scholarly journals Bioavailability of soil Cu, Fe, Mn and Zn from soil fractions

2021 ◽  
Vol 42 (1) ◽  
pp. 19-42
Author(s):  
Renildes Lucio Ferreira Fontes ◽  
◽  
Gilvan Barbosa Ferreira ◽  
Victor Hugo Alvarez V. ◽  
Júlio Cesar Lima Neves ◽  
...  

Cationic micronutrients bioavailability depends on the chemical characteristics of soil fractions. Fourteen soils received individual doses of five micronutrients (Cu, Fe, Mn, Zn, B) arranged in seven treatments set according a Baconian Matrix. The soils incubated with treatments during 15 days had corn cultivated in greenhouse for 30 days, in three consecutive growth cycles. The cationic micronutrients were determined in the corn shoots after each growth cycle. Soil samples collected before the first and after each growth cycle had the available concentrations of Cu, Fe, Mn and Zn determined by single extractions (Mehlich-1 and DTPA-pH 7.3) and by sequential extraction. Correlation analysis was performed for the Cu, Fe, Mn and Zn concentrations determined in the corn shoots, the available concentrations of Cu, Fe, Mn and Zn in the soils (Mehlich-1 and DTPA) and the concentrations of Cu, Fe, Mn and Zn in the soil fractions (sequential extraction). The distribution of available metals forms in fractions reflected their affinity with soil components. Soil available Cu correlated with Cu bound to organic matter. The exchangeable fraction was the main source of soil available Mn and Zn. The Fe availability related mainly to the Mn oxides, Fe oxides, and exchangeable fractions. The plants absorbed Cu mainly from the Mn-oxides and organic matter fractions. Manganese absorbed by plants originated from the exchangeable and Mn-oxides fractions. The Zn absorbed by plants originated mainly from the exchangeable fraction. Correlations of single metal extractions (Mehlich-1 and DTPA) with Cu, Mn and Zn contents in plants were positive.

2003 ◽  
Vol 60 (1) ◽  
pp. 167-173 ◽  
Author(s):  
Clístenes Williams Araújo do Nascimento ◽  
Renildes Lúcio Ferreira Fontes ◽  
Adilson César Fortes Dias Melicio

The knowledge of the chemical forms of copper in soils and the relationships of these forms with soil copper availability are important for predicting the copper behavior in the soil-plant system. The present work studies the influence of liming on the available contents of copper as well as on the forms of copper fractions in six types of Oxisols. Soil samples, with and without liming, received copper at rates of 0.0, 20.0 and 40.0 mg dm-3 and remained incubated for 30 days. Then, available copper was extracted with Mehlich-1, Mehlich-3, DTPA and EDTA solutions, and analyzed by atomic absorption spectrophotometry. Additionally, soil samples were extracted in a sequential procedure to determine Cu in fractions of soil, as follows: exchangeable-Cu fraction, organic matter-Cu fraction, Mn oxide-Cu fraction, amorphous Fe oxide-Cu fraction, crystalline Fe oxide-Cu fraction, residual-Cu fraction, and the total Cu content in the soil. Soil samples to which Cu was added presented higher Cu retention in the organic matter fraction with a small percentage retained in the exchangeable-Cu fraction. Liming resulted in a decrease of Cu in the exchangeable and organic matter fractions and an increase in the Fe and Mn oxide fractions and in the residual fraction. Without liming, the organic matter fraction presented the highest contribution to Cu content found in the soil extracts obtained with all extractors, except EDTA. For treatments with liming, Cu contents in the organic matter fraction were better correlated to Cu contents in extracts obtained with DTPA and Mehlich-3.


2000 ◽  
Vol 57 (3) ◽  
pp. 467-472 ◽  
Author(s):  
Júlio César Martins de Oliveira ◽  
Klaus Reichardt ◽  
Osny O.S. Bacchi ◽  
Luis Carlos Timm ◽  
Durval Dourado-Neto ◽  
...  

Results of an organic matter management experiment of a sugar cane crop are reported for the first cropping year. Sugar cane was planted in October 1997, and labeled with a 15N fertilizer pulse to study the fate of organic matter in the soil-plant system. A nitrogen balance is presented, partitioning the system in plant components (stalk, tip and straw), soil components (five soil organic matter fractions) and evaluating leaching losses. The 15N label permitted to determine, at the end of the growing season, amounts of nitrogen derived from the fertilizer, present in the above mentioned compartments.


Radiocarbon ◽  
1977 ◽  
Vol 19 (2) ◽  
pp. 170-182 ◽  
Author(s):  
H W Scharpenseel ◽  
H Schiffmann

Radiocarbon measurements mainly on soil samples and soil organic matter fractions are being continued. Sample benzene preparation follows Scharpenseel & Pietig (1969; 1970a). Radioactivity is measured in single screw cap quartz vials using a Packard Tri-Carb 3075 as well as a Berthold Betaszint BF 5000.


2020 ◽  
Vol 45 (4) ◽  
Author(s):  
A.O. Abdullahi ◽  
A. Usman ◽  
A.H. Zakari ◽  
J.R. Tukur

This research work is aimed at determining the chemical speciation of metals Zn, Mn, Fe and Pb in soil samples from three major dumpsites within Gombe metropolis, Gombe state. The renowned five steps Tessier sequential extraction method was employed in the extraction of the heavy metals. The metals were extracted into five fractions namely: Exchangeable (F1), carbonate bound (F2), Fe-Mn oxide bound (F3), Bound to organic matter (F4) and the residual fraction (F5) in order of decreasing mobility. The elemental analysis of the fractions was carried out using atomic absorption spectrometric technique. The results showed Zn was predominantly bounded to the exchangeable fraction with 32.66±0.31 mg/kg (54.18%) and least in the Fe – Mn oxide fraction with 0.01±0.00 mg/kg (0.02%). The trend in its abundance is in the order F1> F2>F5>F4>F3. Mn was predominantly associated with the bound to carbonates fraction with the value of 103.3.±3.30 mg/kg (56.14%) and least in the exchangeable with the value of 1.30±1.85mg/kg (2.13%) its occurred in the order F2>F3>F4>F5>F1. The concentration of Fe was highest in the residual fraction with the value of 25.90±1.75mg/kg (45.45%)and least in the carbonate bound fraction wi th 5.10±0.40 mg/kg (2.13%) the order is F5>F4>F3>F2>F1. Pb was not detected in most of the fraction but highest in bond to carbonate and bond to organic matter fraction with the values of 6.64±4.12 mg/Kg (70.64 %) and 2.76±0.10 mg/Kg (29.36 %) respectively in two different samples. It was however established that Zn, Mn and Pb were mostly associated with the first three fractions thus, showed high bio-availabilty whereas Fe was found in the residual fraction and is expected to be low in mobility and less bioavailable. 


2015 ◽  
Vol 39 (4) ◽  
pp. 1068-1078 ◽  
Author(s):  
José Alberto Ferreira Cardoso ◽  
Augusto Miguel Nascimento Lima ◽  
Tony Jarbas Ferreira Cunha ◽  
Marcos Sales Rodrigues ◽  
Luis Carlos Hernani ◽  
...  

Improper land use has lead to deterioration and depletion of natural resources, as well as a significant decline in agricultural production, due to decreased soil quality. Removal of native vegetation to make way for agricultural crops, often managed inadequately, results in soil disruption, decreased nutrient availability, and decomposition of soil organic matter, making sustainable agricultural production unviable. Thus, the aim of the present study was to evaluate the impact of growing irrigated mango (over a 20 year period) on the organic carbon (OC) stocks and on the fractions of soil organic matter (SOM) in relation to the native caatinga (xeric shrubland) vegetation in the Lower São Francisco Valley region, Brazil. The study was carried out on the Boa Esperança Farm located in Petrolina, Pernambuco, Brazil. In areas under irrigated mango and native caatinga, soil samples were collected at the 0-10 and 10-20 cm depths. After preparing the soil samples, we determined the OC stocks, carbon of humic substances (fulvic acid fractions, humic acid fractions, and humin fractions), and the light and heavy SOM fractions. Growing irrigated mango resulted in higher OC stocks; higher C stocks in the fulvic acid, humic acid, and humin fractions; and higher C stocks in the heavy and light SOM fraction in comparison to nativecaatinga, especially in the uppermost soil layer.


2020 ◽  
Vol 36 (3) ◽  
Author(s):  
Jeferson Tiago Piano ◽  
Carlos Augusto Rocha De Moraes Rego ◽  
Andressa Perini Vengen ◽  
Jonas Francisco Egewarth ◽  
Vanessa Aline Egewarth ◽  
...  

The objective of this work was to evaluate the carbon content of the physical, chemical and oxidizable fractions of soil organic matter (SOM) and to calculate the carbon management index (CMI) in an area managed under an integrated crop-livestock system (ICLS) in the western region of Paraná - Brazil. The experiment was carried out at the experimental farm, belonging to the Universidade Estadual do Oeste do Paraná. Seventeen areas, which are managed in different ways, fifteen in ICLS and two areas of controls (Forest and Haymaking), using the design divided with two nested controls, with three replications were evaluated. Deformed and undisturbed soil samples were collected from all the areas to determine the total organic carbon (TOC), carbon stock, the physical, chemical and oxidizable fractions of SOM and the CMI in the layers of 0-0.05, 0.05-0.1 and 0.1-0.2 m. Little significant changes in the fractions were found for the management of the ICLS area in relation to the Forest and the area of Haymaking, although the Forest presented the best values for most of the studied fractions. It is recommended to adopt sustainable practices, such as ICLS, even though the average fractions tend to take time to match reference areas.


2019 ◽  
Vol 182 (5) ◽  
pp. 772-781
Author(s):  
Anna Kühnel ◽  
Martin Wiesmeier ◽  
Peter Spörlein ◽  
Bernd Schilling ◽  
Ingrid Kögel-Knabner

Radiocarbon ◽  
1976 ◽  
Vol 18 (3) ◽  
pp. 268-289 ◽  
Author(s):  
H W Scharpenseel ◽  
F Pietig ◽  
H Schiffmann

Radiocarbon measurements are carried out mainly on soil samples and soil organic matter fractions. Benzene samples are prepared as described earlier (Scharpenseel and Pietig, 1969; 1970). Radioactivity is measured in a single quartz vial, using a Packard Tri Carb Model 3075 as well as a Berthold Betascint BF 5000. Most equipment has been transferred from Bonn University Radiocarbon Dating Lab to Hamburg, where operation of former Bonn Radiocarbon Lab will be continued.


2016 ◽  
Vol 25 (1) ◽  
pp. 19-25
Author(s):  
Kalpana Begum ◽  
Md Faruque Hossain ◽  
Zakia Parveen

An investigation was conducted to determine the distribution and concentrations of different forms of Zn in the soils of Gazipur. Gerua, Kalma and Khilgaon soil series were identified in three land types, named as highland, medium high land and medium low land, respectively. Soil samples were collected from each soil series at three different depth such as surface (0 -15 cm), subsurface (15 -40 cm) and substratum (40 cm+) to determine soil characteristics and the distribution pattern of Zn fractions. Results indicated that amount of total Zn varied significantly, ranges from 14.99 to 36.11 ?g/g at different depth of different land types. Moreover, the purpose of the sequential extraction or fractionation was to find out the Zn in the exchangeable (Exch.), organic matter (Org.) bound, Mn oxide (Mn-O), amorphous Fe oxide (Am. Fe-O), crystalline Fe oxide (Crys. Fe-O) and residual (Res.) fractions. In Gerua, Kalma and Khilgaon soils, Zn concentrations predominated in Res. followed by Crys. Fe-O and Am. Fe-O fractions. Results reflected that soil properties influence the distribution of different Zn fractions in soils.Dhaka Univ. J. Biol. Sci. 25(1): 19-25, 2016


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