Optimization of Oil Palm Fronds Pretreatment Using Ionic Liquid for Levulinic Acid Production

2014 ◽  
Vol 71 (1) ◽  
Author(s):  
Nur Aainaa Syahirah Ramli ◽  
Nor Aishah Saidina Amin ◽  
Ismail Ware
Keyword(s):  
Oil Palm ◽  
Levulinic Acid ◽  
Lignin Degradation ◽  
Process Condition ◽  
Temperature Reaction ◽  
Acid Yield ◽  
Box Behnken Design ◽  
Oil Palm Frond ◽  
Palm Fronds ◽  
Palm Frond

The pretreatment of oil palm frond (OPF) has been carried out using 1-butyl-3-methylimidazolium bromide ([BMIM]Br) in the presence of aqueous sulphuric acid (H2SO4). The effects of reaction temperature, reaction time and [BMIM]Br loading on lignin degradation were investigated by applying Box Behnken Design of Response Surface Methodology (RSM). The optimized process condition for OPF pretreatment were 123°C, 175 min and 9.9 g of [BMIM]Br loading with an optimum lignin degradation of 88.2%. The experimental results fitted-well with the predicted value with less than 5% error. It was also demonstrated that lignin degradation using recycled [BMIM]Br gave sufficient performance for five successive runs. It was revealed from SEM and XRD analyses, that the pretreated OPF was porous and less crystalline after pretreatment. Consequently, the pretreated OPF renders 25.3% levulinic acid yield in acid hydrolysis compared to 18.2% yield for untreated OPF.

scholarly journals Effects of supplementation with phosphorus, calcium and manganese during oil palm frond fermentation by Phanerochaete chrysosporium on ligninase enzyme activity

2020 ◽  
Vol 21 (5) ◽  
Author(s):  
Roni Pazla ◽  
Novirman Jamarun ◽  
Fauzia Agustin ◽  
Mardiati Zain ◽  
Arief Arief ◽  
...  
Keyword(s):  
Enzyme Activity ◽  
Phanerochaete Chrysosporium ◽  
Oil Palm ◽  
Manganese Peroxidase ◽  
Crude Protein ◽  
Lignin Degradation ◽  
Lignin Content ◽  
Oil Palm Frond ◽  
Range Test ◽  
Palm Frond

Abstract. Pazla R, Jamarun N, Agustin F, Zain M, Cahyani NO. 2020. Effects of supplementation with phosphorus, calcium and manganese during oil palm frond fermentation by Phanerochaete chrysosporium on ligninase enzyme activity. Biodiversitas 21: 1833-1838. The objective of this study was to evaluate the effects of supplementation with phosphorus (P) in combination with calcium (Ca) and manganese (Mn) during oil palm frond (OPF) fermentation by Phanerochaete chrysosporium on ligninase enzyme activity and lignin degradation. This study was carried out using a randomized complete design with 3 treatments (addition of P, Ca and Mn) and 5 replicates. The following treatments were performed: T1 (P 1000 + Ca 2000 + Mn 150 ppm), T2 (P 1500 + Ca 2000 + Mn 150 ppm), and T3  (P 2000 + Ca 2000 +Mn 150 ppm). The data were subjected to an analysis of variance (ANOVA), and differences between treatment means were tested using Duncan's multiple range test (DMRT). The parameters measured were as follows: lignin peroxidase (LiP) activity (U/mL), manganese peroxidase (MnP) activity (U/mL), crude protein (CP) content (%), crude fiber (CF) content (%) and the decrease in lignin (%). The results revealed a significant increase in LiP activity and CP content and a decrease in the lignin content (p<0.05) by the addition of P in the T3 treatment. However, the treatment nonsignificantly increased (p>0.05) MnP activity and significantly decreased (P<0.05) the CF content. In conclusion, supplementation of the OPF fermentation process with P 2000, Ca 2000, and Mn 150 ppm resulted in the highest ligninase enzyme activity and in decreased lignin content.

The Effects of Oil Palm Fronds Silage Supplemented with Urea-Calcium Hydroxide on Rumen Fermentation and Nutrient Digestibility of Thai Native-Anglo Nubian Goats

Fermentation ◽  
2021 ◽  
Vol 7 (4) ◽  
pp. 218
Author(s):  
Pin Chanjula ◽  
Chanon Suntara ◽  
Anusorn Cherdthong
Keyword(s):  
Calcium Hydroxide ◽  
Oil Palm ◽  
Rumen Fermentation ◽  
Nutrient Digestibility ◽  
The Other ◽  
Fresh Matter ◽  
Oil Palm Fronds ◽  
Oil Palm Frond ◽  
Palm Fronds ◽  
Palm Frond

This study aimed to examine the combined effects of urea and calcium hydroxide ensiled oil palm fronds on rumen fermentation and digestibility of Thai native-Anglo Nubian goats. A 4 × 4 Latin square design was used to randomly assign four male crossbred goats (Thai native × Anglo Nubian). The dietary treatments were as follows: ensiled oil palm frond with no additives (EOPF as the control), urea 5% (50 g/kg fresh matter) (E-UOPF 5%), calcium hydroxide (Ca(OH)2) 5% (50 g/kg fresh matter) (E-CaOPF 5%), and combination of urea 2.5% (25 g/kg fresh matter) with Ca(OH)2 (25 g/kg fresh matter) (E-UCOPF 2.5%). The oil palm frond ensiled with different additives did not change the DM intake (p > 0.05). The total TMR intakes range from 69.39 to 77.09 g/kg BW0.75. The goats fed with E-UOPF 5.0% consumed significantly more CP than the other groups (p < 0.05). The E-UCOPF increased ME intake by 4.8%, compared with the control treatment (p < 0.05). E-UOPF 5% and E-UCOPF 2.5% significantly increased the CP digestibility by 19.7% and 17.1%, respectively (p < 0.05). Furthermore, E-CaOPF 5.0% and E-UCOPF 2.5% improved the NDF digestibility by about 10.9% and 9.90%, respectively (p < 0.05). The urea-containing oil palm frond (E-UOPF 5.0% and E-UCOPF 2.5%) had higher blood urea nitrogen (BUN) than the other groups (p < 0.05). The TVFA of goats fed E-UCOPF 2.5% was approximately 15.8% higher than that of goats provide EOPF (p < 0.05). The mean concentration of C3 increased by 7.90% and 11.61%, respectively, when E-CaOPF 5.0% and E-UCOPF 2.5% were provided instead of EOPF (p < 0.05). The total N intake and absorbed were highest (p < 0.05) when goats offered E-UOPF 5.0% (p < 0.05). The goats fed oil palm frond without additives had the lowest percentage of N-absorption/N intake (p < 0.05). This study clearly shows that the most suitable treatment is E-UCOPF 2.5%, which enhances DMD, nutrient digestibility, TVFAs, and nitrogen balance and has no negative effects on rumen microbes. This indicates that E-UCOPF 2.5% may be utilized as an alternate roughage source in TMR diets, accounting for at least 40% of the OPF. However, several factors still require consideration for urea-Ca(OH)2 treatments to be successful, including other concentrations of urea, moisture content, duration of pre-treatment, and the metabolizable protein system.

Catalytic Conversion of Oil Palm Fronds to Levulinic Acid in Ionic Liquid

2014 ◽  
Vol 625 ◽  
pp. 361-365 ◽  
Author(s):  
Nur Aainaa Syahirah Ramli ◽  
Nor Aishah Saidina Amin
Keyword(s):  
Ionic Liquid ◽  
Oil Palm ◽  
Levulinic Acid ◽  
Biomass Conversion ◽  
Catalyst Loading ◽  
Process Conditions ◽  
Acid Yield ◽  
Hy Zeolite ◽  
Oil Palm Fronds ◽  
Palm Fronds

Conversion of oil palm fronds (OPF) to levulinic acid (LA) over Fe/HY zeolite catalyst in BMIM[Br] ionic liquid has been investigated in this study. The optimization of OPF conversion reported 24.7% levulinic acid yield at 153 °C, 5.9 h, 0.96 g and 1.1 g of reaction temperature, reaction time, OPF loading and catalyst loading, respectively. The results indicated that BMIM[Br] could disrupt the covalent linkages in the OPF structures and dissolved the hollocellulose. This allowed the hollocellulose chains, accessible to the chemical transformation, to react and produce LA in presence of the Fe/HY catalyst. This study demonstrated that the combination of Fe/HY catalyst and BMIM[Br] has the potential to be applied for biomass conversion to LA under adequate process conditions.

Esterification of Levulinic Acid to Ethyl Levulinate Using Liquefied Oil Palm Frond-Based Carbon Cryogel Catalyst

2019 ◽  
Vol 12 (2) ◽  
pp. 359-369 ◽  
Author(s):  
Muzakkir Mohammad Zainol ◽  
Nor Aishah Saidina Amin ◽  
Mohd Asmadi ◽  
Nur Aainaa Syahirah Ramli
Keyword(s):  
Oil Palm ◽  
Levulinic Acid ◽  
Ethyl Levulinate ◽  
Oil Palm Frond ◽  
Carbon Cryogel ◽  
Palm Frond

scholarly journals Eco-friendly Board from Oil Palm Frond and Citric Acid

2017 ◽  
Vol 4 (2) ◽  
pp. 72-75
Author(s):  
Firda Aulya Syamani ◽  
Sasa Sofyan Munawar
Keyword(s):  
Citric Acid ◽  
Acid Solution ◽  
Oil Palm ◽  
Functional Group ◽  
Citric Acid Solution ◽  
Oil Palm Fronds ◽  
Oil Palm Frond ◽  
Citric Acid Content ◽  
Palm Fronds ◽  
Palm Frond

The utilization of oil palm fronds as composite board raw material has developed due to the declining wood supply. Currently, citric acid is used as natural adhesive on the wood-based moldings to reduce the use formaldehyde-based resin. Citric acid has carboxylic acid functional group that can react with hydroxyl functional group from cellulose by esterification reaction. This paper explain the production of board from oil palm frond and citric acid, then elaborate their physical and mechanical properties.  Oil palm fronds were processed with ring flaker to produce particles with 1 ~ 5 cm length. The particles were dried until the moisture content reached 6%. Citric acid solution was obtained by stirring 700 g citric acid in 1000 ml water.  Citric acid solution were sprayed onto particles. The weight of citric acid were 10%, 15% and 20% based on oil palm fronds’ dry weight. Boards were produced with density target of 0.6 g/cm3 and pressure at 1N/mm2 for 10 min. The hot pressing temperatures were varied at 140ºC, 160ºC, 180ºC, and 200ºC. Physical and mechanical test were performed according to JIS A 5908-2003. The MOR, MOE, IB and SW values of boards with 15 wt% citric acid content and pressed at 200oC were 5.85 N/mm2, 1067.03  N/mm2, 0.26 N/mm2 and 88.80 N respectively. The optimum condition for board production obtained upon citric acid content and pressing temperature in a range of 15% ~ 20% and 180ºC ~ 200ºC, respectively.

scholarly journals Enzymatic Hydrolysis of Pretreated Fibre Pressed Oil Palm Frond by using Sacchariseb C6

2017 ◽  
Vol 206 ◽  
pp. 012008
Author(s):  
F S Hashim ◽  
H W Yussof ◽  
M A K M Zahari ◽  
R A Rahman ◽  
R M Illias
Keyword(s):  
Enzymatic Hydrolysis ◽  
Oil Palm ◽  
Oil Palm Frond ◽  
Hydrolysis Of ◽  
Palm Frond

scholarly journals Investigation on the Dielectric Properties of Pulverized Oil Palm Frond and Pineapple Leaf Fiber for X-Band Microwave Absorber Application

2014 ◽  
Vol 893 ◽  
pp. 488-491 ◽  
Author(s):  
Elfarizanis Baharudin ◽  
Alyani Ismail ◽  
Adam Reda Hasan Alhawari ◽  
Edi Syams Zainudin ◽  
Dayang L.A. Majid ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Oil Palm ◽  
Microwave Absorber ◽  
Band Frequency ◽  
Pineapple Leaf Fiber ◽  
X Band ◽  
Oil Palm Frond ◽  
Palm Frond ◽  
Leaf Fiber

This paper presents the results on dielectric properties of pulverized material based on agricultural waste namely oil palm frond and pineapple leaf fiber for microwave absorber application in the X-band frequency range. The investigation is started by identifying the pulverized materials permittivities and loss tangents using coaxial probe technique, followed by density measurement comprising the determination of bulk and solid densities. Then, by using dielectric mixture model, the solid particle dielectric properties were determined. It is observed that the air properties give quite an effect on the permittivity and loss tangent of the pulverized materials. It is also found that the lower the material density the higher material dielectric constant will be. Furthermore, the results show that, both oil palm frond and pineapple leaf fiber are potential to be X-band absorber with average dielectric constant of 4.40 and 3.38 respectively. The loss tangents for both materials were observed to be more than 0.1 which mark them as lossy materials.

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