scholarly journals V2O5 as magnesium cathode material with extended cyclic stability

2020 ◽  
Vol 10 (3) ◽  
pp. 256-262 ◽  
Author(s):  
Charalampos Drosos ◽  
Benjamin Moss ◽  
Andreas Kafizas ◽  
Dimitra Vernardou
Keyword(s):  
Cathode Material ◽  
Aqueous Electrolyte ◽  
Coulombic Efficiency ◽  
Chemical Vapour ◽  
Cyclic Stability ◽  
Cycle Stability ◽  
Large Area ◽  
Capacity Retention ◽  
Specific Discharge ◽  
Extended Cycle

In this work, the electrochemical performance of aerosol-assisted chemical vapour deposited vanadium pentoxide cathodes at 600 °C, is presented. The as-grown oxides indicate specific discharge capacity of 300 mA h g-1 with capacity retention of 92 % after 10000 scans, coulombic efficiency of 100 %, noble structural stability and high reversibility. The present study shows the possibility to grow large-area magnesium cathode material with extended cycle stability via utilization of an aqueous electrolyte under a corrosive environment. This enhanced performance may be a combination of electrode morphology and adherence, when compared to previous work employing electrode growth temperature at 500 °C.

scholarly journals Electrochemical Performance of \(\text{Na}_{0.44}\text{MnO}_{2}\) Synthesized by Hydrothermal Method Using as a Cathode Material for Sodium Ion Batteries

2017 ◽  
Vol 27 (2) ◽  
pp. 143 ◽  
Author(s):  
Tan Anh Ta ◽  
Long Duy Pham ◽  
Hieu Sy Nguyen ◽  
Chung Vu Hoang ◽  
Chi Ha Le ◽  
...  
Keyword(s):  
Cathode Material ◽  
Hydrothermal Method ◽  
Coulombic Efficiency ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Cycle Stability ◽  
Capacity Retention ◽  
Scanning Electron Microscope Analysis ◽  
Electron Microscope Analysis ◽  
Discharge Capacities

Orthorhombic Na0.44MnO2 with an S-shape tunnel structure was successfully synthesized by a hydrothermal method. The Na0.44MnO2 material has lattice parameters of a = 9.0842 Å, b = 26.2889 Å, and c = 2.8245 Å. Scanning electron microscope analysis reveals that the morphologies of Na0.44MnO2 consist of Na0.44MnO2 nanowires with diameters of about 30-50 nm and Na0.44MnO2 particles with the size in the range of 200 to 500 nm. The first charge and discharge capacities of Na0.44MnO2 cathode, at 0.1 C between 2.0-4.0 V, are 66.2 mAh g-1 and 62.7 mAh g-1, respectively. The Na0.44MnO2 has an excellent cycle stability with 85.3% of capacity retention over 50 cycles. The coulombic efficiency of Na0.44MnO2 material is approximately 90% after 70 cycles. It is suggested that the structure of Na0.44MnO2 is stable during cycling and Na0.44MnO2 can be a promising cathode material for sodium ion batteries.

Fabrication of layered Ti3C2 with an accordion-like structure as a potential cathode material for high performance lithium–sulfur batteries

2015 ◽  
Vol 3 (15) ◽  
pp. 7870-7876 ◽  
Author(s):  
Xiaoqin Zhao ◽  
Min Liu ◽  
Yong Chen ◽  
Bo Hou ◽  
Na Zhang ◽  
...  
Keyword(s):  
Cathode Material ◽  
Discharge Capacity ◽  
High Performance ◽  
Coulombic Efficiency ◽  
Initial Discharge Capacity ◽  
Capacity Retention ◽  
Initial Discharge ◽  
Lithium Sulfur Batteries ◽  
Lithium Sulfur

L-Ti3C2 was prepared by exfoliating Ti3AlC2 in 40% HF. With sulfur-loaded L-Ti3C2 as cathodes, Li–S batteries deliver a high initial discharge capacity of 1291 mA h g−1, an excellent capacity retention of 970 mA h g−1 and coulombic efficiency of 99% after 100 cycles.

scholarly journals In Situ Carbon Coated LiNi0.5Mn1.5O4 Cathode Material Prepared by Prepolymer of Melamine Formaldehyde Resin Assisted Method

2016 ◽  
Vol 2016 ◽  
pp. 1-5 ◽  
Author(s):  
Wei Yang ◽  
Haifeng Dang ◽  
Shengzhou Chen ◽  
Hanbo Zou ◽  
Zili Liu ◽  
...  
Keyword(s):  
Cathode Material ◽  
Discharge Capacity ◽  
Lithium Ion ◽  
Formaldehyde Resin ◽  
Melamine Formaldehyde ◽  
Capacity Retention ◽  
Melamine Formaldehyde Resin ◽  
Carbon Coated ◽  
Specific Discharge ◽  
Face Centered

Carbon coated spinel LiNi0.5Mn1.5O4 were prepared by spray-drying using prepolymer of melamine formaldehyde resin (PMF) as carbon source of carbon coating layer. The PMF carbon coated LiNi0.5Mn1.5O4 was characterized by XRD, SEM, and other electrochemical measurements. The as-prepared lithium nickel manganese oxide has the cubic face-centered spinel structure with a space group of Fd3m. It showed good electrochemical performance as a cathode material for lithium ion battery. After 100 discharge and charge cycles at 0.5 C rate, the specific discharge capacity of carbon coated LiNi0.5Mn1.5O4 was 130 mAh·g−1, and the corresponding capacity retention was 98.8%. The 100th cycle specific discharge capacity at 10 C rate of carbon coated LiNi0.5Mn1.5O4 was 105.4 mAh·g−1, and even the corresponding capacity retention was 95.2%.

scholarly journals Hydrothermal Synthesis of Li2MnO3-Stabilized LiMnO2 as a Cathode Material for Li-Ion Battery

2021 ◽  
Vol 2021 ◽  
pp. 1-6
Author(s):  
Ngoc Hung Vu ◽  
Van-Duong Dao ◽  
Hong Ha Thi Vu ◽  
Nguyen Van Noi ◽  
Dinh Trinh Tran ◽  
...  
Keyword(s):  
Cathode Material ◽  
High Performance ◽  
Low Cost ◽  
High Capacity ◽  
Environmentally Benign ◽  
Li Ion Battery ◽  
Cycle Stability ◽  
Capacity Retention ◽  
Li Ion ◽  
Potential Strategy

Herein, we reported the composite structure of LiMnO2 and Li2MnO3 as a low-cost and environmentally benign cathode material. This composite with the main phase of LiMnO2 (90%) was synthesized by hydrothermal method at 220°C from LiOH and Mn(CH3COO)2 precursors. The obtained nanosized LiMnO2-LiMnO3 cathode material exhibits a high capacity of 265 mAh g-1 at C/10. The incorporation of Li2MnO3 into the LiMnO2 phase could stabilize the structure, leading to the improved cycle stability of the cathode. The capacity retention of the cathode was 93% after 80 cycles at C/2. Our results facilitate a potential strategy for developing high-performance cathode materials based on the Li-Mn-O system.

A high capacity thiospinel cathode for Mg batteries

2016 ◽  
Vol 9 (7) ◽  
pp. 2273-2277 ◽  
Author(s):  
Xiaoqi Sun ◽  
Patrick Bonnick ◽  
Victor Duffort ◽  
Miao Liu ◽  
Ziqin Rong ◽  
...  
Keyword(s):  
Cathode Material ◽  
High Capacity ◽  
Capacity Retention ◽  
Full Cell

A Mg full cell with a thiospinel cathode material shows 190 mA h g−1 capacity and relatively stable capacity retention.

Boosting cycle stability of NCM811 cathode material via 2D Mg-Al-LDO nanosheet coating for lithium-ion battery

2021 ◽  
Vol 867 ◽  
pp. 159079
Author(s):  
Wenchao Liu ◽  
Feng Gao ◽  
Yunhao Zang ◽  
Jiangying Qu ◽  
Jin Xu ◽  
...  
Keyword(s):  
Cathode Material ◽  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Cycle Stability

An inorganic–organic nanocomposite calix[4]quinone (C4Q)/CMK-3 as a cathode material for high-capacity sodium batteries

2017 ◽  
Vol 4 (11) ◽  
pp. 1806-1812 ◽  
Author(s):  
Shibing Zheng ◽  
Jinyan Hu ◽  
Weiwei Huang
Keyword(s):  
Cathode Material ◽  
Discharge Capacity ◽  
High Capacity ◽  
Initial Discharge Capacity ◽  
Capacity Retention ◽  
Initial Discharge ◽  
Sodium Batteries

A novel high-capacity cathode material C4Q/CMK-3 for SIBs shows an initial discharge capacity of 438 mA h g−1 and a capacity retention of 219.2 mA h g−1 after 50 cycles.

Neutron Detectors Made From Chemically Vapour Deposited Semiconductors

1997 ◽  
Vol 487 ◽  
Author(s):  
F. Foulon ◽  
P. Bergonzo ◽  
A. Brambilla ◽  
C. Jany ◽  
B. Guizard ◽  
...  
Keyword(s):  
Detection Efficiency ◽  
Low Cost ◽  
Chemical Vapour ◽  
Polycrystalline Diamond ◽  
Neutron Detection ◽  
Large Area ◽  
Neutron Detectors ◽  
Gadolinium Isotope ◽  
Neutron Detection Efficiency ◽  
Hydrogenated Amorphous

AbstractIn this paper, we present the results of investigations on the use of semiconductors deposited by chemical vapour deposition (CVD) for the fabrication of neutron detectors. For this purpose, 20 μm thick hydrogenated amorphous silicon (a-Si:H) pin diodes and 100 μm thick polycrystalline diamond resistive detectors were fabricated. The detectors were coupled to a neutron-charged particle converter : a layer of either gadolinium or boron (isotope 10 enriched) deposited by evaporation. We have demonstrated the capability of such neutron detectors to operate at neutron fluxes ranging from 101 to 106 neutrons/cm2.s. The fabrication of large area detectors for neutron counting or cartography through the use of multichannel reading circuits is discussed. The advantages of these detectors include the ability to produce large area detectors at low cost, radiation hardness (∼ 4 Mrad for a-Si:H and ∼ 100 Mrad for diamond), and for diamond, operation at temperatures up to 500°C. These properties enable the use of these devices for neutron detection in harsh environments. Thermal neutron detection efficiency up to 22 % and 3 % are expected by coupling a-Si:H diodes and diamond detectors to 3 μm thick gadolinium (isotope 157) and 2 μm thick boron layers, respectively.

LaPO4-coated Li1.2Mn0.56Ni0.16Co0.08O2 as a cathode material with enhanced coulombic efficiency and rate capability for lithium ion batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (94) ◽  
pp. 77324-77331 ◽  
Author(s):  
Qingliang Xie ◽  
Chenhao Zhao ◽  
Zhibiao Hu ◽  
Qi Huang ◽  
Cheng Chen ◽  
...  
Keyword(s):  
Cathode Material ◽  
Lithium Ion Batteries ◽  
Coulombic Efficiency ◽  
Rate Capability ◽  
Lithium Ion ◽  
Combustion Method ◽  
Chemical Precipitation ◽  
Porous Microspheres

Layered Li[Li0.2Mn0.56Ni0.16Co0.08]O2 porous microspheres have been successfully synthesized by a urea combustion method, and then coated with appropriate amount of LaPO4via a facile chemical precipitation route.

scholarly journals Atomic layer deposited V2O5 coatings: a promising cathode for Li-ion batteries

2019 ◽  
Vol 10 (1) ◽  
pp. 21-28
Author(s):  
Martyn Pemble ◽  
Ian Povey ◽  
Dimitra Vernardou
Keyword(s):  
Vanadium Pentoxide ◽  
Coulombic Efficiency ◽  
Lithium Ion ◽  
Chemical Vapor ◽  
Atomic Layer ◽  
Deposition Process ◽  
Chemical Vapor Deposition Growth ◽  
Layer Deposition ◽  
Specific Discharge ◽  
Cathodic And Anodic Processes

A modified, thermal atomic layer deposition process was employed for the pulsed chemical vapor deposition growth of vanadium pentoxide films using tetrakis (dimethylamino) vanadium and water as a co-reagent.Depositions were carried out at 350oC for 400 pulsed CVD cycles, and samples were subsequently annealed for 1hour at 400°C in air to form materials with enhanced cycling stability during the continuous lithium-ion intercala­tion/deintercalation processes. The diffusion coefficient was estimated to be 2.04x10-10 and 4.10x10-10 cm2 s-1 for the cathodic and anodic processes, respectively. These values are comparable or lower than those reported in the literature, indicating the capability of Li+ of getting access into the vanadium pentoxide framework at a fast rate. Overall, it presents a specific discharge capacity of 280 mAh g-1, capacity retention of 75 % after 10000 scans, a coulombic efficiency of 100 % for the first scan, dropping to 85 % for the 10000th scan, and specific energy of 523 Wh g-1.

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