Long-lived zircon growth in trapped eclogite

Author(s):  
Martin Hand ◽  
Renee Tamblyn ◽  
Diana Zivak ◽  
Tom Raimondo

<p>The residence time of rocks within subduction channels provides a narrative on the physical processes that reflect the interplay between subduction rate and angle, coupling between the lower and upper plate and hydration of the mantle wedge.  In oceanic subduction systems, it is now recognised that rocks can reside within subduction channels for 10’s of millions of years.   These apparently long-lived durations of entrainment in the subduction channel probably require circulatory motions that recover material from terminal subduction and simple one-cycle exhumation.  In turn, these residence times can plausibly be used to deduce geodynamic variables that control the subduction system.</p><p>Establishing the duration a rock has been stored within a subduction environment typically requires application of multi-mineral geochronology coupled with considerations of closure systematics.  However because subduction environments are commonly fluid-rich, a mineral with great potential to reveal durations rocks can reside within subduction channels is zircon.  In subduction environments, several studies have documented apparently long-lived records of zircon growth, but seemingly have not recognised the potential for zircon to extract information on the duration a rock experienced subduction channel metamorphism.</p><p>Lawsonite-bearing eclogite in eastern Australia has a remarkable microstructural record of zircon growth.  Thin section-scale 1-3 micron resolution synchrotron mapping by X-ray Fluorescence (XFM) reveals the presence of 1000’s of micron-sized zircons which occasionally range up to 15 microns in size.  Zircon: (1) defines inclusion trails in garnets, (2) is a foliation defining matrix mineral and (3) occurs in retrograde chlorite-bearing veins that formed during post-eclogite blueschist paragenesis.   In-situ U-Pb geochronology shows that zircon growth occurred over the interval c. 520-400 Ma.  The zircons have hydrothermal characteristics with elevated LREE and simple tetragonal morphologies.  The apparently long duration of zircon growth is generally consistent with other geochronology from the eclogite: garnet Sm-Nd and Lu-Hf ages between 530-490 Ma, matrix foliation titanite U-Pb c. 450 Ma, and matrix foliation phengite Ar-Ar and Rb-Sr ages of 460-450 Ma.   </p><p>The small size of the zircons means they cannot be readily extracted using bulk rock methods.  Instead, fast, high-resolution imaging methods such as synchrotron XFM mapping coupled with spatially precise U-Pb-trace element analysis reveal a long history of HFSE element mobility resulting in microstructurally organised zircon growth that allows rock residence time in a subduction channel to be determined.</p><p>If lawsonite eclogite from eastern Australia records more than 100 Ma of zircon growth at eclogite-blueschist facies conditions, the single eclogite sample reflects around 5000-7000 km of consumption of the palaeo-pacific plate under the east Gondwana margin while remaining trapped in the subduction channel.</p>

2013 ◽  
Vol 10 (3) ◽  
pp. 286-292

The trace element analysis of Aleppo pine (Pinus halepensis Mill) as a function of tree age, was achieved by the tree-ring sampling method, in a polluted region of Attica, Greece. The elements quantitatively determined for the last 140 years by atomic spectrophotometry analysis were: Cu, Fe, Zn, Mn and Pb. With the exception of Pb, all other elements tend to increase for the time period of this study. A very interesting fluctuation was noted between the years 1920 to 1960-1970, a time coinciding with the major industrial activity of the area. The decreasing concentration of all elements for the last few decades may be attributed to the increasing environmental awareness as well as respective regulations posed by the government and the E.U. The radial distribution of concentrations in annual tree rings provides adequate information that, in most of the cases, can be related to the history of the tree and the biological processes interacting on its growth. Soil, litter, air deposits and water are important nutrient sources contributing to changes in elemental concentration in the annual rings.


1992 ◽  
Vol 02 (01) ◽  
pp. 1-18 ◽  
Author(s):  
V. VALKOVIC

Hair is the unique biological material which, because of its growth, reflects the biomedical and environmental history of the subject. Because of convenience in handling and sampling and relatively high concentrations of metals, trace-element analysis of human hair has been applied widely for different purposes. Although even the measurements of the bulk trace element levels contain some information, the real meaning is contained in longitudinal and radial concentration profiles. This is best achievable by X-ray emission spectroscopy measurements.


Author(s):  
John J. Donovan ◽  
Donald A. Snyder ◽  
Mark L. Rivers

We present a simple expression for the quantitative treatment of interference corrections in x-ray analysis. WDS electron probe analysis of standard reference materials illustrate the success of the technique.For the analytical line of wavelength λ of any element A which lies near or on any characteristic line of another element B, the observed x-ray counts at We use to denote x-ray counts excited by element i in matrix j (u=unknown; s=analytical standard; ŝ=interference standard) at the wavelength of the analytical line of A, λA (Fig. 1). Quantitative analysis of A requires an accurate estimate of These counts can be estimated from the ZAF calculated concentration of B in the unknown C,Bu measured counts at λA in an interference standard of known concentration of B (and containing no A), and ZAF correction parameters for the matrices of both the unknown and the interference standard at It can be shown that:


2019 ◽  
Vol 608 ◽  
pp. 247-262 ◽  
Author(s):  
MD Ramirez ◽  
JA Miller ◽  
E Parks ◽  
L Avens ◽  
LR Goshe ◽  
...  

Author(s):  
Yasunori Goto ◽  
Hiroomi Eguchi ◽  
Masaru Iida

Abstract In the automotive IC using thick-film silicon on insulator (SOI) semiconductor device, if the gettering capability of a SOI wafer is inadequate, electrical characteristics degradation by metal contamination arises and the yield falls. At this time, an automotive IC was made experimentally for evaluation of the gettering capability as one of the purposes. In this IC, one of the output characteristics varied from the standard, therefore failure analysis was performed, which found trace metal elements as one of the causes. By making full use of 3D perspective, it is possible to fabricate a site-specific sample into 0.1 micrometre in thickness without missing a failure point that has very minute quantities of contaminant in a semiconductor device. Using energy dispersive X-ray, it is possible to detect trace metal contamination at levels 1E12 atoms per sq cm. that are conventionally detected only by trace element analysis.


Author(s):  
Daniel Araujo Goncalves ◽  
Tina McSweeney ◽  
Mirian Cristina dos Santos ◽  
Marco A. Utrera Martines ◽  
Luiz Francisco Malmonge ◽  
...  

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