Charge Transfer Dye Probe for Thiol-containing Amino Acid

AbstractAn asymmetric organocatalytic nucleophilic aromatic substitution reaction of azlactones with electron-deficient aryls was established. A variety of α-aryl α-alkyl α-amino acid esters and peptides were obtained in decent yields and stereoselectivities. A new bifunctional catalytic mode involving charge-transfer interaction and hydrogen bonding is proposed to explain the enantioselectivity.

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Spectrophotometric study of the charge transfer complexation of some amino acid derivative drugs as electron donors with 7,7,8,8-tetracyanoquinodimethane

Bulletin of the Chemical Society of Ethiopia ◽

10.4314/bcse.v24i1.52957 ◽

2010 ◽

Vol 24 (1) ◽

Cited By ~ 3

Author(s):

Sheng Yun Li ◽

Qiao Lin Guo ◽

Wen Yuan ◽

Yu Cui Hou ◽

Li Ming Du

Keyword(s):

Charge Transfer ◽

Amino Acid ◽

Acid Derivative ◽

Spectrophotometric Study ◽

Electron Donors ◽

Amino Acid Derivative ◽

Charge Transfer Complexation

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ChemInform Abstract: CHARGE TRANSFER AS A MOLECULAR PROBE IN SYSTEMS OF BIOLOGICAL INTEREST, OR ELEKTRONEN-DONATOR-ACCEPTOR-KOMPLEXE BEI POLYPEPTIDEN PART 7, THE USE OF PARAQUAT AS AN NMR.- AND CHARGE-TRANSFER-PROBE FOR SOLVENT-EXPOSED AROMATIC AMINO-ACID

Chemischer Informationsdienst ◽

10.1002/chin.197510081 ◽

1975 ◽

Vol 6 (10) ◽

Author(s):

JAN W. VERHOEVEN ◽

ANNE-MARIE A. VERHOEVEN-SCHOFF ◽

ANDRE MASSON ◽

ROBERT SCHWYZER

Keyword(s):

Charge Transfer ◽

Amino Acid ◽

Aromatic Amino Acid ◽

Molecular Probe ◽

Biological Interest

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Amino-Acid-Induced Preferential Orientation of Perovskite Crystals for Enhancing Interfacial Charge Transfer and Photovoltaic Performance

Small ◽

10.1002/smll.201604305 ◽

2017 ◽

Vol 13 (22) ◽

pp. 1604305 ◽

Cited By ~ 44

Author(s):

Yen-Chen Shih ◽

Yu-Bing Lan ◽

Chia-Shuo Li ◽

Hsiao-Chi Hsieh ◽

Leeyih Wang ◽

...

Keyword(s):

Charge Transfer ◽

Amino Acid ◽

Photovoltaic Performance ◽

Preferential Orientation ◽

Interfacial Charge Transfer ◽

Interfacial Charge

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Amide Tricobaltcarbon Clusters With Multiple Redox Centers

Australian Journal of Chemistry ◽

10.1071/ch9861435 ◽

1986 ◽

Vol 39 (9) ◽

pp. 1435 ◽

Cited By ~ 6

Author(s):

BH Robinson ◽

J Simpson ◽

ME Trounson

Keyword(s):

Charge Transfer ◽

Amino Acid ◽

Electronic Effects ◽

Acid Moiety ◽

Amide Linkage ◽

Substituent Group ◽

Irreversible Oxidation ◽

Amino Acid Moiety ◽

Intervalence Charge Transfer ◽

Redox Centers

The complexes FcNHC (O)CCo3(CO)9 ( Fc = ferrocenyl ) (3) and Fc ( alaOMe )C(O)CCo3(CO)9 (ala = alanine ) (5) have been synthesized from the +C(O)CCo3(CO)9 cation and FcNH2 or Fc ( alaOMe )H respectively. Derivatives FcNHC (O)CCo3(CO)6[P( OPh )3]3 (4) and Fc ( alaOMe )C(O)CCo3(CO)6[P( OPh )3]3 (6) are also described. Analysis of the spectroscopic and redox behaviour shows that the amide linkage acts as a -I, -M substituent group to Fc and the Co3C unit acts as a-I, +M group. Unlike complexes where these redox centres are directly linked, electronic effects are not transmitted between Co3C and Fc . Oxidation at the ferrocene centre and reduction at the Co3C centre in (3) and (5) is chemically reversible whereas oxidation of the amino acid moiety is irreversible; oxidation of the cluster takes place in (4) and (6) but no intervalence charge transfer is observed.

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