conjugated organic materials
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Revisiting the Heck Reaction for Fluorous Materials Applications

Synlett ◽  
2021 ◽  
Author(s):  
Timothy M. Swager ◽  
Kosuke Yoshinaga
Keyword(s):  
Heck Reaction ◽  
Organic Materials ◽  
Conjugated Organic Materials

AbstractInstalling fluoroalkyl chains on a molecule by the Heck reaction is a versatile method to transform the molecule’s properties that enable unique materials applications. This work further expands the scope of this reaction to thiophenes, which were able to undergo further functionalization and polymerization, highlighting the potential of these molecules in conjugated organic materials.

Why are S–F and S–O non-covalent interactions stabilising?

2018 ◽  
Vol 6 (45) ◽  
pp. 12413-12421 ◽  
Author(s):  
Karl J. Thorley ◽  
Iain McCulloch
Keyword(s):  
Organic Materials ◽  
Torsional Potential ◽  
Non Covalent Interactions ◽  
Conjugated Organic Materials ◽  
Covalent Interactions ◽  
Dipole Alignment

Dipole alignment of substituents greatly affects the torsional potential between neighbouring rings in conjugated organic materials.

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