Abstract
π-Molecules play important roles in many applications such as organic light emitting devices, photocatalysis, photovoltaics, biosensors and medicine. Very often, high-performance π-conjugated molecules are of great research interest. However, owing to the conflict between the design of efficient π structure (good rigidity and planarity) and efficient π aggregates (minimum face-to-face π effect), it is challenging for traditional planar π or recently emerged twisted π molecules to realize very high exciton utilization in solid state. Herein, we report a new π skeleton, folded π, to achieve high exciton utilization in solids. Folded π-based molecules tend to form molecular packing patterns that are rich in π interactions, favoring the suppression of unfavorable energy dissipation pathways such as molecular thermal perturbation. Meanwhile, the potential face-to-face π effect between planar π is well prevented by the hydrogen atoms around the π planes. As a result of effective packing, all the synthesized π-based molecules show very high exciton utilization in solids.