scholarly journals Latvijas minerālās izejvielas eko-keramikas izstrādei

2018 ◽  
Vol 35 ◽  
pp. 62-85
Author(s):  
Gaida Sedmale ◽  
Māris Rundāns ◽  
Mārtiņs Randers ◽  
Ingunda Šperberga ◽  
Andris Cimmers

Darbā dots ieskats par iespējām izmantot Latvijas minerālās izejvielas kā bāzi vai  piedevu  keramikas  materiālu  (eko-materiālu)  izstrādei ar dažādu pielietošanas aspektu, to skaitā parādīt iespēju šo materiālu ieguves tehnoloģisko procesu optimizēšanai virzībā uz to apdedzināšanas temperatūras samazināšanu, līdz ar to reducējot kaitīgu gāzveida izmešu nonākšanu vidē. Parādīti darbu rezultāti laika periodā no 2007. g. līdz 2017. g. Tiek apskatīti un analizēti sekojoši pētījumi:neapstrādāta māla pielietošana atkritumu deponēšanas vietu noblīvēšanai;daļēji dehidratizēta māla pielietošana Cr3+, Cr6+, Zn2+ un Cu+ jonu sorbcijai, kas veidojas galvanisko procesu notekūdeņos; poru saturošas augsttemperatūras keramikas izstrāde no jauktiem izejvielu maisījumiem, kas nodrošina pietiekamu gāzveida fāzes izveidošanos keramikas apdedzināšanas procesā, veidojot poras, lai pielietotu par filtrēšanas/attīrīšanas materiālu;illīta māla piedevu izmantošana, lai pazeminātu augsttemperatūras blīvas keramikas saķepināšanas/apdedzināšanas temperatūru, iegūstot ilgspējīgu mehāniski un termiski izturīgu produktu; kā arī tehnoloģiskie procesi, kas nodrošina porainas, siltumu izolējošas keramikas materiāla ieguvi pie pazeminātām temperatūrām (ģeopolimēru metode).Mineral Raw Materials of Latvia for Development of Eco-CeramicsThe paper gives an insight into the possibilities to use Latvian mineral raw materials as a base or additives for the development of ceramic materials (eco- materials) with different application aspects, including showing the possibility of optimizing the technological processes of these materials towards the reduction of their firing temperature, thereby reducing the release of harmful gaseous effluents into the environment.The results of the works that are reported in the period were obtained from  2007 to 2017. The following studies are reviewed and analyzed: the use of untreated clay for the sealing of waste deposits; the use of partly dehydrated clay for sorption of Cr3+,6+, Zn2+ and Cu2+, which have formed in galvanic processes; the development of porous high temperature ceramics from mixes  of mineral raw materials and synthetic additives that provide a sufficient gas phase  formation in the firing process and consecutively to form pores in obtained ceramic material; the use of illite clay additives to reduce the temperature of sintering of high temperature dense mechanical and thermally durable ceramics, as well as technological processes that ensure the production of porous, heat-insulating ceramic materials at reduced temperatures (geopolymer method).

2015 ◽  
Vol 47 (1) ◽  
pp. 58-66 ◽  
Author(s):  
Farit Kh. Urakaev ◽  
Kenzhebek A. Akmalaev ◽  
Eljan S. Orynbekov ◽  
Beykut D. Balgysheva ◽  
Dinar N. Zharlykasimova

2020 ◽  
Vol 22 (27) ◽  
pp. 15381-15388
Author(s):  
Long Zhao ◽  
Ralf I. Kaiser ◽  
Wenchao Lu ◽  
Musahid Ahmed ◽  
Artem D. Oleinikov ◽  
...  

1H-Phenalene can be synthesized via the reaction of the 1-naphthyl radical with methylacetylene and allene under high temperature conditions prevalent in carbon-rich circumstellar environments and combustion systems.


2020 ◽  
Vol 166 ◽  
pp. 02002
Author(s):  
Ihor Kholoshyn ◽  
Natalia Panteleeva ◽  
Oleksandr Trunin ◽  
Liudmyla Burman ◽  
Olga Kalinichenko

Infrared spectroscopy (IR) is a highly effective method for the analysis of minerals, rocks and ores, capable of solving a whole range of problems when choosing innovative solutions for the technological processing of various types of mineral raw materials. The article considers the main directions of using the infrared spectroscopy method in assessing the technological properties of minerals and their behavior in technological processes: evaluation of the grade (quality) of mineral raw materials; analysis of the behavior of minerals in the technological process with prediction of their technological properties; analysis of changes in the structure and properties of minerals in technological processes; operational analysis of mineral substances at various stages of technological processing. The article illustrates all aspects of the use of infrared spectroscopy at various stages of studying the material composition of mineral raw materials in its enrichment assessment by specific examples of solving problems arising from the technological redistribution of various types of ore and non-metallic minerals.


2010 ◽  
Vol 150-151 ◽  
pp. 1234-1238
Author(s):  
Rong Lin Wang ◽  
Jia Lin Sun ◽  
Jing Long Bu ◽  
Zhi Fa Wang

Al-ZrO2 composites were sintered in N2 atmosphere at 1000 oC, 1100 oC, 1200 oC and 1300 oC with ZrO2 and Al powders as raw materials. Formation mechanism of AlZrO and ZrAlON phases in Al-ZrO2-N2 systems were investigated by TG-DTA, XRD, SEM and EDS analyses. Results showed there existed new phases of ZrAl3O3N and AlxZr1-xO2-0.5x beside ZrO, ZrN, Al2O3, AlN and intermediate phases of Al7O3N5, Al8O3N6, ZrON, ZrON2, Zr7O8N4 in samples sintered at 1000 oC to 1300 oC. There existed process of mass transfer of ZrO2 in gas phase in samples at high temperature. Dynamics processes of ZrAl3O3N and AlxZr1-xO2-0.5x phases formed in N2 atmosphere at high temperature included contact reaction and ZrAlON sosoloid crystallization.


2014 ◽  
Vol 602-603 ◽  
pp. 451-456
Author(s):  
Jie Guang Song ◽  
Xiu Qin Wang ◽  
Fang Wang ◽  
Shi Bin Li ◽  
Gang Chang Ji

ZrB2, YAG and Al2O3 are widely applied because of some excellent performances, but ZrB2 is easily oxidized in the high-temperature air. To make the ZrB2 ceramics obtain better oxidation resistance, high-density ZrB2-YAG-Al2O3 ceramics were prepared. The influences of coated composite powders on the densification and the oxidation resistance of ZrB2-YAG-Al2O3 ceramics were investigated. The 80wt%ZrB2-YAG-Al2O3 multiphase ceramic materials from different composite raw materials with the spark plasma sintering technique were successfully prepared. The densification of ZrB2-YAG-Al2O3 ceramics with Al2O3-Y2O3 composite powder coated is easier than that of ZrB2-YAG-Al2O3 ceramics with YAG-Al2O3 powder mixed. The reaction temperature is lower than the 1100¡æ for synthesizing YAG powders from Al2O3-Y2O3 composite powders. The weight gain are increased with increased the oxidation temperature. B2O3 is reacted with Al2O3 to form Al18B4O33, Al18B4O33 is melted and coated on the surface of ceramics to form a protective layer for the oxidation resistance of ceramics at high temperature. The oxidation weight gain of ZrB2-YAG-Al2O3 ceramic with Al2O3-Y2O3 composite powder coated is lower than that of ZrB2-YAG-Al2O3 ceramic with YAG-Al2O3 powder mixed.


2018 ◽  
Vol 163 ◽  
pp. 06004 ◽  
Author(s):  
Mateusz Sitarz ◽  
Izabela Hager ◽  
Joanna Kochanek

The advent of modern aluminosilicate binders has resulted in practical uses for fly ash, which belongs to the group of secondary mineral raw materials; this provides an interesting alternative to cementitious binders, which have a large carbon footprint. Geopolymers mineral binders with a growing range of applications in construction. Their inorganic, amorphous structure endows them with better resistance to high temperature compared to cementitious binders. In this study, the alkaline activation of aluminosilicate Połaniec Fly Ash made it possible to obtain noncementitious material with compressive strength of 18.5 MPa. The article presents the results of a comparison of characteristics of geopolymer mortar and Portland cement mortar after thermal exposure.


2002 ◽  
Vol 74 (11) ◽  
pp. 2083-2096 ◽  
Author(s):  
H. Altenburg ◽  
J. Plewa ◽  
G. Plesch ◽  
O. Shpotyuk

The use of thick films becomes more and more important in particular for electronic and microelectronic applications. The term “thick film ” does not relate so much to the thickness of the film but more to the kind of deposition. Thick films are made by low-priced processes such as doctor (dr) blading, screen-printing, or spraying methods, etc. The preparation of thick films of ceramic material by these methods generally implies a processing sequence of the following steps: preparation of the oxide powders; preparation of pastes and slurries; painting/printing, etc.of the pastes onto a suitable substrate; drying at low temperature; and sintering at high temperature to get a consolidated layer. These technologies and the fabricated thick films of thermoresistive and superconducting materials will be discussed.


2005 ◽  
Vol 475-479 ◽  
pp. 1497-1502
Author(s):  
C.H. Wu

In the framework of the European Fusion Research Program, a great effort has been made to develop an innovative carbon-based ceramic material to meet all of all operational requirements. After a decade of research and development, It is succeeded to develop an advanced material: namely, a 3D CFC, contains about 8-10 at% of Silicon with porosity is about 3-5% . This advanced ceramic material possess very high thermal conductivity, dimensional stability under the neutron irradiation, lower chemical erosion (longer life time), lower tritium retention and lower reactivity with water and oxygen (safety concern) . This innovative ceramic materials seems very promising for application in the high temperature, neutron and hydrogen environment. A detailed discussion on development , properties and application of material is presented.


2021 ◽  
Vol 35 (3) ◽  
pp. 2425-2433
Author(s):  
Zhongli He ◽  
Bing Song ◽  
Cai Liang ◽  
Bin Liu ◽  
Zhirui Ma ◽  
...  

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