scholarly journals Interpretation of zircon corona textures from metapelitic granulites of Ivrea-Verbano Zone, Northern Italy: Two-stage decomposition of Fe-Ti oxides

2016 ◽  
Author(s):  
Elizaveta Kovaleva ◽  
Håkon Austrheim ◽  
Urs Klötzli

Abstract. In this study we report the occurrence of zircon corona textures in metapelitic granulites of the Ivrea-Verbano Zone. Unusual zircon textures are spatially associated with Fe-Ti oxides and occur as (1) vermicular-shaped aggregates 50–200 µm long and 5–20 µm thick, and as (2) zircon coronas and fine-grain chains, hundreds of µm long and ≤ 1 µm thick, spatially associated with (1). Formation of such textures is a result of mineral-fluid reactions, which occurred in two stages and involved: (1) decomposition of ilmenite to Zr-rich rutile and vermicular-shaped zircon during peak metamorphism and initial cooling stage, and (2) recrystallization of Zr-rich rutile to Zr-depleted rutile and submicron-thick zircon coronas during further exhumation and cooling. We also observed hat-shaped grains that are composed of preexisting zircon overgrown by zircon coronas during stage (2). Hat-shaped grains have a flat surface towards the oxide phase, which indicates partial dissolution of preexisting zircon grain. Formation of vermicular zircon (1) preceded ductile and brittle deformation of the host rock, as vermicular zircon is found both plastically- and cataclastically-deformed. Formation of thin zircon coronas (2) was coeval with or soon after the brittle deformation, as coronas occasionally fill fractures in the host rock. Occurrences of zircon coronas has important implications in fundamental studies regarding metamorphism, metasomatism and element transport in the Earth’s crust. We demonstrate that metamorphic zircon can nucleate and grow as a result of hydration reactions at the cooling stage after granulite-facies metamorphism, and reflects stages of rock evolution. Zircon corona textures are the tool for indicating metamorphic and metasomatic reactions in the host rock, and establish the directions of the reaction front.

Solid Earth ◽  
2017 ◽  
Vol 8 (4) ◽  
pp. 789-804 ◽  
Author(s):  
Elizaveta Kovaleva ◽  
Håkon O. Austrheim ◽  
Urs S. Klötzli

Abstract. In this study, we report the occurrence of zircon coronae textures in metapelitic granulites of the Ivrea–Verbano Zone. Unusual zircon textures are spatially associated with Fe–Ti oxides and occur as (1) vermicular-shaped aggregates 50–200 µm long and 5–20 µm thick and as (2) zircon coronae and fine-grained chains, hundreds of micrometers long and ≤ 1 µm thick, spatially associated with the larger zircon grains. Formation of such textures is a result of zircon precipitation during cooling after peak metamorphic conditions, which involved: (1) decomposition of Zr-rich ilmenite to Zr-bearing rutile, and formation of the vermicular-shaped zircon during retrograde metamorphism and hydration; and (2) recrystallization of Zr-bearing rutile to Zr-depleted rutile intergrown with quartz, and precipitation of the submicron-thick zircon coronae during further exhumation and cooling. We also observed hat-shaped grains that are composed of preexisting zircon overgrown by zircon coronae during stage (2). Formation of vermicular zircon (1) preceded ductile and brittle deformation of the host rock, as vermicular zircon is found both plastically and cataclastically deformed. Formation of thin zircon coronae (2) was coeval with, or immediately after, brittle deformation as coronae are found to fill fractures in the host rock. The latter is evidence of local, fluid-aided mobility of Zr. This study demonstrates that metamorphic zircon can nucleate and grow as a result of hydration reactions and mineral breakdown during cooling after granulite-facies metamorphism. Zircon coronae textures indicate metamorphic reactions in the host rock and establish the direction of the reaction front.


2017 ◽  
Author(s):  
Elizaveta Kovaleva ◽  
Håkon O. Austrheim ◽  
Urs S. Klötzli

Abstract. In this study, we report the occurrence of zircon coronae textures in metapelitic granulites of the Ivrea-Verbano Zone. Unusual zircon textures are spatially associated with Fe-Ti oxides and occur as (1) vermicular-shaped aggregates 50–200 µm long and 5–20 µm thick, and as (2) zircon coronae and fine-grained chains, hundreds of µm long and ≤ 1 µm thick, spatially associated with the larger zircon grains. Formation of such textures is a result of zircon precipitation during cooling after peak metamorphic conditions, which involved: (1) decomposition of Zr-rich ilmenite to Zr-bearing rutile and vermicular-shaped zircon during retrograde metamorphism and hydration; (2) recrystallization of Zr-bearing rutile to Zr-depleted rutile intergrown with quartz and submicron-thick zircon coronae during further exhumation and cooling. We also observed hat-shaped grains that are composed of preexisting zircon overgrown by zircon coronae during stage (2). Formation of vermicular zircon (1) preceded ductile and brittle deformation of the host rock, as vermicular zircon is found both plastically- and cataclastically-deformed. Formation of thin zircon coronae (2) was coeval with, or immediately after brittle deformation, as coronae are found to fill fractures in the host rock. The latter is evidence of local, fluid-aided mobility of Zr. This study demonstrates that metamorphic zircon can nucleate and grow as a result of hydration reactions and mineral breakdown during cooling after granulite-facies metamorphism. Zircon corona textures indicate metamorphic reactions in the host rock, and establishing the direction of the reaction front.


2019 ◽  
Vol 48 (3) ◽  
pp. 49-63
Author(s):  
Milena Georgirva ◽  
Tzvetomila Vladinova

Garnet–clinopyroxene–K-feldspar granulite occurs as a thick layer or boudin within the variegated rocks of the Chepelare shear zone in the Central Rhodope massif, Bulgaria. It consists of several domains: mesocratic homogeneous matrix (clinopyroxene–plagioclase–K-feldspar–quartz ± amphibole), porphyroblastic garnet, K-feldspar and clinopyroxene, and strongly foliated fine-grain bands (chloritized biotite–chlorite–prehnite–albite ± epidote). The origin and nature of the matrix mineral association is still unclear. The peak porphyroblast association forms at the expense of plagioclase from the matrix at higher pressure. The fine-grain deformation zones channel the lattermost fluid infiltration. The clinopyroxene-garnet and Zr-in-titanite thermometry give temperatures higher than 790–860 ºC at 2 GPa and, with thermodynamic modeling, suggests crystallization at ~1.8–2.1 GPa and temperature of ~850 ºC in HP granulite field for the porphyroblast granulite association.


2002 ◽  
Vol 66 (6) ◽  
pp. 985-1002 ◽  
Author(s):  
P. J. Downes ◽  
A. W. R. Bevan

Abstract A deposit of chrysoberyl (BeAl2O4), including the variety alexandrite, occurs near Dowerin, in the southwestern region of the Archaean Yilgarn Craton, Western Australia. The deposit is situated in the northern part of the Lake Grace Terrain, a crustal component of the southwestern Yilgarn Craton, in granulite-facies gneisses (2640–2649 Ma; T = 700°C, P <6 kbar) adjacent to the margin of the Kellerberrin Batholith (2587±25 Ma). Beryllium mineralization at Dowerin occurs in plagioclase-quartz-biotite-garnet gneiss and cross-cutting tourmaline-plagioclase veins situated adjacent to lenses of actinolite-cummingtonite-phlogopite schist. Crystals of chrysoberyl (0.15–1.74 wt.% Cr2O3; 2.25–3.23 wt.% FeO; trace–0.13 wt.% ZnO; SiO2 <0.05 wt.%) are found embedded in almandine or plagioclase, and closely intergrown with biotite and/or zincian hercynite in the host-rock gneiss. Minor Cr and Fe in the alexandrite variety of chrysoberyl were possibly derived from associated zincian hercynite and/or almandine. Trace beryl (0.04–0.20 wt.% Cr2O3; 0.54–0.71 wt.% FeO; trace– 0.22 wt.% Na2O; 0.1–0.71 wt.% MgO) occurs as anhedral interstital grains between crystals of chrysoberyl, plagioclase and biotite, and as rare inclusions in chrysoberyl. Textural and mineral chemical evidence suggests that chrysoberyl and zincian spinels (chromite to hercynite containing from 2–8 wt.% ZnO) formed during granulite-facies regional metamorphism and probably pre-dated the formation of metamorphic tourmaline-plagioclase veins during the same metamorphic episode. The Be, B and Zn required to form chrysoberyl, beryl, tourmaline and zincian spinels may have been released by metamorphic reactions in host-rock metapelites during prograde granulite-facies metamorphism.


Early cratonal development of the Arabian Shield of southwestern Saudi Arabia began with the deposition of calcic to calc-alkalic, basaltic to dacitic volcanic rocks, and immature sedimentary rocks that subsequently were moderately deformed, metamorphosed, and intruded about 960 Ma ago by dioritic batholiths of mantle derivation (87Sr/86Sr = 0.7029). A thick sequence of calc-alkalic andesitic to rhyodacitic volcanic rocks and volcanoclastic wackes was deposited unconformably on this neocraton. Regional greenschistfacies metamorphism, intensive deformation along north-trending structures, and intrusion of mantle-derived (87Sr/86Sr = 0.7028) dioritic to granodioritic batholiths occurred about 800 Ma. Granodiorite was emplaced as injection gneiss about 785 Ma (87Sr/86Sr = 0.7028- 0.7035) in localized areas of gneiss doming and amphibolite to granulite facies metamorphism. Deposition of clastic and volcanic rocks overlapped in time and followed orogeny at 785 Ma. These deposits, together with the older rocks, were deformed, metamorphosed to greenschist facies, and intruded by calc-alkalic plutons (87Sr/86Sr = 0.7035) between 600 and 650 Ma. Late cratonal development between 570 and 550 Ma involved moderate pulses of volcanism, deformation, metamorphism to greenschist facies, and intrusion of quartz monzonite and granite. Cratonization appears to have evolved in an intraoceanic, island-arc environment of comagmatic volcanism and intrusion.


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