or bedrock erosion probably explains the declining phase of the curve (decreasing weathering, heavier isotopic values) at higher sediment loads. The pattern of change for water column total nutrients (nitrogen and phosphorus) with sediment loads is similar to that of the weathering index. Most water quality problems occur in association with soil erosion, and at sediment loads that are intermediate for the estuaries studied. Limited evidence is presented that flushing can moderate the impact of sediment loads upon the estuaries.

scholarly journals Seasonal dynamics of organic carbon and metals in thermokarst lakes from the discontinuous permafrost zone of western Siberia

2015 ◽  
Vol 12 (10) ◽  
pp. 3009-3028 ◽  
Author(s):  
R. M. Manasypov ◽  
S. N. Vorobyev ◽  
S. V. Loiko ◽  
I. V. Kritzkov ◽  
L. S. Shirokova ◽  
...  
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Water Column ◽  
Seasonal Dynamics ◽  
Permafrost Zone ◽  
Ice Formation ◽  
Thermokarst Lakes ◽  
Thermokarst Lake ◽  
Discontinuous Permafrost ◽  
Lake Waters

Abstract. Despite relatively good knowledge of the biogeochemistry of Siberian thermokarst lakes during summer base flow, their seasonal dynamics remains almost unexplored. This work describes the chemical composition of ~130 thermokarst lakes ranging in size from a few m2 to several km2, located in the discontinuous permafrost zone. Lakes were sampled during spring flood, just after the ice break (early June), the end of summer (August), the beginning of ice formation (October) and during the full freezing season in winter (February). The lakes larger than 1000 m2 did not exhibit any statistically significant control of the lake size on dissolved organic carbon (DOC), the major and trace element concentrations over three major open water seasons. On the annual scale, the majority of dissolved elements including organic carbon increased their concentration from 30 to 500%, with a statistically significant (p < 0.05) trend from spring to winter. The concentrations of most trace elements (TEs) increased in the order spring > summer > autumn > winter. The ice formation in October included several stages: first, surface layer freezing followed by crack (fissure) formation with unfrozen water from the deeper layers spreading over the ice surface. This water was subsequently frozen and formed layered ice rich in organic matter. As a result, the DOC and metal (Mn, Fe, Ni, Cu, Zn, As, Ba and Pb) concentrations were highest near the surface of the ice column (0 to 20 cm) and decreased by a factor of 2 towards the bottom. The main implications of discovered freeze-driven solute concentrations in thermokarst lake waters are enhanced colloidal coagulation and removal of dissolved organic matter and associated insoluble metals from the water column to the sediments. The measured distribution coefficients of a TE between amorphous organo-ferric coagulates and lake water (<0.45 μm) were similar to those reported earlier for Fe-rich colloids and low molecular weight (<1 kDa, or <1–2 nm) fractions of thermokarst lake waters, suggesting massive co-precipitation of TE with amorphous Fe oxyhydroxide stabilized by organic matter. Although the concentration of most elements was lowest in spring, this period of maximal water coverage of land created a significant reservoir of DOC and soluble metals in the water column that can be easily mobilized to the hydrological network. The highest DOC concentration observed in the smallest (<100 m2) water bodies in spring suggests their strongly heterotrophic status and, therefore, a potentially elevated CO2 flux from the lake surface to the atmosphere.

scholarly journals Traces of sunlight in the organic matter biogeochemistry of two shallow subarctic lakes

2021 ◽  
Author(s):  
Marttiina V. Rantala ◽  
Carsten Meyer-Jacob ◽  
E. Henriikka Kivilä ◽  
Tomi P. Luoto ◽  
Antti. E. K. Ojala ◽  
...  
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Lake Sediments ◽  
Lake Water ◽  
Human Impacts ◽  
Global Environmental Change ◽  
Carbon Export ◽  
Subarctic Lakes ◽  
Carbon Regulation ◽  
In Situ Experiments

AbstractGlobal environmental change alters the production, terrestrial export, and photodegradation of organic carbon in northern lakes. Sedimentary biogeochemical records can provide a unique means to understand the nature of these changes over long time scales, where observational data fall short. We deployed in situ experiments on two shallow subarctic lakes with contrasting light regimes; a clear tundra lake and a dark woodland lake, to first investigate the photochemical transformation of carbon and nitrogen elemental (C/N ratio) and isotope (δ13C, δ15N) composition in lake water particulate organic matter (POM) for downcore inferences. We then explored elemental, isotopic, and spectral (inferred lake water total organic carbon [TOC] and sediment chlorophyll a [CHLa]) fingerprints in the lake sediments to trace changes in aquatic production, terrestrial inputs and photodegradation before and after profound human impacts on the global carbon cycle prompted by industrialization. POM pool in both lakes displayed tentative evidence of UV photoreactivity, reflected as increasing δ13C and decreasing C/N values. Through time, the tundra lake sediments traced subtle shifts in primary production, while the woodland lake carried signals of changing terrestrial contributions, indicating shifts in terrestrial carbon export but possibly also photodegradation rates. Under global human impact, both lakes irrespective of their distinct carbon regimes displayed evidence of increased productivity but no conspicuous signs of increased terrestrial influence. Overall, sediment biogeochemistry can integrate a wealth of information on carbon regulation in northern lakes, while our results also point to the importance of considering the entire spectrum of photobiogeochemical fingerprints in sedimentary studies.

Biogeochemical and ecological features of sinking particulate matter in the deep Ionian Sea (E. Mediterranean) during a 10-year time series study: impacts of atmospheric and oceanographic variabilities on carbon production and sequestration

2021 ◽  
Author(s):  
Alexandra Gogou ◽  
Constantine Parinos ◽  
Spyros Stavrakakis ◽  
Emmanouil Proestakis ◽  
Maria Kanakidou ◽  
...  
Keyword(s):  
Particulate Matter ◽  
Organic Carbon ◽  
Carbon Cycle ◽  
Atmospheric Deposition ◽  
Water Column ◽  
Particulate Organic Carbon ◽  
Nutrient Dynamics ◽  
Ionian Sea ◽  
Ecological Features ◽  
The Impact

&lt;p&gt;Biotic and abiotic processes that form, alter, transport, and remineralize particulate organic carbon, silicon, calcium carbonate, and other minor and trace chemical species in the water column are central to the ocean&amp;#8217;s ecological and biogeochemical functioning and of fundamental importance to the ocean carbon cycle. Sinking particulate matter is the major vehicle for exporting carbon from the sea surface to the deep sea. During its transit towards the sea floor, most particulate organic carbon (POC) is returned to inorganic form and redistributed in the water column. This redistribution determines the surface concentration of dissolved CO&lt;sub&gt;2&lt;/sub&gt;, and hence the rate at which the ocean can absorb CO&lt;sub&gt;2&lt;/sub&gt; from the atmosphere. The ability to predict quantitatively the depth profile of remineralization is therefore critical to deciphering the response of the global carbon cycle to natural and human-induced changes.&lt;/p&gt;&lt;p&gt;Aiming to investigate the significant biogeochemical and ecological features and provide new insights on the sources and cycles of sinking particulate matter, a mooring line of five sediment traps was deployed from 2006 to 2015 (with some gap periods) at 5 successive water column depths (700, 1200, 2000, 3200 and 4300 m) in the SE Ionian Sea, northeastern Mediterranean (&amp;#8216;NESTOR&amp;#8217; site). We have examined the long-term records of downward fluxes for Corg, N&lt;sub&gt;tot&lt;/sub&gt;, &amp;#948;&lt;sup&gt;13&lt;/sup&gt;Corg and &amp;#948;&lt;sup&gt;15&lt;/sup&gt;N&lt;sub&gt;tot&lt;/sub&gt;, along with the associated ballast minerals (opal, lithogenics and CaCO&lt;sub&gt;3&lt;/sub&gt;), lipid biomarkers, Chl-a and PP rates, phytoplankton composition, nutrient dynamics and atmospheric deposition. &amp;#160;&lt;/p&gt;&lt;p&gt;The satellite-derived seasonal and interannual variability of phytoplankton metrics (biomass and phenology) and atmospheric deposition (meteorology and air masses origin) was examined for the period of the sediment trap experiment. Regarding the atmospheric deposition, synergistic opportunities using Earth Observation satellite lidar and radiometer systems are proposed (e.g. Cloud&amp;#8208;Aerosol Lidar with Orthogonal Polarization - CALIOP, Moderate Resolution Imaging Spectroradiometer - MODIS), aiming towards a four&amp;#8208;dimensional exploitation of atmospheric aerosol loading (e.g. Dust Optical Depth) in the study area.&lt;/p&gt;&lt;p&gt;Our main goals are to: i) develop a comprehensive knowledge of carbon fluxes and associated mineral ballast fluxes from the epipelagic to the mesopelagic and bathypelagic layers, ii) elucidate the mechanisms governing marine productivity and carbon export and sequestration to depth and iii) shed light on the impact of atmospheric forcing and deposition in respect to regional and large scale circulation patterns and climate variability and the prevailing oceanographic processes (internal variability).&lt;/p&gt;&lt;p&gt;Acknowledgments&lt;/p&gt;&lt;p&gt;We acknowledge support of this work by the Action &amp;#8216;National Network on Climate Change and its Impacts &amp;#8211; &lt;strong&gt;CLIMPACT&lt;/strong&gt;&amp;#8217;, funded by the Public Investment Program of Greece (GSRT, Ministry of Development and Investments).&lt;/p&gt;

scholarly journals Chemical characterization of fine particular matter in Changzhou, China and source apportionment with offline aerosol mass spectrometry

2016 ◽  
Author(s):  
Zhaolian Ye ◽  
Jiashu Liu ◽  
Aijun Gu ◽  
Feifei Feng ◽  
Yuhai Liu ◽  
...  
Keyword(s):  
Trace Elements ◽  
Organic Matter ◽  
Organic Carbon ◽  
Source Apportionment ◽  
Major Ions ◽  
Chemical Properties ◽  
Chemical Characterization ◽  
Water Soluble ◽  
Traffic Emissions ◽  
Aerosol Mass

Abstract. Knowledge on aerosol chemistry in densely populated regions is critical for reduction of air pollution, while such studies haven't been conducted in Changzhou, an important manufacturing base and polluted city in the Yangtze River Delta (YRD), China. This work, for the first time, performed a thorough chemical characterization on the fine particular matter (PM2.5) samples, collected during July 2015 to April 2016 across four seasons in Changzhou city. A suite of analytical techniques were employed to characterize organic carbon / elemental carbon (OC / EC), water-soluble organic carbon (WSOC), water-soluble inorganic ions (WSIIs), trace elements, and polycyclic aromatic hydrocarbons (PAHs) in PM2.5; in particular, an Aerodyne soot particle aerosol mass spectrometer (SP-AMS) was deployed to probe the chemical properties of water-soluble organic aerosols (WSOA). The average PM2.5 concentrations were found to be 108.3 μg m−3, and all identified species were able to reconstruct ~ 80 % of the PM2.5 mass. The WSIIs occupied about half of the PM2.5 mass (~ 52.1 %), with SO42−, NO3− and NH4+ as the major ions. On average, nitrate concentrations dominated over sulfate (mass ratio of 1.21), indicating influences from traffic emissions. OC and EC correlated well with each other and the highest OC / EC ratio (5.16) occurred in winter, suggesting complex OC sources likely including both secondarily formed and primarily emitted OA. Concentrations of eight trace elements (Mn, Zn, Al, B, Cr, Cu, Fe, Pb) can contribute up to 6.0 % of PM2.5 during winter. PAHs concentrations were also high in winter (140.25 ng m−3), which were predominated by median/high molecular weight PAHs with 5- and 6-rings. The organic matter including both water-soluble and water-insoluble species occupied ~ 20 % PM2.5 mass. SP-AMS determined that the WSOA had an average atomic oxygen-to-carbon (O / C), hydrogen-to-carbon (H / C), nitrogen-to-carbon (N / C) and organic matter-to-organic carbon (OM / OC) ratios of 0.36, 1.54, 0.11, and 1.74, respectively. Source apportionment of WSOA further identified two secondary OA (SOA) factors (a less oxidized and a more oxidized OA) and two primary OA (POA) factors (a nitrogen enriched hydrocarbon-like traffic OA and a cooking-related OA). On average, the POA contribution overweighed SOA (55 % vs. 45 %), indicating the important role of local anthropogenic emissions to the aerosol pollution in Changzhou. Our measurement also shows the abundance of organic nitrogen species in WSOA, and the source analyses suggest these species likely associated with traffic emissions, which warrants more investigations on PM samples from other locations.

Biogeochemistry of organic carbon, CO2, CH4, and trace elements in thermokarst water bodies in discontinuous permafrost zones of Western Siberia

2012 ◽  
Vol 113 (1-3) ◽  
pp. 573-593 ◽  
Author(s):  
L. S. Shirokova ◽  
O. S. Pokrovsky ◽  
S. N. Kirpotin ◽  
C. Desmukh ◽  
B. G. Pokrovsky ◽  
...  
Keyword(s):  
Trace Elements ◽  
Organic Carbon ◽  
Western Siberia ◽  
Water Bodies ◽  
Discontinuous Permafrost

scholarly journals Dissolved organic carbon and major and trace elements in peat porewater of sporadic, discontinuous, and continuous permafrost zones of western Siberia

2017 ◽  
Vol 14 (14) ◽  
pp. 3561-3584 ◽  
Author(s):  
Tatiana V. Raudina ◽  
Sergey V. Loiko ◽  
Artyom G. Lim ◽  
Ivan V. Krickov ◽  
Liudmila S. Shirokova ◽  
...  
Keyword(s):  
Trace Elements ◽  
Organic Carbon ◽  
Western Siberia ◽  
Peat Soil ◽  
Major And Trace Elements ◽  
Permafrost Zone ◽  
Discontinuous Permafrost ◽  
Latitudinal Transect ◽  
Soil Solutions ◽  
Continuous Permafrost

Abstract. Mobilization of dissolved organic carbon (DOC) and related trace elements (TEs) from the frozen peat to surface waters in the permafrost zone is expected to enhance under ongoing permafrost thaw and active layer thickness (ALT) deepening in high-latitude regions. The interstitial soil solutions are efficient tracers of ongoing bio-geochemical processes in the critical zone and can help to decipher the intensity of carbon and metals migration from the soil to the rivers and further to the ocean. To this end, we collected, across a 640 km latitudinal transect of the sporadic to continuous permafrost zone of western Siberia peatlands, soil porewaters from 30 cm depth using suction cups and we analyzed DOC, dissolved inorganic carbon (DIC), and 40 major elements and TEs in 0.45 µm filtered fraction of 80 soil porewaters. Despite an expected decrease in the intensity of DOC and TE mobilization from the soil and vegetation litter to the interstitial fluids with the increase in the permafrost coverage and a decrease in the annual temperature and ALT, the DOC and many major and trace elements did not exhibit any distinct decrease in concentration along the latitudinal transect from 62.2 to 67.4° N. The DOC demonstrated a maximum of concentration at 66° N, on the border of the discontinuous/continuous permafrost zone, whereas the DOC concentration in peat soil solutions from the continuous permafrost zone was equal to or higher than that in the sporadic/discontinuous permafrost zone. Moreover, a number of major (Ca, Mg) and trace (Al, Ti, Sr, Ga, rare earth elements (REEs), Zr, Hf, Th) elements exhibited an increasing, not decreasing, northward concentration trend. We hypothesize that the effects of temperature and thickness of the ALT are of secondary importance relative to the leaching capacity of peat, which is in turn controlled by the water saturation of the peat core. The water residence time in peat pores also plays a role in enriching the fluids in some elements: the DOC, V, Cu, Pb, REEs, and Th were a factor of 1.5 to 2.0 higher in mounds relative to hollows. As such, it is possible that the time of reaction between the peat and downward infiltrating waters essentially controls the degree of peat porewater enrichments in DOC and other solutes. A 2° northward shift in the position of the permafrost boundaries may bring about a factor of 1.3 ± 0.2 decrease in Ca, Mg, Sr, Al, Fe, Ti, Mn, Ni, Co, V, Zr, Hf, Th, and REE porewater concentration in continuous and discontinuous permafrost zones, and a possible decrease in DOC, specific ultraviolet absorbency (SUVA), Ca, Mg, Fe, and Sr will not exceed 20 % of their current values. The projected increase in ALT and vegetation density, northward migration of the permafrost boundary, or the change of hydrological regime is unlikely to modify chemical composition of peat porewater fluids larger than their natural variations within different micro-landscapes, i.e., within a factor of 2. The decrease in DOC and metal delivery to small rivers and lakes by peat soil leachate may also decrease the overall export of dissolved components from the continuous permafrost zone to the Arctic Ocean. This challenges the current paradigm on the increase in DOC export from the land to the ocean under climate warming in high latitudes.

scholarly journals Soil aggregation and organic carbon of Oxisols under coffee in agroforestry systems

2014 ◽  
Vol 38 (1) ◽  
pp. 278-287 ◽  
Author(s):  
Gabriel Pinto Guimarães ◽  
Eduardo de Sá Mendonça ◽  
Renato Ribeiro Passos ◽  
Felipe Vaz Andrade
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Soil Aggregation ◽  
Root Penetration ◽  
Conventional System ◽  
Physical Quality ◽  
Soil Physical Quality ◽  
Organic Coffee ◽  
On Farm ◽  
The Impact

Intensive land use can lead to a loss of soil physical quality with negative impacts on soil aggregates, resistance to root penetration, porosity, and bulk density. Organic and agroforestry management systems can represent sustainable, well-balanced alternatives in the agroecosystem for promoting a greater input of organic matter than the conventional system. Based on the hypothesis that an increased input of organic matter improves soil physical quality, this study aimed to evaluate the impact of coffee production systems on soil physical properties in two Red-Yellow Oxisols (Latossolos Vermelho-Amarelos) in the region of Caparaó, Espirito Santo, Brazil. On Farm 1, we evaluated the following systems: primary forest (Pf1), organic coffee (Org1) and conventional coffee (Con1). On Farm 2, we evaluated: secondary forest (Sf2), organic coffee intercropped with inga (Org/In2), organic coffee intercropped with leucaena and inga (Org/In/Le2), organic coffee intercropped with cedar (Org/Ced2) and unshaded conventional coffee (Con2). Soil samples were collected under the tree canopy from the 0-10, 10-20 and 20-40 cm soil layers. Under organic and agroforestry coffee management, soil aggregation was higher than under conventional coffee. In the agroforestry system, the degree of soil flocculation was 24 % higher, soil moisture was 80 % higher, and soil resistance to penetration was lower than in soil under conventional coffee management. The macroaggregates in the organic systems, Org/In2, Org/In/Le2, and Org/Ced2 contained, on average, 29.1, 40.1 and 34.7 g kg-1 organic carbon, respectively. These levels are higher than those found in the unshaded conventional system (Con2), with 20.2 g kg-1.

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