Comparative Study of Radiative Heating Techniques for Fast Processing of Functional Coatings for Sustainable Energy Applications

This study assesses the use of short wavelength radiative heating techniques such as near infrared, intense pulse light and ultraviolet heating for processing coatings in energy applications. Concentrating on the importance of investigating different radiative wavelengths to advance these technologies as scalable processes via reduced heating times. It illustrates the mechanisms by which these techniques can transform thin film materials: sintering, binder removal, drying and chemical reactions. It focuses on successful research applications and the methods used to apply these radiative mechanisms in solar energy, battery storage and fuel cells, whilst considering the materials suitable for such intentions. The purpose of this paper is to highlight to academics as well as industrialists some of the potential advantages and applications of radiative heating technologies.

Metal Oxide Oxidation Catalysts as Scaffolds for Perovskite Solar Cells

Whilst the highest power conversion efficiency (PCE) perovskite solar cell (PSC) devices that have reported to date have been fabricated by high temperature sintering (>500 °C) of mesoporous metal oxide scaffolds, lower temperature processing is desirable for increasing the range of substrates available and also decrease the energy requirements during device manufacture. In this work, titanium dioxide (TiO2) mesoporous scaffolds have been compared with metal oxide oxidation catalysts: cerium dioxide (CeO2) and manganese dioxide (MnO2). For MnO2, to the best of our knowledge, this is the first time a low energy band gap metal oxide has been used as a scaffold in the PSC devices. Thermal gravimetric analysis (TGA) shows that organic binder removal is completed at temperatures of 350 °C and 275 °C for CeO2 and MnO2, respectively. By comparison, the binder removal from TiO2 pastes requires temperatures >500 °C. CH3NH3PbBr3 PSC devices that were fabricated while using MnO2 pastes sintered at 550 °C show slightly improved PCE (η = 3.9%) versus mesoporous TiO2 devices (η = 3.8%) as a result of increased open circuit voltage (Voc). However, the resultant PSC devices showed no efficiency despite apparently complete binder removal during lower temperature (325 °C) sintering using CeO2 or MnO2 pastes.