Modeling Payne effect on basis of linearization of a visco-hyperelastic model

The present work concerns the modeling of the Payne effect in nonlinear viscoelasticity. This effect is a characteristic property of filled elastomers. Indeed, under cyclic loading of increasing amplitude, a decrease is shown in the storage modulus and a peak in the loss modulus. In this study, the Payne effect is assumed to arise from a change of the material microstructure, i.e., the thixotropy. The so-called intrinsic time or shift time was inferred from solving a differential equation that represents the evolution of a material's microstructure. Then, the physical time is replaced by the shift time in the framework of a recent fractional visco-hyperelastic model, which was linearized in the neighborhood of a static pre-deformation. As a result, we have investigated the effects of static pre-deformation, frequency, and magnitude of dynamic strain on storage and loss moduli in the steady state. Thereafter, the same set of parameters identified from the complex Young's modulus was used to predict the stress in the pre-deformed configuration. Finally, it is demonstrated that the proposed model is reasonably accurate in predicting Payne effect.

Application of biowaste in rubber blend

Submitted paper deals with the incorporation of biological waste into the rubber blend and moreover, it is mainly connected with the determination of the influence of this biowaste on the basic properties of the blends and vulcanizate. Wood flour, which comes from the production of wood pellets, was used as the biowaste. Biowaste was used as a filler but also as a plasticizer. The effect of the mentioned biowaste (wood flour) in rubber blend was determined from the aspect of curing characteristics and physical-mechanical properties. In addition, Payne effect was also determined. Achieved results show the possibilities of partial use of biowaste in the rubber blend and provide other research possibilities.

Potency of Urea-Treated Halloysite Nanotubes for the Simultaneous Boosting of Mechanical Properties and Crystallization of Epoxidized Natural Rubber Composites

Halloysite nanotubes (HNTs) are naturally occurring tubular clay made of aluminosilicate sheets rolled several times. HNT has been used to reinforce many rubbers. However, the narrow diameter of this configuration causes HNT to have poor interfacial contact with the rubber matrix. Therefore, increasing the distance between layers could improve interfacial contact with the matrix. In this work, Epoxidized Natural Rubber (ENR)/HNT was the focus. The HNT layer distance was successfully increased by a urea-mechanochemical process. Attachment of urea onto HNT was verified by FTIR, where new peaks appeared around 3505 cm−1 and 3396 cm−1, corresponding to urea’s functionalities. The intercalation of urea to the distance gallery of HNT was revealed by XRD. It was also found that the use of urea-treated HNT improved the modulus, tensile strength, and tear strength of the composites. This was clearly responsible for interactions between ENR and urea-treated HNT. It was further verified by observing the Payne effect. The value of the Payne effect was found to be reduced at 62.38% after using urea for treatment. As for the strain-induced crystallization (SIC) of the composites, the stress–strain curves correlated well with the results from synchrotron wide-angle X-ray scattering.

IMPROVEMENT OF SILICA-REINFORCED NATURAL RUBBER TIRE TREAD COMPOUNDS BY JOINT HYBRIDIZATION WITH SMALL AMOUNTS OF SECONDARY FILLERS AND POLYMERS

ABSTRACT To improve the properties of silica-reinforced truck tire tread compounds, especially abrasion resistance, the effect of vinyl contents in butadiene rubber (BR) or solution styrene–butadiene rubber (SSBR) as secondary polymers in silica-filled natural rubber (NR) compounds at a ratio of 80/20 phr is investigated in the first part of this study. By increasing the levels of vinyl contents in BR in combination with NR, a better Payne effect, 300% modulus, reinforcement index, and tan delta at −20 and 0 ° C are obtained, whereas the tensile strength, elongation at break, and DIN abrasion resistance index decrease with increasing vinyl contents. Higher vinyl contents in SSBR result in improvements in Payne effect, 300% modulus, tan delta at −20 and 0 °C but only a small improvement in DIN abrasion resistance index. Combinations of secondary fillers and polymers in silica-filled NR are covered in the second part of present study. Silica/carbon black–filled NR/BR and NR/SSBR, respectively, and silica/organoclay–filled NR/BR and NR/SSBR show positive effects on scorch time and optimum cure time, with only slight changes in Payne effect, tensile properties, tan delta at −20 and 0 ° C and DIN abrasion resistance as compared with compounds with carbon black N134. The use of organoclay results in an enhanced Payne effect and tan delta at 60 °C, indicative of reduced filler–filler networking and consequently a lower rolling resistance of tire tread compounds as compared with the compound without organoclay. The specific combination of a small amount of organoclay replacing the same amount of silica, together with some of the NR replaced by high-vinyl BR, promises a substantial overall boost in wet and ice traction, abrasion, and wear resistance as compared with straight NR/silica tire treads. This new observation helps to overcome one of the main shortcomings of NR/silica compounds: their generally low wear resistance.