Anion Dependent Particle Size Control of Platinum Nanoparticles Synthesized in Ethylene Glycol

The polyol synthesis is a well-established method to form so-called “surfactant-free” nanoparticles (NPs). In the present study, the NP size resulting from the thermal reduction of the precursors H2PtCl6, H2Pt(OH)6, or Pt(acac)2 in presence of the bases NaOH or Na(acac) at different concentrations is studied. It is shown that the size control depends more strongly on the nature of the precursor (metal salt) than on the anion present in the base. The latter is surprising as the concentration of the base anion is often an important factor to achieve a size control. The reduction of H2PtCl6 or H2Pt(OH)6 in presence of NaOH and Na(acac) confirm the observation that the NP size is determined by the OH−/Pt molar ratio and expands it to the base anion/Pt molar ratio. In contrast, the reduction of Pt(acac)2 in presence of the bases NaOH (previous reports) or Na(acac) (shown in the present work) leads to larger NPs of ca. 3 nm, independent of the concentration of the base anions. Hence, the anion effect observed here seems to originate predominantly from the nature of the precursor (precursor anion dependence) and only for certain precursors as H2PtCl6 or H2Pt(OH)6 the size control depends on the base anion/Pt molar ratio.

Single-molecule magnets under dc field with an anion effect: self-assembly of pure dysprosium(iii) metallacycles

The anion-adaptive self-assembly described here not only offers a facile approach to produce large single-molecule magnets but also provides an understanding of how structural factors affect the magnetic properties.

High Efficacy Glycerol Acetalization with silica gel immobilized Bronsted acidic ionic liquids catalyst - Preparation and comprehending the counter-anion effect on the catalytic activity

The subsequent imidazolium sulfonate zwitterions (ZIs) with unconventional counter-anions were used to fabricate a series of mesoporous silica gel immobilized Bronsted acidic ionic liquids (SG@BAILs) nano-catalysts. In comparison to traditional...