Abstract. A full diurnal measurement of stratospheric column
NO2 has been made over the Jet Propulsion Laboratory's Table Mountain
Facility (TMF) located in the mountains above Los Angeles, California, USA
(2.286 km above mean sea level, 34.38∘ N, 117.68∘ W).
During a representative week in October 2018, a grating spectrometer
measured the telluric NO2 absorptions in direct solar and lunar
spectra. The stratospheric column NO2 is retrieved using a modified
minimum-amount Langley extrapolation, which enables us to accurately treat
the non-constant NO2 diurnal cycle abundance and the effects of
tropospheric pollution near the measurement site. The measured 24 h cycle
of stratospheric column NO2 on clean days agrees with a 1-D
photochemical model calculation, including the monotonic changes during
daytime and nighttime due to the exchange with the N2O5 reservoir
and the abrupt changes at sunrise and sunset due to the activation or
deactivation of the NO2 photodissociation. The observed daytime
NO2 increasing rate is (1.34±0.24)×1014 cm−2 h−1. The observed NO2 in one of the afternoons during the
measurement period was much higher than the model simulation, implying the
influence of urban pollution from nearby counties. A 24 h back-trajectory
analysis shows that the wind first came from inland in the northeast and
reached southern Los Angeles before it turned northeast and finally
arrived at TMF, allowing it to pick up pollutants from Riverside County, Orange
County, and downtown Los Angeles.