Effects of silane coupling agent modifications of hollow glass microspheres on syntactic foams with epoxy matrix

A syntactic foam was prepared from an epoxy resin matrix and modified hollow glass microsphere fillers. Modification by silane coupling agents with different molecular structures was analyzed, and the optimal content of the silane coupling agent was determined. The results demonstrated that all silane coupling agents enhanced the adhesion between the hollow glass microspheres and epoxy resin matrix, resulting in enhanced water absorption, compressive performance, tensile performance, and bending performance compared to those prepared using unmodified hollow glass microspheres. Among silane coupling agents with different end groups, the one with a sulfhydryl end group exhibited optimal modification for hollow glass microspheres. Among the silane coupling agents with different backbone structures, the one with silanol groups exhibited the optimal modification of hollow glass microspheres. Additionally, the performance of the syntactic foams was optimal when 6% of the silanol-containing coupling agent was used. The results demonstrated that syntactic foams prepared with hollow glass microspheres modified by silane coupling agents exhibited improvements in water absorption, compressive performance, tensile performance, and bending performance, compared with those prepared using unmodified hollow glass microspheres. Among silane coupling agents with different end structures, the one with a sulfhydryl group as end group showed the best modification effect on hollow glass microspheres. The water absorption was 0.35%, the compressive strength was 62.15 MPa, the tensile strength was 40.15 MPa, and the bending strength was 53.17 MPa. Among silane coupling agents with different backbone structures, the one with silanol groupsbonds showed the best results. Its compressive strength was up to 64.15 MPa, the tensile strength was 35.47 MPa, and the bending strength was 53.99 MPa.

DYNAMIC IMPACT RESISTANCE OF COMPOSITE SANDWICH PANELS WITH 3-D PRINTED POLYMER SYNTACTIC FOAM CORES

Polymer-based syntactic foams find use in the marine industry as primary structural materials due to their inherent lightweight nature and enhanced mechanical properties relative to pure HDPE. 3-D printing these materials circumvents the use of joining assemblies, enabling the production of complex shapes as standalone structures. Although the quasi-static response of these 3D printed foams has been well studied independently in recent years, their dynamic impact resistance and tolerance as potential core material for sandwich panels have not been the focus. Moreover, 3D printing is known to impart directionality in the printed syntactic foams, which may introduce failure mechanisms typically not observed in molded foams. It is therefore important to investigate the mechanics of 3-D printed syntactic foam core composite sandwich structures under impact loading and characterize their failure mechanisms for establishing dynamic impact resistance. To this end, 3-D printed syntactic foams have been developed using rasters of High-Density Polyethylene (HDPE) and Glass MicroBalloon (GMB) fillers by adopting the Fused Raster Fabrication (FFF) technique. The current study is performed to assess the impact performance of these composite foam cores based on the volume fraction of fillers and print orientation. The weight percentage of GMB fillers in printed specimens ranges from 0% to 60% in increments of 20%. This study presents the impact response of these composite sandwich panels at different energy levels, in compliance with ASTM D7136/D7136M - 20. Observations suggest that an increase in GMB % in HDPE matrix improves the impact performance in terms of the peak load of the material, but the failure behavior becomes brittle to an extent. Observing the failed specimens under a Micro-CT scanner captures the failure morphologies and helps characterize failure processes during impact. It is noticed that core materials with higher GMB content are prone to individual raster breakage and delamination at the back face, in addition to debonding between individual rasters. Specimens printed along the longer dimension (y-direction) impart more warping in the final sandwich structures than that of specimens printed along the shorter dimension (x-direction). Therefore, they are more susceptible to delamination at the back face. Addition of GMB fillers mitigate the tendency of the sandwich panels to warp.