The Effect of Temperature on Sulfuric Acid-Catalyzed Hydrolysis of Oil Palm Frond to Levulinic Acid

2015 ◽  
Vol 4 (1) ◽  
pp. 52-55
Author(s):  
A. Awaluddin ◽  
A. Kurnia ◽  
A. Prayitno ◽  
E. Saputra ◽  
Saryono
Author(s):  
F S Hashim ◽  
H W Yussof ◽  
M A K M Zahari ◽  
R A Rahman ◽  
R M Illias

2014 ◽  
Vol 202 (9) ◽  
pp. 1235-1244 ◽  
Author(s):  
Hadi Amirkhani ◽  
Robiah Yunus ◽  
Umer Rashid ◽  
Shanti Faridah Salleh ◽  
A. B. Dayang Radhiah ◽  
...  

2014 ◽  
Vol 71 (1) ◽  
Author(s):  
Nur Aainaa Syahirah Ramli ◽  
Nor Aishah Saidina Amin ◽  
Ismail Ware

The pretreatment of oil palm frond (OPF) has been carried out using 1-butyl-3-methylimidazolium bromide ([BMIM]Br) in the presence of aqueous sulphuric acid (H2SO4). The effects of reaction temperature, reaction time and [BMIM]Br loading on lignin degradation were investigated by applying Box Behnken Design of Response Surface Methodology (RSM). The optimized process condition for OPF pretreatment were 123°C, 175 min and 9.9 g of [BMIM]Br loading with an optimum lignin degradation of 88.2%. The experimental results fitted-well with the predicted value with less than 5% error. It was also demonstrated that lignin degradation using recycled [BMIM]Br gave sufficient performance for five successive runs. It was revealed from SEM and XRD analyses, that the pretreated OPF was porous and less crystalline after pretreatment. Consequently, the pretreated OPF renders 25.3% levulinic acid yield in acid hydrolysis compared to 18.2% yield for untreated OPF.


2019 ◽  
Vol 12 (2) ◽  
pp. 359-369 ◽  
Author(s):  
Muzakkir Mohammad Zainol ◽  
Nor Aishah Saidina Amin ◽  
Mohd Asmadi ◽  
Nur Aainaa Syahirah Ramli

2012 ◽  
Vol 550-553 ◽  
pp. 103-106
Author(s):  
Ying Liu ◽  
Lu Lin ◽  
Xiao Yu Sui ◽  
Jun Ping Zhuang ◽  
Chun Sheng Pang

The effects of catalyst amount on the yields of levulinic and hydroxymethyl furfural were investigated during conversion of glucose to levulinic acid catalyzed by solid super acid SO42- / TiO2-Al2O3-SnO2. XRD and XPS were used to analyse the characteristics of solid super acid SO42- / TiO2-Al2O3-SnO2 before reaction and after reaction. The results showed that: solid super acid SO42- / TiO2-Al2O3-SnO2exhibited good catalytic activity in the reaction of hydrolysis of glucose to produce levulinic acid. There were three obvious peaks in these XRD spectra. The peaks on 44.6° and 67.1° were the characteristic diffraction peaks of γ-Al2O3. The anatase characteristic diffraction peak was on 37.4°. The catalyst was steady in the process. The binding energy of S 2p was similar to the binding energy of standard S6+ 2p in the S 2p XPS spectrum of solid super acid. O 1s XPS was double-peaked spectrum. The increase of element C was the main reason of inactivation of catalyst.


2014 ◽  
Vol 893 ◽  
pp. 488-491 ◽  
Author(s):  
Elfarizanis Baharudin ◽  
Alyani Ismail ◽  
Adam Reda Hasan Alhawari ◽  
Edi Syams Zainudin ◽  
Dayang L.A. Majid ◽  
...  

This paper presents the results on dielectric properties of pulverized material based on agricultural waste namely oil palm frond and pineapple leaf fiber for microwave absorber application in the X-band frequency range. The investigation is started by identifying the pulverized materials permittivities and loss tangents using coaxial probe technique, followed by density measurement comprising the determination of bulk and solid densities. Then, by using dielectric mixture model, the solid particle dielectric properties were determined. It is observed that the air properties give quite an effect on the permittivity and loss tangent of the pulverized materials. It is also found that the lower the material density the higher material dielectric constant will be. Furthermore, the results show that, both oil palm frond and pineapple leaf fiber are potential to be X-band absorber with average dielectric constant of 4.40 and 3.38 respectively. The loss tangents for both materials were observed to be more than 0.1 which mark them as lossy materials.


Author(s):  
Siti Nur Ridhwah Muhamed Ramli ◽  
Tengku Elida Tengku Zainal Mulok ◽  
Sabiha Hanim Mohd Salleh ◽  
Khalilah Abdul Khalil ◽  
Othman Ahmad ◽  
...  

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