scholarly journals Synthesis of Lauric-Myristic Acid/Activated Carbon Composite as a New Shape-Stabilized Energy Storage Material

2021 ◽  
Author(s):  
Yanghua Chen ◽  
Minrong GE ◽  
Feng ZHAO ◽  
Xue YANG

In this work, a new composite phase change material (CPCM) with lauric-myristic acid (LA-MA) eutectic as PCM and activated carbon (AC) was used as supporting material with four different mass ratios of 5.0:5.0, 5.5:4.5, 6.0:4.0, and 6.5:3.5, respectively. The properties and microstructure of LA-MA/AC were analyzed by some characterization methods. The results show that the composite process of LA-MA eutectic and AC was a simple physical mixing and no new chemical bonds were found. The fusion and freeze temperature, enthalpy of the samples were measured by differential scanning calorimetry (DSC), and the residual weight of the samples was analyzed by thermogravimeter (TGA). It was shown that the fusion and freeze temperature of LA-MA eutectic separately were 32.42 ℃ and 33.63 ℃, and its fusion enthalpy and freeze enthalpy were 152.64 J/g and 148.8 J/g, respectively. TGA data shows that the thermal stability of LA-MA eutectic was obviously improved by adding AC as a support material. The results of this study can be available for reference to solar energy storage applications.

2021 ◽  
Author(s):  
Yanghua CHEN ◽  
Zhaohe WANG ◽  
Minrong GE ◽  
Feng ZHAO

In this study, hexadecanol-myristic acid (HD-MA) binary eutectic mixtures were adsorbed into activated carbon (AC) to prepare the composite phase transition materials(CPCMs). In the hexadecanol-myristic acid/activated carbon (HD-MA/AC) composites, the mixture of HD–MA acted as the phase change energy storage material and the AC was used as the matrix supporting material. Activated carbon is a kind of inorganic supporting material, which has developed pore structure, strong adsorption, high mechanical strength, corrosion resistance and good thermal stability. As the supporting material, activated carbon was helpful to prevent the eutectics from leakage. The chemical structure and crystal phase structure of HD-MA/AC composites were tested by FT-IR and XRD. The microstructure of the composites was observed through field emission scanning electron microscopy (FE-SEM). It was found that the organic binary eutectics were adsorbed on the surface and inside by activated carbon. Thermal properties of the composites were measured by differential scanning calorimetry (DSC). The results of performance test demonstrated that the satisfactory sample CPCM1 melted at 42.38 °C with latent heat of 76.24 J/g and solidified at 38.32 °C with latent heat of 67.08 J/g. The test results of TGA indicated that the prepared composites of hexadecanol-myristic acid/activated carbon possessed great thermal stability and high reliability. It is predicted that the shape-stabilized HD-MA/AC composites have great potential for thermal energy storage.


RSC Advances ◽  
2017 ◽  
Vol 7 (36) ◽  
pp. 22170-22177 ◽  
Author(s):  
Jie Han ◽  
Songyang Liu

The addition of activated carbon (10%) effectively enhances the thermal conductivity and heat transfer properties of the MA/H-diatomite-2 composite PCM.


2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
Arash Badakhsh ◽  
Kay-Hyeok An ◽  
Chan Woo Park ◽  
Byung-Joo Kim

Herein, simplified time-efficient production of AlN-coated SiC (SiC@AlN) ceramic powder was practiced. Short-term vibratory ball milling with high frequency was employed to integrate the microsize particles. Also, paraffin as a significant phase change material (PCM) was reinforced using the manufactured SiC@AlN in order to enhance the thermal conductivity (TC) and stability of the final composite. Various characterization methods were used to clarify the changes in particle size of the biceramic powder as well as the thermal features of the paraffin-based composite. Manufactured SiC@AlN was found to be the most effective in the improvement of interfacial adhesion of composite components and the subsequent enhancement of TC, compared with singular ceramic powders as the reinforcing agents. Also, differential scanning calorimetry (DSC) indicated a very slight increase in latent heat of the fabricated composite PCM.


2021 ◽  
pp. 152808372110417
Author(s):  
Zhou Zhao ◽  
Ningning Tong ◽  
Hong Song ◽  
Yan Guo ◽  
Jinmei Wang

In this work, a phase-change energy storage nonwoven fabric was made of polyurethane phase-change material (PUPCM) by a non-woven melt-blown machine. Polyethylene glycol 2000 was used as the phase transition unit and diphenyl-methane-diisocyanate as the hard segment to prepare PUPCM. Thermal stability of the PUPCM was evaluated through thermal stability analysis. The performance of pristine PUPCM was determined by Fourier transform infrared spectroscopy and differential scanning calorimetry to analyze the spinning technology of spinning temperature and the stretching process. Phase-change energy storage nonwoven fabric (413.22 g/m2) was prepared, and the morphology, solid–solid exothermic phase transition, mechanical properties, and the structures were characterized. The enthalpy of solid–solid exothermic phase transition reached 60.17 mJ/mg (peaked at 23.14°C). The enthalpy of solid–solid endothermic phase transition reached 67.09 mJ/mg (peaked at 34.34°C). The strength and elongation of phase-change energy storage nonwoven fabric were found suitable for garments and tent fabrics.


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