scholarly journals Distribution of inorganic phosphorus in profiles and particle-size fractions across an established riparian buffer and adjacent cropped area at the Dian lake

2015 ◽  
Vol 7 (4) ◽  
pp. 3223-3244
Author(s):  
G. S. Zhang ◽  
J. C. Li

Abstract. Riparian buffer can trap sediment and nutrients sourced from upper cropland and minimizing eutrophication risk of water quality. This study aimed to investigate the distributions of soil inorganic phosphorus (Pi) forms among profile and particle-size fractions in an established riparian buffer and adjacent cropped area at the Dian lake, Southwestern China. The Ca-bound fraction (62 %) was the major proportion of the Pi in the riparian soils. Buffer rehabilitation from cropped area had a limited impact on total phosphorus (TP) concentrations after 3 years, but has contributed to a change in Pi forms. At 0–20 cm soil layer, levels of the Olsen-P, nonoccluded, Ca-bound and total Pi were lower in the buffer than the cropped area; however, the Pi distribution between the cropped area and the buffer did not differ significantly as depth increased. The clay fraction corresponded to 57 % of TP and seemed to be both a sink for highly recalcitrant Pi and a source for labile Pi. The lower concentration of Pi forms in the silt and sand particle fraction in the surface soil was observed in the buffer area, which indicating that the Pi distribution in coarse particle fraction has sensitively responded to land-use changes.

Solid Earth ◽  
2016 ◽  
Vol 7 (1) ◽  
pp. 301-310 ◽  
Author(s):  
Guo Sheng Zhang ◽  
Jian Cha Li

Abstract. Riparian buffers can trap sediment and nutrients sourced from upper cropland, minimizing the eutrophication risk of water quality. This study aimed to investigate the distributions of soil inorganic phosphorus (Pi) forms among profile and particle-size fractions in an established riparian buffer and adjacent cropped area at the Dian lake, southwestern China. The Ca-bound fraction (62 %) was the major proportion of the Pi in the riparian soils. After 3 years' restoration, buffer rehabilitation from cropped area had a limited impact on total phosphorus (TP) concentrations, but has contributed to a change in Pi forms. In the 0–20 cm soil layer, levels of the Olsen-P, non-occluded, Ca-bound, and total Pi were lower in the buffer than the cropped area; however, the Pi distribution between the cropped area and the buffer did not differ significantly as depth increased. The clay fraction corresponded to 57 % of TP and seemed to be both a sink for highly recalcitrant Pi and a source for labile Pi. The lower concentration of Pi forms in the silt and sand particle fraction in the surface soil was observed in the buffer area, which indicated that the Pi distribution in coarse particle fraction had sensitively responded to land use changes.


Revista CERES ◽  
2012 ◽  
Vol 59 (6) ◽  
pp. 867-872 ◽  
Author(s):  
Julião Soares de Souza Lima ◽  
Rone Batista de Oliveira ◽  
Samuel de Assis Silva

Information on the spatial distribution of particle size fractions is essential for use planning and management of soils. The aim of this work to was to study the spatial variability of particle size fractions of a Typic Hapludox cultivated with conilon coffee. The soil samples were collected at depths of 0-0.20 and 0.20-0.40 m in the coffee canopy projection, totaling 109 georeferentiated points. At the depth of 0.2-0.4 m the clay fraction showed average value significantly higher, while the sand fraction showed was higher in the depth of 0-0.20 m. The silt showed no significant difference between the two depths. The particle size fractions showed medium and high spatial variability. The levels of total sand and clay have positive and negative correlation, respectively, with the altitude of the sampling points, indicating the influence of landscape configuration.


1980 ◽  
Vol 60 (1) ◽  
pp. 61-70 ◽  
Author(s):  
C. G. KOWALENKO ◽  
G. J. ROSS

The dynamics of fixation and release of NH4+ in soils were studied using tracer N under field and laboratory conditions. Field data showed that release of fixed NH4+ was relatively slow after an initial moderately fast release. Forty months of field weathering of Bainsville soil left 3.48 kg 15N/ha in the 75-cm profile of the 13.5 kg 15N/ha applied and most (76%) of this recovered 15N was fixed NH4+–N. The relative quantitative importance of recently fixed NH4+ in the various particle size fractions was not in the same order as the native fixed NH4+. The fine silt fraction (2–5 μm) fixed a larger amount (whole soil basis) than the fine clay fraction (< 0.2 μm). The coarse clay fraction (0.2–2 μm) fixed the most NH4+ added as well as being the fraction containing the most native fixed NH4+. Sand size fractions were shown to contain native fixed NH4+ and were capable of fixing a small amount of added NH4+. Measurements of recently fixed NH4+–N in various particle sizes covering four time intervals (up to 40 mo) of field weathering under fallow showed that the 0.2 to 2-μm fraction was quantitatively most important, the < 0.2-μm fraction most readily released recently fixed NH4+ and the 2 to 5-μm fraction was the most stable with respect to recently fixed NH4+. Plant growth affected the relative stability of the recently fixed NH4+ in the various particle size fractions. Laboratory studies of three Brookston soil samples revealed higher estimates of fixation of NH4+ by direct tracer methods than by indirect extraction methods. This discrepancy was assumed to have been caused by some exchange of added NH4+ with native fixed NH4+ and by some NH4+ being fixed on other sites. The relationship between mineralogical and related analyses to fixation of NH4+ was discussed.


2012 ◽  
Vol 63 (4) ◽  
pp. 9-15 ◽  
Author(s):  
Zygmunt Brogowski ◽  
Wojciech Kwasowski

Abstract The distribution of organic matter in the genetic horizons of lateritic soil within a 100-cm profile to the basaltic parent rock is almost except for horizon Ap. Assuming that the sum of organic matter in 100 cm of the soil profile is 100%, 25.7% of these compounds occur in horizon Ap, whereas in the remaining horizons this value varies within 18-19.2%. In all size fractions, except the clay fraction in diameter of <0.002 mm, the content of organic matter decreases to a certain depth, and increases again in the deepest horizon located directly on the solid basaltic rock. The clay fraction displays an opposite trend; the content of organic matter in them increases with depth. In the horizon at the depth of 60-80 cm, the clay fraction <0.002 mm accumulates half of the total sum of organic compounds of all the remaining fractions. Such distribution of organic matter in soil and among its particle size probably results from the character of the basaltic weathered debris, as well as climate and vegetation covering the studied area.


2003 ◽  
Vol 47 (7-8) ◽  
pp. 233-241 ◽  
Author(s):  
J.G. Lin ◽  
S.Y. Chen ◽  
C.R. Su

Mobility and toxicity of metals associated with sediments are generally affected by metal speciation and granular compositions. Due to the various speciation patterns of heavy metals in sediments, it is not reliable to assess the potential toxicity of heavy metals on the aquatic environment with the total concentrations of heavy metals in sediments. The purposes of this study were to investigate the distribution of metal speciation in different particle-size fractions of sediments collected from two rivers (the Ke-Ya River and Ell-Ren River) in Taiwan, and to assess their potential toxicity to the aquatic ecosystem. Metals in the exchangeable, carbonate-bound and Fe/Mn oxide-bound forms obtained by sequential extraction were considered to be mobile and related with anthropogenic pollution. The degree of metal pollution and potential toxicity of sediments were higher in the lower reaches of both rivers. The metal speciation in sediments had a bimodal distribution over particle-size fractions. Heavy metals were subject to accumulation in the silt/clay fraction (&lt;25μmm) and coarse sand (420-2,000μmm). By normalizing the sum of the exchangeable, carbonate-bound, and Fe/Mn oxide-bound metals, it suggested that the potential toxicity to the aquatic ecosystem was caused by the fine sediments as well as coarse sediments.


2018 ◽  
Vol 26 (4) ◽  
pp. 352-359
Author(s):  
Julião Soares de Souza Lima ◽  
Samuel Assis Silva ◽  
Daniel Pena Pereira ◽  
Marcelo Soares Altoé

Knowing the variation of particle-size fractions, considering the relief forms, contributes for understanding the variation of other soil attributes. This work aimed to study the spatial distribution of the probability of particle-size fractions occurrence (clay, silt, very fine sand, fine sand, coarse sand, and total sand) in a clayey Oxisol with predominance of concave and convex curvatures. A sampling grid with 94 sampling points in 33x33m spacing at a depth of 0–0.20 m was built using a GPS. The spatial analysis was performed through indicator kriging. The spherical model was fit for all soil fractions, with ranges varying from 130 m to 280 m. In the region of convex curvature, the clay fraction presented the highest probability of occurrence (0.75 to 1.00), whereas in the concave region the coarse sand and total sand fractions presented the highest probability of occurrence. The very fine sand fraction and the silt did not present pattern of distribution in relation to the dominant curvatures of the relief.


Soil Research ◽  
2001 ◽  
Vol 39 (2) ◽  
pp. 361 ◽  
Author(s):  
R. L. Parfitt ◽  
G. J. Salt

Although several studies have quantified either C mineralisation or net N mineralisation in particle-size fractions, no work has examined simultaneous C and net N mineralisation. Therefore, we conducted an 18-week laboratory incubation to compare simultaneous mineralisation in sand, silt, and clay fractions. The soils (silt loams) were collected from fields of long-term pasture and maize. Sand, silt, and clay were separated by mild dispersion in water followed by centrifugation. Samples were incubated at 25°C in the dark in a quartz matrix, and were leached every 2 weeks with 0.004 M CaCl 2 at a suction of 20 kPa to remove soluble products. C mineralisation was determined from CO 2 -C evolved each 2 weeks, and mineral N was measured in the leachate. C mineralisation, on a C basis, followed the order sand > clay > silt, and was related (r 2 = 0.88) to the proportion of O-alkyl C (carbohydrate C) estimated from 13 C NMR. The low mineralisation in the silt may also have been a result of the physical protection of substrates in small pores in this fraction. The rates of N release were initially rapid from the maize soil fractions, and were consistent with the high initial mineral-N contents; subsequently, the rates were slower, and probably related to C mineralisation. For the pasture soil, N mineralisation followed the order clay>silt>sand, and was inversely related to the C: N ratios. Immobilisation appeared to take place in the sand fraction, whereas a large part of the net N mineralisation occurred in the clay fraction. There is now good evidence that rates of C and net N mineralisation differ within discrete particle size fractions, and data on such fractions could be useful for constructing soil organic matter models.


2002 ◽  
Vol 82 (2) ◽  
pp. 265-268 ◽  
Author(s):  
D. Curtin

Although phyllosilicate clays, with their large surface areas, are often considered to play the leading role in stabilizing soil organic matter against microbial attack, several studies have suggested recently that oxides of Al and Fe may stabilize organic matter in some soils. The distribution of organic C and oxides in clay (< 0.2 and 0.2–2 mm) and silt fractions (2–5, 5–20, and 20–50 mm) of four Saskatchewan soils (organic C ranged from 21 to 46 g kg-1) was examined to differentiate the contributions of oxides and specific surface to organic matter retention. Carbon concentrations in the particle size fractions (separated following ultrasonic dispersion of the soils) tended to be highest in the fine silt and coarse clay fractions, not in the fine clay as would be expected if specific surface was the sole factor governing organic matter content. When data for the four soils were pooled there was a strong relationship between organic C (y) in the size fractions and Al (x) extracted by dithionite-citrate-bicarbonate [y = 33.9 x0,5 - 7.3; R2 = 0.90***], suggesting a role for A1 in determining the C storage capacity of the size fractions. The C: A1 ratio increased from an average of 12:1 in clay-sized material to 28:1 in coarse silt. Because it had less A1 per unit mass of C, organic matter in the silt separates may be more weakly bonded to mineral material than is clay-associated organic matter. This may imply that organic matter bound to silt is less stable, and thus susceptible to mineralization, than is organic matter residing in the clay fraction. Key words: Organic matter stabilization, particle size separates, extractable A1 and Fe


Soil Research ◽  
1990 ◽  
Vol 28 (3) ◽  
pp. 387 ◽  
Author(s):  
JD Armour ◽  
GSP Ritchie ◽  
AD Robson

The zinc (Zn) content of particle size fractions of 12 mainly Zn deficient soils was measured by extraction with three contrasting extractants. The soils, which ranged from sands to a black earth, were from Western Australia and Queensland and particle size fractions (clay, silt, fine sand, coarse sand) were obtained by sieving and sedimentation after ultrasonification of soil suspended in deionized water. The extractants were concentrated HNO3/H2SO4/HClO4 (acid extractable or AE-Zn), DTPA and 0.002 M CaCl2. For each extractant, Zn contents of the fractions and whole soils were correlated with organic carbon and ammonium oxalate extractable Fe and Al. The AE-Zn concentrations in whole soils were 0.6-132 mg kg-1 and high clay soils had higher concentrations (mean 54 mg kg-1) than low clay soils (mean 2 mg kg-1). After fractionation, lowest AE- and DTPA-Zn were found in coarse sand fractions and concentrations increased with decreasing particle size. Clay plus silt fractions contained 60-99% of the whole soil AE-Zn and 76-93% of the whole soil DTPA-Zn. The CaCl2-Zn concentrations were very low (<5.0 �g kg-1) for all soils. In whole soils, DTPA-Zn was only a small proportion, 3.2% and 1.8%, of the AE-Zn in the low clay and high clay soils, respectively. The CaCl2-Zn was generally less than 2% of the DTPA-Zn in whole soils. In whole soils, AE-Zn was correlated with oxalate extractable Fe and with oxalate A1 (r = 0.72 and 0.71, respectively; P <0.01), whereas DTPA-Zn was correlated with oxalate extractable Fe (r = 0.82; P < 0.01). The AE- and DTPA-Zn were correlated with organic carbon only in some fractions. The DTPA- and CaCl2-Zn were not correlated with AE-Zn content, nor was DPTA-Zn correlated with CaCl2-Zn in whole soils or fractions (P<0.05). Dispersion of the soils with ultrasonification in the absence of dispersing agents was not as effective as dispersion with conventional mechanical/chemical dispersion. The percentage of the soil recovered in the clay fraction after sonification was 23-78% of that recovered by the conventional method. Fine and coarse sand contents were similar for either method, indicating that incomplete dispersion of clay by ultrasonification resulted in higher silt contents.


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