Simple and Rapid Method by Sensitive Value of UV-Visible Spectrophotometric Determination of Copper (II) by Cloud Point Extraction

Author(s):  
Inas J. Mahdi
RSC Advances ◽  
2015 ◽  
Vol 5 (80) ◽  
pp. 65321-65327 ◽  
Author(s):  
Chunlei Fan ◽  
Shengxu Luo ◽  
Rong Liu

BTF is exists with spirolactone species with adding Cu2+, which leads to the absorbance intensity is decreased gradually and the decrease of the absorbance value is linear for Cu2+.


2020 ◽  
Vol 85 (1) ◽  
pp. 89-96 ◽  
Author(s):  
Denys Snigur ◽  
Alexander Chebotarev ◽  
Vitaliy Dubovyi ◽  
Dmytro Barbalat ◽  
Anastasiia Klochkova

The novel cloud point extraction procedure for preconcentration of copper(II) was discovered. A simple chemical method for initiating the cloud point extraction (CPE) has been proposed. The formation of surfactant rich phase in a system containing a nonionic surfactant Triton X-100, copper(II), 6,7-dihydroxy-4-methyl-2-phenylbenzopyrilium chloride (DHMPhB) and ammonium benzoate is observed immediately upon the sulfuric acid addition into solution. Under the optimal conditions (absorption band maximum was 540 nm, concentration 1.5?10-4 mol dm-3 of DHMPhB, 1.0 vol.% of Triton X-100, 2.0 cm3 of 0.75 mol dm-3 ammonium benzoate, and 1.0 cm3 of 0.5 mol dm-3 sulfuric acid solution for obtaining benzoic?benzoate buffer solution with pH 4.5 and initiation immediate surfactant rich phase formation) the calibration plot for spectrophotometric determination of copper(II) was linear in the range of copper(II) concentration 0.02?0.95 ?g cm?3. The limit of detection was calculated 0.006 ?g cm?3. The water samples were analyzed according to a suggested procedure with satisfactory results.


2006 ◽  
Vol 157 (3-4) ◽  
pp. 215-222 ◽  
Author(s):  
Valfredo Azevedo Lemos ◽  
Moacy Selis Santos ◽  
Márcio José Silva dos Santos ◽  
Daniel Rodrigues Vieira ◽  
Cleber Galvão Novaes

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