A METHOD TO CHARACTERIZE MATERIALS TO BE USED ON OLEOPHILIC SKIMMERS1

2005 ◽  
Vol 2005 (1) ◽  
pp. 837-840 ◽  
Author(s):  
Victoria A. Broje ◽  
Arturo A. Keller

ABSTRACT A significant amount of effort is being devoted by scientists and industry in order to increase the efficiency of oil spill recovery equipment as it determines the impact of oil spills on coastal ecosystems as well as the time and cost of cleanup operations. One way to increase the efficiency of adhesion skimmers is to replace traditional recovery materials with polymeric materials that have the highest affinity for oil. The research conducted at the University of California Santa Barbara has shown that modern scientific equipment such as a Dynamic Contact Angle Analyzer can be used for evaluation of candidate materials and selection of materials that can be most efficiently used for oil spill cleanup. The study found that the contact angle formed between oil and test surface can be used to characterize the affinity of material to oil. The contact angle correlates well with the mass of recovered oil. For a given oil, the lower the contact angle the higher the recovered mass. The study also showed that surface roughness and oil composition have a significant effect on the results of the adhesion tests. Higher roughness results in lower contact angle and larger recovered mass, for the same oil-polymer pair.

Author(s):  
Yina Yao ◽  
Shuai Meng ◽  
Cong Li ◽  
Xiantao Chen ◽  
Rui Yang

Droplet spreading and oscillation occur when a liquid droplet impacts on the solid surfaces. This process is vital in many industrial applications, such as ink-jet printing technologies, spray coating and agricultural spray deposition. However, the researches that have been done mainly focused on the spreading process, and less attention has been paid to the droplet oscillation phenomenon, which has influence on the solidification and evaporation process. Therefore, the study on droplet oscillation phenomenon after the impact is necessary and valuable. This paper aims at analyzing the droplet oscillation phenomenon using VOF method. Since the contact angle varies dramatically in the dynamic process, a dynamic contact angle model is introduced to improve the simulation accuracy. The dynamic contact angle model has been verified by comparing the numerical results with experimental and theoretical results. In order to study the factors that may influence the droplet oscillation period, different droplet diameters and impact velocities are utilized in this simulation. The results show that the oscillation period presents a positive relationship with droplet diameter. However, the impact velocity has no apparent influence on the oscillation period, which agrees well with the theoretical analysis.


Author(s):  
S. Sangplung ◽  
J. A. Liburdy

Successive droplet impingement onto a solid surface is numerically investigated using a CFD multiphase flow model (VOF method). The main focus of this study is to better understand the hydrodynamics of the non-splash impingement process, particularly the effect of a dynamic contact angle and fluid properties along with the interaction between successive droplets while they are impinging onto a solid surface. The pre-impact droplet conditions are prescribed based on a spherical droplet diameter, velocity, and inter-droplet spacing. The molecular kinetic theory is used to model the dynamic contact angle as a function of a contact line velocity. The numerical scheme is validated against experiment results. In the impact spreading and receding processes, results are analyzed to determine the nondimensional deformation characteristics of both single and successive droplet impingements with the variation of fluid properties such as surface tension and dynamic viscosity. These characteristics include spreading ratio, spreading velocity, and a dynamic contact angle. The inclusion of a dynamic contact angle is shown to have a major effect on droplet spreading. In successive droplet impingement, the second drop causes a surge of spreading velocity and contact angle with an associate complex recirculating flow near the contact line after it initially impacts the preceding droplet when it is in an advancing condition. This interaction is less dramatic when the first drop is receding or stationary. The surface tension has the most effect on the maximum spreading radius in both single and successive droplet impingements. In contrast to this, the viscosity directly affects the damping of the spreading-receding process.


Author(s):  
Yan Zhang ◽  
Albert Ratner

With the current interest in bio-derived and blended transportation fuels, the impact of the variable viscosity in these fuels on spray and splash properties has become an area of concern. In this work, the dynamics of a liquid drop impacting and spreading on a flat, smooth surface was computationally investigated by employing the volume of fluid (VOF) approach with the commercial solver Fluent 12.0.16, and the results were base-lined with experimental measurements. Of particular interest was the degree of fidelity required of the contact angle model, with the present work proposing and testing a combined static contact angle-dynamic contact angle (SCA-DCA) model to describe drop spreading. This model was shown to reduce the behavior information required as compared with full dynamic contact angle (DCA) models while significantly improving over the accuracy of a pure static contact angle (SCA) model. Two different computational domains were tested and compared for the proposed SCA-DCA model, a quarter-drop versus a full-drop domain, with the results showing that the error was reduced when the full domain was employed.


Author(s):  
O.N Goncharova ◽  
◽  
I.V. Marchuk ◽  
A.V. Zakurdaeva ◽  
◽  
...  

Polar Biology ◽  
2021 ◽  
Vol 44 (3) ◽  
pp. 575-586
Author(s):  
Pepijn De Vries ◽  
Jacqueline Tamis ◽  
Jasmine Nahrgang ◽  
Marianne Frantzen ◽  
Robbert Jak ◽  
...  

AbstractIn order to assess the potential impact from oil spills and decide the optimal response actions, prediction of population level effects of key resources is crucial. These assessments are usually based on acute toxicity data combined with precautionary assumptions because chronic data are often lacking. To better understand the consequences of applying precautionary approaches, two approaches for assessing population level effects on the Arctic keystone species polar cod (Boreogadus saida) were compared: a precautionary approach, where all exposed individuals die when exposed above a defined threshold concentration, and a refined (full-dose-response) approach. A matrix model was used to assess the population recovery duration of scenarios with various but constant exposure concentrations, durations and temperatures. The difference between the two approaches was largest for exposures with relatively low concentrations and short durations. Here, the recovery duration for the refined approach was less than eight times that found for the precautionary approach. Quantifying these differences helps to understand the consequences of precautionary assumptions applied to environmental risk assessment used in oil spill response decision making and it can feed into the discussion about the need for more chronic toxicity testing. An elasticity analysis of our model identified embryo and larval survival as crucial processes in the life cycle of polar cod and the impact assessment of oil spills on its population.


2013 ◽  
Vol 333-335 ◽  
pp. 2004-2009
Author(s):  
Lin Ling Jiang ◽  
Wei Mo ◽  
Xiao Jing Yang ◽  
Tian Li Xue ◽  
Shao Jian Ma

To better understand the sedimentation processes of bentonite, the sedimentation characteristic of bentonite suspension was studied by using the sedimentation analysis module of Dynamic Contact Angle Meter and Tensiometer. The results indicated that sedimentation characteristics of bentonite suspension were affected by the concentration and pH values of the suspension together with the dosage of dispersants. The natural sedimentation rates of bentonite suspension declined firstly with prolonging the sedimentation time and soon stabilized after about 50s. The sedimentation weight of particles hardly changed when the concentration ranged from 0.5% to 5.0%, while it increased significantly when ranged from 5.0% to 10.0%. The sedimentation weight and rate were relatively bigger at 4.4, 11.8 than that of 6.0, 7.9, and the maximum values appeared at pH11.8. Adding sodium pyrophosphate could improve the dispersibility of bentonite suspension.


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