Distribution of Heavy Metals (Cd, Cu, Co, Cr, Hg, Mn, Ni, Pb, Zn, and As) in Overbank Sediments of Ibar Tributaries (in Serbia)

The Ibar River is an international river whose watercourse passes next to numerous technogenic landfills and chemical-industrial complexes. They can affect the quality of water in the river, as well as the quality of overbank sediments. The river flows into the West Morava River near Kraljevo and it represents its largest tributary. The analysis of the overbank sediments of Ibar tributaries showed high concentration of heavy metals at some points. The statistical analysis of the content determined the existence of two synthetic factors around which heavy metals were concentrated. The comparison of the chemical composition of overbank sediment with the composition of geological and pedological substratum on which they were developed showed that the increased concentrations of heavy metals were mostly a product of geological and pedological composition of the river’s substratum and basin, and had no connection with (possible) anthropogenic factors. However, due to the sensitivity and proximity of potential pollutants, the necessity to constantly monitor chemical composition of overbank sediments in the river basin was determined.

Submarine canyon systems focusing sub-surface fluid in the Canterbury Basin, South Island, New Zealand

This work uses a high-quality 3D seismic volume from offshore Canterbury Basin, New Zealand, to investigate how submarine canyon systems can focus sub-surface fluid. The seismic volume was structurally conditioned to improve the contrast in seismic reflections, preserving their lateral continuity. It reveals multiple pockmarks, eroded gullies and intra-slope lobe complexes occurring in association with the Waitaki Submarine Canyon. Pockmarks are densely clustered on the northern bank of the canyon and occur at a water depth of 500–900 m. In parallel, near-seafloor strata contain channel-fill deposits, channel lobes, meandering channel belts and overbank sediments deposited downslope of the submarine canyon. We propose that subsurface fluid migrates from relatively deep Cretaceous strata through shallow channel-fill deposits and lobes to latter seep out through the canyon and associated gullies. The new, reprocessed Fluid Cube meta-attribute confirms that fluids have seeped out through the eroded walls of the Waitaki Canyon, with such a seepage generating seafloor depressions in its northern bank. Our findings stress the importance of shallow reservoirs (channel-fill deposits and lobes) as potential repositories for fluid, hydrocarbons, or geothermal energy on continental margins across the world.

Anthropogenic Transformation Disconnects a Lowland River From Contemporary Carbon Stores in Its Catchment

Rivers transport carbon from continents to oceans. Surprisingly, this carbon has often been found to be centuries old, not originating from contemporary plant biomass. This can be explained by anthropogenic disturbance of soils or discharge of radiocarbon–depleted wastewater. However, land enclosure and channel bypassing transformed many rivers from anabranching networks to single–channel systems with overbank sediment accumulation and lowered floodplain groundwater tables. We hypothesized that human development changed the fluvial carbon towards older sources by changing the morphology of watercourses. We studied radiocarbon in the Elbe, a European, anthropogenically–transformed lowland river at discharges between low flow and record peak flow. We found that the inorganic carbon, dissolved organic carbon (DOC) and particulate organic carbon was aged and up to 1850 years old. The ∆14C values remained low and invariant up to median discharges, indicating that the sources of modern carbon (fixed after 1950) were disconnected from the river during half of the time. The total share of modern carbon in DOC export was marginal (0.04%), 72% of exported DOC was older than 400 years. This was in contrast to undisturbed forested subcatchments, 72% of whose exported DOC was modern. Although population density is high, mass balances showed that wastewater did not significantly affect the ∆14C-DOC in the Elbe river. We conclude that wetlands and other sources of contemporary carbon were decoupled from the anthropogenically transformed Elbe stream network with incised stream bed relative to overbank sediments, shifting the sources of fluvial carbon in favor of aged stores.

Application of 239,240 Pu, 137Cs and heavy metals for dating of river sediments

The periodical nature of overbank sediment accumulation makes their detailed dating much more difficult than dating sediments in water reservoirs. To improve the commonly used dating with 137Cs, we combined this method with Pu isotopes and heavy metals in order to date sediments of the Chechło River (southern Poland), which was polluted by a lead-zinc mine. We analyzed 137Cs, Pu isotopes and heavy metal concentrations in three profiles of overbank sediments and in two profiles of subsidence basins in the lower river reach. The results indicate a lower accuracy and higher uncertainty of the overbank than the dating of reservoir sediments. The application of plutonium isotopes provided very important information validating caesium peaks or providing the principal information regarding horizons dated with heavy metals. The obtained dates give the earliest possible age of particular horizons with the actual sediment deposition delayed by several to a dozen years. This investigation shows that using plutonium radioisotopes can be a useful tool for dating, particularly of the youngest overbank sediments where numerous sedimentation gaps cause uncertainties in the application of other methods, e.g. radiocaesium and heavy metals.

“Grain-size bookkeeping,” a new aid for siliciclastic systems with examples from paralic environments

ABSTRACT Sedimentary logs form the foundation of many studies of ancient and modern sedimentary successions. In siliciclastic settings in particular, vertical grain-size trends are important records of past depositional processes and environments, so that they are recorded with care and are often central to final interpretations. It is rare for the actual grain size to play a similar role. Yet there is significant value in (i) digitizing sedimentary logs to produce statistical grain-size data and (ii) the deliberate study of grain size, a process described here as “grain-size bookkeeping.” To illustrate this, over 5.9 km of sedimentary logs have been digitized from the Miocene to Pliocene paleo–Orinoco delta, the Cretaceous Ferron Last Chance and Notom deltas, and the Jurassic Ravenscar Group. The digital data reveal how grain size partitions into distinct sedimentary facies, proximal-to-distal changes, changes related to stratigraphy and base level, and the overall grain size of paralic systems. It emerges that fluvio-distributary channels are the coarsest-grained sediment bodies in each of the studied systems. The coarsest material does not reach the shoreline, though the grain sizes of fluvio-distributary channels and shoreline sand bodies overlap, in accordance with the concept that the former feeds the later. By contrast, overbank sediments are relatively fine-grained, suggesting that, with the exception of channel belts, coarse sediment can largely bypass the delta plain. Grain-size changes occur across some key stratigraphic surfaces, but not consistently so. Channels in valleys are, on average, coarser than similar channels in unconfined systems, but, in the presented datasets, valleys do not contain the coarsest channels. The data have also allowed the analysis of down-system fining rates in ancient, sandy fluvio-distributary systems, with grain size being measured to decrease at rates ranging from 0.7 to 7.7 μm/km—values that compare favorably with modern rivers. Such large-scale trends are ornamented by, and link to, smaller-scale spatial changes associated with, for example, channel bars, crevasses, and mouth bars, and an initial dataset of associated fining rates has been collected. In general, very large systems (rivers) have low fining rates because of their great size, whereas the converse is true for small systems, especially if the grain size range is large. Consideration of downstream fining rates has led to the insight that avulsion initiates an unequal race to the shoreline. Suspended very fine sand and silt is likely to reach the shoreline with the avulsion flood waters, but bedload will advance far more slowly, perhaps too slowly to reach the shoreline before the river avulses again. Some avulsions may lead to notable temporal variations in the caliber of sediment supplied to shorelines. As expected, the largest system, the paleo-Orinoco, is the finest grained. The Ferron deltas have catchment areas 12 and 22 times smaller than the Orinoco, and are the coarsest grained. Remarkably, though their catchment areas differ by a factor of two, they have almost identical sand grain-size distributions. The data have also proved powerful in refining paleogeographic reconstructions, in particular suggesting “missing” depositional elements needed to complete local sediment routing systems. Careful tracking of grain size is also beneficial in that it is a key control on permeability, the description of which is crucial to the prediction of subsurface fluid flow.