Determination of the Source and Pathway of Cyanide-Bearing Mine Water Seepage

Keyword(s):  
2015 ◽  
Vol 15 (4) ◽  
pp. 307
Author(s):  
N.V. Zhuravlyova ◽  
R.R. Potokina ◽  
Z.R. Ismagilov

A method for determination of 2,4,6-trinitrotoluene in  geoenvironmental subjects by gas chromatography with mass-spectrometric detection was proposed. The distribution of 2,4,6-trinitrotoluene in wastes and sewage water samples from mining plants was studied. The presence of this compound in surface water was established. Other nitrogen-containing compounds, in particular, 2-amino-4,6-dinitrotoluene and<br />2,4,-dinitrotoluene, were also identified in the studied samples.<br />The 2,4,6-trinitrotoluene (TNT) is the most important shattering explosive used for blasting out. This compound is highly toxic and stable to biodegradation. The TNT belongs to the second hazard class (highly hazardous); its maximum permissible concentration (MPC) in drinking water sources was strongly restricted, from 0.5 to 0.01 mg/L. A method for determination of 2,4,6-trinitrotoluene in surface water, sewage water and wastes by gas chromatography with mass-spectrometric detection has been developed. The TNT calibration curve was shown to be linear over the concentration range of 1.6-160 μg/mL, and the correlation factor of the line was equal to 0.997. The distribution of 2,4,6-trinitrotoluene in sewage water and wastes from mining plants has been studied. Mine water in the case of underground mining has high TNT concentrations, which cannot be decreased by the existing traditional methods of sewage water treatment. TNT is detected also in surface water after mine water disposal. Note that the TNT concentrations can exceed many times the maximum permissible concentrations prescribed for water works system.<br />2-amino-4,6-dinitrotoluene and 2,4,-dinitrotoluene, which can be considered as products of TNT metabolism, were also identified in the studied samples. The developed method and results of the present study make it possible to introduce the quantitative<br />determination of TNT and its metabolites into the programs for monitoring of surface water, sewage water and wastes in the mining plant sites in different countries as well in Russia, namely in Kuzbass.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Qianling Liu ◽  
Zhongjian Zhang ◽  
Bin Zhang ◽  
Wenping Mu ◽  
Huijie Zhang ◽  
...  

AbstractThe identification of open-pit mine water sources is of great significance in preventing water disasters. Combined with hydrochemistry and multivariate statistical analysis, this paper systematically analyzed the hydraulic connections between aquifers and the complex seepage water sources in the pit and roadway of Dagushan iron mine through qualitative analysis and quantitative calculation. According to the hydrochemical characteristics of the study area, the causes of seepage water at different positions in the mining area were reasonably explained. The results show that there is a possible hydraulic connection or similar source of water body between the bedrock fissure aquifer and the eluvium pore aquifer. The water seepage of 2# roadway mainly comes from bedrock fissure aquifer in the north of mining area. The reason for serious water seepage in the 3# roadway and the western side of the pit is that the fault connects the shallow alluvial pore aquifer and bedrock fissure aquifer. The source of water on the southern side pit comes from the river and groundwater on the southern side of the mine. The results presented here provide significant guidance for the management of mine water seepage problems.


2009 ◽  
Vol 60 (6) ◽  
pp. 1201-1213 ◽  
Author(s):  
Adam Ricka ◽  
Tomas Kuchovsky ◽  
Ondra Sracek ◽  
Josef Zeman

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