scholarly journals Sources and mechanisms of seawater freshening at the Tsivol’ki and Sedov’ bays (Novaya Zemlya): isotope (δD, δ18О) data

2019 ◽  
Vol 59 (6) ◽  
pp. 928-938
Author(s):  
E. O. Dubinina ◽  
S. A. Kossova ◽  
A. Yu. Miroshnikov
Keyword(s):  
Surface Waters ◽  
Water Exchange ◽  
Free Water ◽  
Kara Sea ◽  
River Waters ◽  
Fresh Waters ◽  
Novaya Zemlya ◽  
Deep Waters ◽  
Continental Runoff ◽  
The Difference

Three-year monitoring of isotope (D, 18О) parameters in the waters of the Sedov and Tsivolki bays (Novaya Zemlya) was carried out. The fresh waters of the bays are originated from several sources (continental runoff, precipitations, and waters going from the archipelago). The freshening extent and sources of fresh waters are different at the different depth. The D and 18О values varies only in the surface waters which contains more than 30% of fresh component. In 2015 the surface waters of Sedov bay were represented by Ob river waters, and the surface waters of Tsivolki bay were enriched by the runoff from Novaya Zemlya. Deep waters in both bays show signs of desalination by high latitude atmospheric precipitations. These waters can be transferred to the southeast coast of Novaya Zemlya through the trenches of St. Anne and Voronin. The difference in the freshening mechanisms of the waters of Sedov and Tsivolka bays is determined by different bottom morphologies and different degrees of free water exchange with the Kara Sea.

scholarly journals Target screening of plant secondary metabolites in river waters by liquid chromatography coupled to high-resolution mass spectrometry (LC–HRMS)

2020 ◽  
Vol 32 (1) ◽  
Author(s):  
Mulatu Yohannes Nanusha ◽  
Martin Krauss ◽  
Carina D. Schönsee ◽  
Barbara F. Günthardt ◽  
Thomas D. Bucheli ◽  
...  
Keyword(s):  
Secondary Metabolites ◽  
Surface Waters ◽  
High Resolution Mass Spectrometry ◽  
Water Cycle ◽  
Endocrine Disrupting Chemicals ◽  
Plant Secondary Metabolites ◽  
Biologically Active ◽  
Plant Metabolites ◽  
River Waters ◽  
Target Screening

Abstract Background Substantial efforts have been made to monitor potentially hazardous anthropogenic contaminants in surface waters while for plant secondary metabolites (PSMs) almost no data on occurrence in the water cycle are available. These metabolites enter river waters through various pathways such as leaching, surface run-off and rain sewers or input of litter from vegetation and might add to the biological activity of the chemical mixture. To reduce this data gap, we conducted a LC–HRMS target screening in river waters from two different catchments for 150 plant metabolites which were selected from a larger database considering their expected abundance in the vegetation, their potential mobility, persistence and toxicity in the water cycle and commercial availability of standards. Results The screening revealed the presence of 12 out of 150 possibly toxic PSMs including coumarins (bergapten, scopoletin, fraxidin, esculetin and psoralen), a flavonoid (formononetin) and alkaloids (lycorine and narciclasine). The compounds narciclasine and lycorine were detected at concentrations up to 3 µg/L while esculetin and fraxidin occurred at concentrations above 1 µg/L. Nine compounds occurred at concentrations above 0.1 µg/L, the Threshold for Toxicological Concern (TTC) for non-genotoxic and non-endocrine disrupting chemicals in drinking water. Conclusions Our study provides an overview of potentially biologically active PSMs in surface waters and recommends their consideration in monitoring and risk assessment of water resources. This is currently hampered by a lack of effect data including toxicity to aquatic organisms, endocrine disruption and genotoxicity and demands for involvement of these compounds in biotesting.

Free Water Influence on the Dynamic Tensile Behaviour of Concrete

2011 ◽  
Vol 82 ◽  
pp. 45-50 ◽  
Author(s):  
Benjamin Erzar ◽  
Pascal Forquin
Keyword(s):  
Dynamic Behaviour ◽  
Free Water ◽  
Dynamic Strength ◽  
Fragmentation Process ◽  
Tensile Behaviour ◽  
Water Influence ◽  
Micro Cracks ◽  
The World ◽  
The Difference ◽  
Impact Experiments

Concrete is a material used all over the world for civil engineering but the mechanisms governing its dynamic behaviour are still not well understood. In this work, spalling tests and edge-on impact experiments have been used to determine the influence of the free-water contained in pores and micro-cracks on the dynamic strength and on the fragmentation process. Moreover, spalling tests have been also used to identify the main mechanisms leading to the difference of behaviour observed between wet and dry concrete.

Content and variability of nutrients in the water area of ​​Blagopoluchiya Bay (Novaya Zemlya, Kara Sea)

2021 ◽  
Author(s):  
Gennadii Borisenko ◽  
Alexander Polukhin ◽  
Valentina Sergeeva
Keyword(s):  
Russian Federation ◽  
Basic Research ◽  
Open Water ◽  
Water Area ◽  
Kara Sea ◽  
Arctic Ecosystems ◽  
Shirshov Institute ◽  
Surrounding Water ◽  
Novaya Zemlya Archipelago ◽  
Novaya Zemlya

<p>In the frames of the scientific program “Investigation of the Russian Arctic ecosystems” in 2007-2020 held by Shirshov Institute of Oceanology, comprehensive studies of the bays of the Novaya Zemlya archipelago (NZA) were carried out. There is very little information in the scientific literature on the dynamics and hydrochemical structure of the waters of the bays. Our investigations have revealed that the concentration of nutrients (first of all, nitrates and silicate) in the bays of NZA was higher than in the surrounding water area of ​​the Kara Sea. The most well studied and open for investigations is the Blagopoluchiya Bay in the northern island of NZA. Blagopoluchiya Bay is a fjord-type bay with several streams of the glacier origin.</p><p>The concentrations of nutrients (N, P, Si, C) in the streams were observed in August-September (0-1.53 µM of PO<sub>4</sub><sup>3-</sup>, 6.4-50.2 µM of SiO<sub>3</sub><sup>2-</sup>, 0.6-11.2 µM of NO<sub>2</sub><sup>-</sup>+NO<sub>3</sub><sup>-</sup>, 732-4815 µM of DIC). The observed content of nutrients in the waters of the bay was on average 2 times lower, but not lower than the level limiting the development of phytoplankton.</p><p>We suppose that high concentrations of nutrients in NZA bays in August-September were supported by increasing glacial runoff from NZA during the summer open water period and the removal of products of degradation of shore rocks with it. Despite the constant enrichment of nutrients, the concentration of phytoplankton in Blagopoluchiya Bay was extremely low (0.2-0.7 mkgC/l) in comparison with the adjacent marine part of the Kara Sea in all years of research.  Perhaps it was due to osmostress of planktonic algae during desalination of the bay by the NZA runoff.</p><p>This work was supported by the State Agreement of The Ministry of Science and Education of Russian Federation (theme №0128-2019-0008); Russian Foundation for Basic Research project 18-05-60069 (processing hydrochemistry data); Russian Scientific Foundation project 19-17-00196 (data obtaining); by the Grant of the President of the Russian Federation MK-860.2020.5 (processing carbonate chemistry data).</p>

Distribution of Some Selected Surface Active Agents (SAAs) in the Aquatic and Global Environment with Their Toxic Impact: A Comprehensive Review

2020 ◽  
Vol 33 (1) ◽  
pp. 31-46
Author(s):  
Ramsingh Kurrey ◽  
Anushree Saha ◽  
Manas Kanti Deb
Keyword(s):  
Surface Waters ◽  
Anaerobic Degradation ◽  
River Waters ◽  
Toxic Impact ◽  
Amphiphilic Molecules ◽  
Surface Active Agents ◽  
Soils And Sediments ◽  
Surface Active ◽  
Soil Sediments ◽  
Dispersing Agents

Surface active agents (SAAs) are a class of compounds, which find various applications in different fields of human activities. Surfactants are generally amphiphilic molecules, which are strongly adsorbed at interfaces between the phases. Surfactants windily used as detergency, emulsion, stabilizing and dispersing agents have led to the discharge of highly contaminated wastewaters in aquatic environment. Once reached in the various compartments of the environment such as rivers, lakes, soils, and sediments, surfactants can undergo aerobic or anaerobic degradation. Concentrations of surfactants in wastewaters, river waters, and sewage waters can range milligrams in maximum cases, while it reaches several grams in sludge, soil and sediments in environments. The environmental facts of SAAs and concentration in surface waters, soils or sediments are reviewed in details. This review provides information on levels of surface-active agents in various environmental samples including soil, sediments, sewage wastewater, river wastewater and aerosols.

New data on the fauna and the biogeographic structure of the Hydrozoa, Scyphozoa, Staurozoa and Alcyonacea (Anthozoa) of the Kara Sea

2021 ◽  
Vol 325 (2) ◽  
pp. 143-155
Author(s):  
N.E. Zhuravleva
Keyword(s):  
Cold Water ◽  
Kara Sea ◽  
Novaya Zemlya ◽  
The North ◽  
Anna Trough ◽  
New Material ◽  
Western Side ◽  
Academy Of Sciences ◽  
North Western ◽  
Arctic Fauna

The paper considers the species composition of the fauna of several cnidarian groups of the Kara Sea. The author presents a list of species of the studied groups and indicates the types of habitat for each species. The analysis was based on the literature data, the collections of the Zoological Institute of the Russian Academy of Sciences and material collected in the Kara Sea during the expedition to the R/V Professor Multanovsky in 2019. In total, 87 species of Hydrozoa, 3 species of Scyphozoa, 4 species of Staurozoa, and 5 species of the order Alcyonacea from the class Anthozoa were recorded for the fauna of the Kara Sea, based on the new material obtained by the author and published literature data. The report presents the biogeographic structure of the discussed cnidarian groups. According to the types of biogeographic ranges, the fauna of the above-mentioned cnidarian groups in the Kara Sea mostly consists of representatives of the Boreal-Arctic type of habitat (63%), the Boreal and Amphiboreal biogeographic groups each containing 12% of the total number of described species, and the Panoceanic and Arctic groups together accounting for only 9% and 4% of the fauna of the Kara Sea. Two species new for the Kara Sea, Neoturris pileata (Forsskål, 1775) and Neoturris pileata (Forsskål, 1775), are described. Neoturris pileata is an element of the warm-water Atlantic fauna that penetrated into the Kara Sea with waters of Atlantic genesis. Nausithoe werneri is an element of the cold-water Arctic fauna that penetrated into the Novaya Zemlya Trough of the Kara Sea from the north-western side from the St. Anna Trough, which was open to the Polar Basin.

scholarly journals Imprint of a dissolved cobalt basaltic source on the Kerguelen Plateau

2012 ◽  
Vol 9 (12) ◽  
pp. 5279-5290 ◽  
Author(s):  
J. Bown ◽  
M. Boye ◽  
P. Laan ◽  
A. R. Bowie ◽  
Y.-H. Park ◽  
...  
Keyword(s):  
Surface Waters ◽  
External Input ◽  
Eastern Slope ◽  
Kerguelen Plateau ◽  
Dissolved Iron ◽  
Deep Waters ◽  
Iron Supply ◽  
Natural Iron ◽  
Shelf Sediments ◽  
Lateral Advection

Abstract. Processes of cobalt (Co) entrainment from shelf sediments over the Kerguelen Plateau were studied during the KEOPS (Kerguelen Ocean Plateau compared Study) in order to explain the exceptionally high dissolved cobalt concentrations that have been measured in the surface waters above the Kerguelen Plateau, and in intermediate and deep waters above its eastern slope. Lateral advection and dissolution of Co contained in basalt sediments around Heard Island, a main source of lithogenic Co in the study area, were shown to imprint the process of surface enrichment over the plateau. Dissolved Co enrichment was strongest at the intercept of the eastern slope with intermediate and deep waters, probably due to more efficient mobilisation of the sediments in the slope current, in addition to advection of Co-enriched and low-oxygenated ocean water masses. In surface waters, the strong sedimentary Co inputs were estimated to be much higher than biological Co uptake in phytoplankton blooms, underlining the potential use of dissolved cobalt as tracer of the natural iron fertilization above the Kerguelen Plateau. Based on a simple steady-state balance equation of the external input of dissolved iron over the plateau, the fertilization of iron inferred by using dissolved Co as a tracer of basalt sources is estimated to be 28 × 102 ± 21 × 102 t yr−1 in surface waters of the Kerguelen Plateau. This estimate is consistent with preceding ones (Zhang et al., 2008; Chever et al., 2010), and the calculated iron supply matches with the phytoplankton demand (Sarthou et al., 2008).

Nutrients, Chlorophyll, and Internal Tides in the St. Lawrence Estuary

1976 ◽  
Vol 33 (12) ◽  
pp. 2747-2757 ◽  
Author(s):  
Jean-Claude Therriault ◽  
Guy Lacroix
Keyword(s):  
Surface Waters ◽  
Internal Tides ◽  
Upstream Region ◽  
Mixing Process ◽  
Low Oxygen ◽  
Lawrence Estuary ◽  
Deep Waters ◽  
High Nutrient ◽  
Phosphate Nitrate ◽  
St Lawrence Estuary

Tide-dependent variations of temperature, salinity, dissolved oxygen, phosphate, nitrate, and chlorophyll a support the existence of internal tides (longitudinal and transversal) in the St. Lawrence estuary. Vertical oscillations of the poorly oxygenated and nutrient-rich intermediate and deep waters of the estuary have been documented at the head of the Laurentian Channel, the region in which the internal tides are thought to be generated. Penetration of intermediate waters (high-nutrient and low-oxygen concentrations) beyond the Laurentian Channel associated with the internal tides and linked with an intense mixing process in the upstream region permits the nutrient enrichment of the surface waters and their eventual advection in the seaward direction.

scholarly journals A Simple Method for the Detection of Biofilms Using a Heatable Capacitive Sensor Structure (CSS): Description, Proof of Concept, and Some Technical Improvements

Sensors ◽  
2022 ◽  
Vol 22 (2) ◽  
pp. 445
Author(s):  
Kai-Uwe Zirk ◽  
Manuel Olze ◽  
Harald Pötzschke
Keyword(s):  
Printed Circuit Boards ◽  
Free Water ◽  
Spray Coating ◽  
Internal Surface ◽  
Capacitive Sensor ◽  
Simple Method ◽  
Realistic Condition ◽  
Main Challenge ◽  
Sensor Structure ◽  
The Difference

This article presents a novel method for the detection of biofilms based on a heatable, capacitive sensor structure (CSS). Biofilms are capable of strongly binding large amounts of water to their extracellular biopolymer matrix, which is detectable via its dielectric properties. A main challenge is to determine the difference between the inherent occurring presence of moisture in the ecosystem, which is necessary to form a biofilm and an actual formed biofilm. Therefore, the CSS is carefully heated to evaporate unbound surface moisture and determine whether there is a remaining residual alternation of the capacitance in comparison to the dry state. As a reproduceable substitute for complex, real biofilms, a hygroscopic, medical hydrogel-based on polysaccharides was used and applied by spray coating. Printed circuit boards (PCB) in different geometries and materials were used as CSS and compared in terms of their performance. A layer-thickness of 20 µm for the hydrogel coating to be sufficiently detected was defined as a realistic condition based on known values for real biofilms cited in literature. For this thickness a double-meander structure proves to be preferable over interdigitating and spiral geometries. It does offer a 30% lower, yet sufficient sensitivity, but shows advantages in manufacturing (one layer instead of two) and conductive heating capability. In the experiments, free water showed virtually no residual change, while the hydrogel-coated CSS still shows an approx. 300% higher value compared to a dry capacity. Yet, the overall small capacities of about 6–30 pF in dry state are difficult to measure and therefore sensitive to interferences and noise, which results in a high deviation. The principle of measurement can be evaluated as proofed by the carried out experiments, though offering room for improvement in the design of the study. The new method might be especially useful for pipes (e.g., hydrodynamically ineffective sensors installed in a pipe wall) if they at least are not permanently flooded with an aqueous medium, but can occasionally dry. If the internal surface is still only moist, it can be dried by initial heating.

Estimation of the seasonal input of freshwater in the Kara sea surface layer using hydrochemical proxies

2021 ◽  
Author(s):  
Uliana Kazakova ◽  
Alexander Polukhin
Keyword(s):  
Surface Layer ◽  
Coastal Zone ◽  
Dissolved Inorganic Carbon ◽  
Major Ions ◽  
Kara Sea ◽  
Total Alkalinity ◽  
Shirshov Institute ◽  
Arctic Water ◽  
Total Contribution ◽  
Continental Runoff

<p>The Kara Sea receives about 55 % of the total continental runoff to the Siberian Arctic. Water of the Yenisei and Ob Rivers with low salinity (mineralization), flowing into the sea, forms a surface desalinated layer. The desalinated layer spreads over the sea area under the influence of hydrological and meteorological factors. Meltwater generated by the melting of marine and riverine ice and precipitation contribute to the formation of a surface desalinated layer along with continental runoff.</p><p>Determining the amount of fresh water is not accurate enough if only the salinity of surface water is considered. It is possible to identify riverine water and meltwater using hydrochemical proxies. The ratio of the major ions in seawater differs from that in riverine and meltwater. River waters are characterized by an increased content of silicate and reduced values of total alkalinity. At the same time, it is possible to identify the waters of the Ob and Yenisei Rivers by the estimated values of the total alkalinity and dissolved inorganic carbon obtained during the research expeditions to the Kara sea from 1993 to 2020.</p><p>The calculation of the parts of waters of different origin is done as a result of solving a system of equations. It includes the salinity and alkalinity values of the observed surface waters and those presumably involved in the mixing process. The salinity and alkalinity values of meltwater are taken as 0 and 134 µM respectively.</p><p>The total contribution of the Ob and Yenisei runoff ranges from 20 to 90% as it approaches the estuarine areas. The correlation coefficient between the proportion of river water and the salinity of the surface layer is quite high, it is equal to -0.9. This characterizes the inverse linear relationship. The separate contribution of the waters of the Yenisei differs from the contribution of the waters of the Ob, which is related to the hydrological conditions of the rivers.</p><p>The contribution of meltwater to the formation of the surface layer of the Kara Sea did not exceed 20%, with the exception of the coastal zone of the Novaya Zemlya. In this coastal zone, meltwater provides the greatest contribution compared to the other sources, which is associated with glacial runoff.</p><p>The work is implemented in the framework of the state assignment of the Shirshov Institute of Oceanology RAS (theme No. 0149-2019-0008), with the support of the Russian Scientific Foundation (project № 19-17-00196) and the grant of President of Russian Federation № MK-860.2020.5.</p>

scholarly journals The Mixing Regime and Turbidity of Lake Banyoles (NE Spain): Response to Climate Change

Water ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1621
Author(s):  
Teresa Serra ◽  
Josep Pascual ◽  
Ramon Brunet ◽  
Jordi Colomer
Keyword(s):  
Climate Change ◽  
Surface Waters ◽  
Warming Trend ◽  
Western Mediterranean ◽  
Aquifer Recharge ◽  
Temperature Changes ◽  
The Past ◽  
Deep Waters ◽  
Cooling Trend ◽  
Ne Iberian Peninsula

This study analyses the water temperature changes in Lake Banyoles over the past four decades. Lake Banyoles, Spain’s second highest lake, situated in the western Mediterranean (NE Iberian Peninsula). Over the past 44 years, the warming trend of the lake’s surface waters (0.52 °C decade−1) and the cooling trend of its deep waters (−0.66 °C decade−1) during summer (July–September) have resulted in an increased degree of stratification. Furthermore, the stratification period is currently double that of the 1970s. Meanwhile, over the past two decades, lake surface turbidity has remained constant in summer. Although turbidity did decrease during winter, it still remained higher than in the summer months. This reduction in turbidity is likely associated with the decrease in groundwater input into the lake, which has been caused by a significant decrease in rainfall in the aquifer recharge area that feeds the lake through groundwater sources. As a unique freshwater sentinel lake under the influence of the climate change, Lake Banyoles provides evidence that global warming in the western Mediterranean boosts the strength and duration of the lake’s stratification and, in response, the associated decrease in the turbidity of its epilimnion.

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