Micronutrient export from glacier to fjord, southwest Greenland: potential impacts on open ocean primary productivity

Author(s):  
Rachael Ward ◽  
Kathrine Hendry ◽  
Jemma L. Wadham ◽  
Jon R. Hawkings ◽  
Robert M. Sherrell ◽  
...  

<p>The accelerated melting of the Greenland Ice Sheet could potentially enhance fluxes of key nutrients, to the surrounding oceans, impacting marine biogeochemical processes and ecosystems. Iron (Fe) is one key micronutrient for marine phytoplankton that may be affected by this increase in meltwater flux, with high export of dissolved and particulate Fe from glacial meltwaters into fjords and a potentially significant increase in the supply of labile and potentially bioavailable Fe to the Greenlandic shelf. However, biogeochemical processing within estuarine-like fjord systems may result in depletion of nutrients, acting as a sink of micronutrients before they can reach the coastal ocean. The extent to which glacially derived micronutrients, specifically Fe, reach coastal waters remains an unanswered question.</p><p>Here, we address this question by assessing the concentration of dissolved (<0.45 µm) and labile particulate (determined using the Berger leach) bio-essential trace metals (Fe, Cd, Mn, Ni, Cu, Zn) in two contrasting glaciated fjords in southwest Greenland; one fed predominantly by marine terminating glaciers and the other by a land terminating glacier. We investigate the difference in size fractionated concentrations between fjords and the transport of these metals from stations close to glacial termini down to the fjord mouths. Our findings reveal that each micronutrient exhibits a distinctive behaviour, with some metals enhanced in meltwaters (e.g. dissolved Fe and Mn) and some depleted (e.g. dissolved Cd), relative to marine waters. The spatial variability in our dataset highlights that concentration of Fe and other trace metals (Cd, Mn, Ni, Cu, Zn) enriched in meltwaters become depleted towards the mouth of the fjords, with non-conservative loss from surface waters. Despite this depletion, the concentrations of these metals in waters that reach the coastal zone are significantly higher than typical surface ocean values, both in dissolved and labile particulate form. These data can ultimately be used in combination with a physical understanding of the fjord systems to constrain the capacity of fjords to enhance productivity downstream and deliver micronutrients into coastal and open ocean systems. Furthermore, the direct comparison of land- and marine-terminating glacial fjords could provide valuable information on the potential future impact of retreating glacial systems with enhanced melting.</p>

Author(s):  
F. A. J. Armstrong ◽  
G. T. Boalch

SUMMARYMeasurements of the ultra-violet absorption spectra between 200 and 400 mix, have been made with a spectrophotometer. At short wave-lengths natural sea water has double the absorbancy of artificial sea water. The difference in samples from shallow depths is ascribed to organic material, of which part may be the Gelbstoff of Kalle. Regional variations have been found, coastal waters having higher U.V. absorptions. A small seasonal effect with an increase in absorbancy in summer in the English Channel has been seen. In deep Atlantic water increased absorption below 235 m/x may be due to its high nitrate concentration. At longer wave-lengths absorbancies were less than in surface waters. Measurements of U.V. absorption may supplement other physical methods of characterizing water masses.


2020 ◽  
Author(s):  
Peter Landschützer ◽  
Goulven G. Laruelle ◽  
Alizee Roobaert ◽  
Pierre Regnier

Abstract. In this study, we present the first combined open and coastal ocean pCO2 mapped monthly climatology (Landschützer et al. (2020), doi:10.25921/qb25-f418, https://www.nodc.noaa.gov/ocads/oceans/MPI-ULB-SOM_FFN_clim.html) constructed from observations collected between 1998 and 2015 extracted from the Surface Ocean CO2 Atlas (SOCAT) database. We combine two neural network-based pCO2 products, one from the open ocean and the other from the coastal ocean, and investigate their consistency along their common overlap areas. While the difference between open and coastal ocean estimates along the overlap area increases with latitude, it remains close to 0 μatm globally. Stronger discrepancies, however, exist on the regional level resulting in differences that exceed 10 % of the climatological mean pCO2, or an order of magnitude larger than the uncertainty from state of the art measurements. This also illustrates the potential of such analysis to inform the measurement community about the locations where additional measurements are essential to better represent the aquatic continuum and improve our understanding of the carbon exchange at the air water interface. A regional analysis further shows that the seasonal carbon dynamics at the coast-open interface are well represented in our climatology. While our combined product is only a first step towards a true representation of both the open ocean and the coastal ocean air-sea CO2 flux in marine carbon budgets, we show it is a feasible task and the present data product already constitutes a valuable tool to investigate and quantify the dynamics of the air-sea CO2 exchange consistently for oceanic regions regardless of its distance to the coast.


Author(s):  
James S. Webber

INTRODUCTION“Acid rain” and “acid deposition” are terms no longer confined to the lexicon of atmospheric scientists and 1imnologists. Public awareness of and concern over this phenomenon, particularly as it affects acid-sensitive regions of North America, have increased dramatically in the last five years. Temperate ecosystems are suffering from decreased pH caused by acid deposition. Human health may be directly affected by respirable sulfates and by the increased solubility of toxic trace metals in acidified waters. Even man's monuments are deteriorating as airborne acids etch metal and stone features.Sulfates account for about two thirds of airborne acids with wet and dry deposition contributing equally to acids reaching surface waters or ground. The industrial Midwest is widely assumed to be the source of most sulfates reaching the acid-sensitive Northeast since S02 emitted as a byproduct of coal combustion in the Midwest dwarfs S02 emitted from all sources in the Northeast.


2017 ◽  
Vol 14 (19) ◽  
pp. 4545-4561 ◽  
Author(s):  
Goulven G. Laruelle ◽  
Peter Landschützer ◽  
Nicolas Gruber ◽  
Jean-Louis Tison ◽  
Bruno Delille ◽  
...  

Abstract. In spite of the recent strong increase in the number of measurements of the partial pressure of CO2 in the surface ocean (pCO2), the air–sea CO2 balance of the continental shelf seas remains poorly quantified. This is a consequence of these regions remaining strongly under-sampled in both time and space and of surface pCO2 exhibiting much higher temporal and spatial variability in these regions compared to the open ocean. Here, we use a modified version of a two-step artificial neural network method (SOM-FFN; Landschützer et al., 2013) to interpolate the pCO2 data along the continental margins with a spatial resolution of 0.25° and with monthly resolution from 1998 to 2015. The most important modifications compared to the original SOM-FFN method are (i) the much higher spatial resolution and (ii) the inclusion of sea ice and wind speed as predictors of pCO2. The SOM-FFN is first trained with pCO2 measurements extracted from the SOCATv4 database. Then, the validity of our interpolation, in both space and time, is assessed by comparing the generated pCO2 field with independent data extracted from the LDVEO2015 database. The new coastal pCO2 product confirms a previously suggested general meridional trend of the annual mean pCO2 in all the continental shelves with high values in the tropics and dropping to values beneath those of the atmosphere at higher latitudes. The monthly resolution of our data product permits us to reveal significant differences in the seasonality of pCO2 across the ocean basins. The shelves of the western and northern Pacific, as well as the shelves in the temperate northern Atlantic, display particularly pronounced seasonal variations in pCO2,  while the shelves in the southeastern Atlantic and in the southern Pacific reveal a much smaller seasonality. The calculation of temperature normalized pCO2 for several latitudes in different oceanic basins confirms that the seasonality in shelf pCO2 cannot solely be explained by temperature-induced changes in solubility but are also the result of seasonal changes in circulation, mixing and biological productivity. Our results also reveal that the amplitudes of both thermal and nonthermal seasonal variations in pCO2 are significantly larger at high latitudes. Finally, because this product's spatial extent includes parts of the open ocean as well, it can be readily merged with existing global open-ocean products to produce a true global perspective of the spatial and temporal variability of surface ocean pCO2.


2000 ◽  
Vol 12 (4) ◽  
pp. 414-417 ◽  
Author(s):  
Harvey Marchant ◽  
Andrew Davidson ◽  
Simon Wright ◽  
John Glazebrook

The concentrations of viruses, bacteria, chroococcoid cyanobacteria and chlorophyll a were determined in surface waters of the Southern Ocean during spring. Viral concentrations declined southward from around 4 × 106 ml−1 near Tasmania to a minimum of around 1 × 106 ml−1 at the Polar Front. South of the Front, virus concentrations increased again, reaching around 4 × 106 ml−1 in the sea-ice zone south of 60°S. Bacterial concentration decreased southwards across the Southern Ocean from around 6.5 × 105 ml−1 near Tasmania to < 1.0 × 105 ml−1 in the sea-ice zone. Cyanobacteria accounted for < 8% of the prokaryotes. There was no significant relationship between viral abundance and eithercyanobacterial or chl a concentration. Viral and bacterial concentrations were not significantly correlated north (P {0.10 < r < 0.20}) or south (P {0.20 < r < 0.5}) of the Polar Front. The virus to bacteria ratio (VBR) was between 3 and 15 in the open ocean but varied between 15 and 40 in the sea-ice region. These virus concentrations and VBRs indicate that viruses are no less important in Southern Ocean ecosystems than elsewhere in the world's oceans.


2019 ◽  
Vol 59 (6) ◽  
pp. 928-938
Author(s):  
E. O. Dubinina ◽  
S. A. Kossova ◽  
A. Yu. Miroshnikov

Three-year monitoring of isotope (D, 18О) parameters in the waters of the Sedov and Tsivolki bays (Novaya Zemlya) was carried out. The fresh waters of the bays are originated from several sources (continental runoff, precipitations, and waters going from the archipelago). The freshening extent and sources of fresh waters are different at the different depth. The D and 18О values varies only in the surface waters which contains more than 30% of fresh component. In 2015 the surface waters of Sedov bay were represented by Ob river waters, and the surface waters of Tsivolki bay were enriched by the runoff from Novaya Zemlya. Deep waters in both bays show signs of desalination by high latitude atmospheric precipitations. These waters can be transferred to the southeast coast of Novaya Zemlya through the trenches of St. Anne and Voronin. The difference in the freshening mechanisms of the waters of Sedov and Tsivolka bays is determined by different bottom morphologies and different degrees of free water exchange with the Kara Sea.


2021 ◽  
Vol 13 (7) ◽  
pp. 3491-3512
Author(s):  
Anne Solgaard ◽  
Anders Kusk ◽  
John Peter Merryman Boncori ◽  
Jørgen Dall ◽  
Kenneth D. Mankoff ◽  
...  

Abstract. We present the Programme for Monitoring of the Greenland Ice Sheet (PROMICE) Ice Velocity product (https://doi.org/10.22008/promice/data/sentinel1icevelocity/greenlandicesheet, Solgaard and Kusk, 2021), which is a time series of Greenland Ice Sheet ice velocity mosaics spanning September 2016 through to the present. The product is based on Sentinel-1 synthetic aperture radar data and has a 500 m grid spacing. A new mosaic is available every 12 d and spans two consecutive Sentinel-1 cycles (24 d). The product is made available within ∼ 10 d of the last acquisition and includes all possible 6 and 12 d pairs within the two Sentinel-1A cycles. We describe our operational processing chain from data selection, mosaicking, and error estimation to final outlier removal. The product is validated against in situ GPS measurements. We find that the standard deviation of the difference between satellite- and GPS-derived velocities (and bias) is 20 m yr−1 (−3 m yr−1) and 27 m yr−1 (−2 m yr−1) for the components in an eastern and northern direction, respectively. Over stable ground the values are 8 m yr−1 (0.1 m yr−1) and 12 m yr−1 (−0.6 m yr−1) in an eastern and northern direction, respectively. This is within the expected values; however, we expect that the GPS measurements carry a considerable part of this uncertainty. We investigate variations in coverage from both a temporal and spatial perspective. The best spatial coverage is achieved in winter due to the comprehensive data coverage by Sentinel-1 and high coherence, while summer mosaics have the lowest coverage due to widespread melt. The southeast Greenland Ice Sheet margin, along with other areas of high accumulation and melt, often has gaps in the ice velocity mosaics. The spatial comprehensiveness and temporal consistency make the product ideal both for monitoring and for studying ice-sheet-wide and glacier-specific ice discharge and dynamics of glaciers on seasonal scales.


Sign in / Sign up

Export Citation Format

Share Document