Formation mechanisms of ringwoodite: clues from the Martian meteorite Northwest Africa 8705

Ringwoodite and wadsleyite are the high-pressure polymorphs of olivine, which are common in shocked meteorites. They are the major constituent minerals in the terrestrial mantle. NWA 8705, an olivine-phyric shergottite, was heavily shocked, producing shock-induced melt veins and pockets associated with four occurrences of ringwoodite: (1) the lamellae intergrown with the host olivine adjacent to a shock-induced melt pocket; (2) polycrystalline assemblages preserving the shapes and compositions of the pre-existing olivine within a shock-induced melt vein (60 μm in width); (3) the rod-like grains coexisting with wadsleyite and clinopyroxene within a shock-induced melt vein; (4) the microlite clusters embedded in silicate glass within a very thin shock-induced melt vein (20 μm in width). The first two occurrences of ringwoodite likely formed via solid-state transformation from olivine, supported by their morphological features and homogeneous compositions (Mg# 64–62) similar to the host olivine (Mg# 66–64). The third occurrence of ringwoodite might fractionally crystallize from the shock-induced melt, based on its heterogeneous and more FeO-enriched compositions (Mg# 76–51) than those of the coexisting wadsleyite (Mg# 77–67) and the host olivine (Mg# 66–64) of this meteorite. The coexistence of ringwoodite, wadsleyite, and clinopyroxene suggests a post-shock pressure of 14–16 GPa and a temperature of 1650–1750 °C. The fourth occurrence of ringwoodite with compositional variation (Mg# 72–58) likely crystallized from melt at 16–18 GPa and 1750–1850 °C. The presence of the four occurrences of ringwoodite was probably due to their very fast cooling rates in and/or adjacent to the thin shock-induced melt veins and small pockets. In addition, the higher Fa-contents of the host olivine (Fa35–39) in NWA 8705 than those in ordinary chondrites (Fa16–32) makes the olivine–ringwoodite transformation prolong to a lower pressure.

Intracrystalline melt migration in deformed olivine revealed by trace element compositions and polyphase solid inclusions

Melt transport mechanisms have an important impact on the chemical composition of the percolated host rock and the migrating melts. Melt migration is usually assumed to occur at grain boundaries. However, microstructural studies revealed the occurrence of polyphase inclusions along dislocations, subgrain boundaries and microcracks in single mineral grains. The inclusions are interpreted as crystallized melt pockets suggesting that melts can migrate within deformed crystals. Intracrystalline melt migration and diffusive re-equilibration can lead to significant mineral trace element enrichments when associated with dissolution–precipitation reactions. In this contribution, we study a body of replacive troctolites associated with the Erro-Tobbio ophiolitic mantle peridotites (Ligurian Alps, Italy). The replacive formation of the olivine-rich troctolite involved extensive impregnation of a dunitic matrix, i.e. partial dissolution of olivine and concomitant crystallization of interstitial phases. The olivine matrix is characterized by two distinct olivine textures: (i) coarse deformed olivine, representing relicts of the pre-existing mantle dunite matrix (olivine1), and (ii) fine-grained undeformed olivine, a product of the melt–rock interaction process (olivine2). Previous studies documented a decoupling between olivine texture and trace element composition, namely enriched trace element compositions in olivine1 rather than in olivine2, as would be expected from the dissolution–precipitation process. Notably, the trace element enrichments in deformed olivines are correlated with the occurrence of elongated 10 µm size polyphase inclusions (clinopyroxene, Ti-pargasite, chromite) preferentially oriented along olivine crystallographic axes. These inclusions show irregular contacts and have no crystallographic preferred orientation with the host olivine, and the phases composing the inclusions show similar chemical compositions to the vermicular phases formed at the grain boundaries during late-stage reactive crystallization of the troctolite. This suggests that the investigated inclusions did not form as exsolutions of the host olivine but rather by input of metasomatic fluids percolating through the deformed olivine grains during closure of the magmatic system. We infer that strongly fractionated volatile-rich melts were incorporated in oriented microfractures within olivine1 and led to the crystallization of the polyphase inclusions. The presence of intracrystalline melt greatly enhanced diffusive re-equilibration between the evolved melt and the percolated olivine1, in turn acquiring the enriched character expected in neoformed olivine crystals. Intracrystalline melt percolation can have strong geochemical implications and can lead to efficient re-equilibration of percolated minerals and rocks.

Occurrence of Fe3+ and formation process of precipitates within oxidized olivine phenocrysts in basalt lava from Kuroshima volcano, Goto islands, Nagasaki, Japan

The oxidation state of Fe and precipitates within olivine phenocrysts from an olivine-basalt from Kuroshima volcano, Goto Islands, Nagasaki Prefecture, Japan, were determined using electron microprobe analysis, 57Fe Mössbauer spectroscopy, Raman spectroscopy and transmission electron microscopy, to examine the formation process of the Fe-bearing precipitates.The average Fo content of the olivine phenocrysts is 76.2 mol.%. The olivine phenocrysts occasionally have precipitate minerals at their rims, especially on rims near vesicles. The 57Fe Mössbauer spectrum of olivine separates consists of two doublets assigned to Fe2+ at the octahedral M1 and M2 sites, and a Fe3+ doublet at the M1 and M2 sites. The Fe2+:Fe3+ ratio is 90(5):10(1). The precipitates at the rims of the olivine phenocrysts consistof magnetite and enstatite showing coaxial relations with host olivine, and grow parallel to the olivine c axis. Moreover, clusters consisting of nanoscale domains of a few tens of nm in size occur in the host olivine. Their rounded form and appearance in transmission electron microscope images are similar to those of the magnetite precipitates, but they have an olivine structure and can be regarded as embryos of magnetite within the olivine.The oxidation process of olivine phenocrysts under cooling conditions is: (1) formation of magnetite embryos on the rims of olivinephenocrysts; (2) formation of enstatite-like pyroxene domains by depletion of Fe in olivine due to the generation of magnetite embryos; (3) crystallization of magnetite and enstatite-like pyroxene precipitates.

A late ultramafic suite in the Kap Edvard Holm layered gabbro complex, East Greenland

The Kap Edvard Holm Complex is an early Tertiary layered gabbro situated on the western side of the Kangerdlugssuaq fjord. Layered olivine gabbros in the Taco Point area are cut by several wehrlitic sill-like bodies which comprise a late ultramafic suite. An intrusive wehrlitic facies in the inner part of the bodies consists of olivine (+minor chrome-spinel) orthocumulate with clinopyroxene oikocrysts and interstitial plagioclase, kaersutite and phlogopite. A replacive facies which occurs in the marginal zones is texturally similar to the intrusive facies but contains no chromespinel and is more feldspathic, varying from a melanocratic olivine gabbro to a feldspathic wehrlite. It occurs where the sills wedge out laterally, in the lower contact zones where finger structures are widely developed, and in the upper contact zones where wehrlitic pipes feed melanocratic sheets, called parasol structures, which preferentially follow mafic layers in the host olivine gabbro. The wehrlites formed by the intrusion of hot, hydrous, ultrabasic magma into consolidated layered olivine gabbro. The replacive facies was formed by the volume for volume metasomatic replacement of olivine gabbro; dissolution of plagioclase was accompanied by crystallization of olivine. Some clinopyroxene was initially resorbed and later reprecipitated during this process. The relatively dense pore magma migrating upwards was restricted to pipes and spread out laterally when it encountered readily replaced mafic layers, while below the sills gabbro was replaced en masse and finger structures were formed. Similar late ultramafic suites occur in ophiolites, and their presence in the Kap Edvard Holm Complex supports suggestions that it acted as an ocean ridge type magma chamber during the initiation of early Tertiary sea floor spreading in the North Atlantic.

A Spinifex Rock from Munro Township, Ontario

The textural and compositional characteristics of a spinifex rock (MS-1) from Munro township, Ontario have been investigated in some detail. When projected into Mg–CaO–Al2O3 and CaO–MgO–FeO space, MS-1 appears late in the fractionation trends for peridotites, associated spinifex rocks and high Mg basalts. The latter trend extrapolates almost linearly to olivine tholeiite compositions.There are two types of blade megacrysts in the rock, both apparently representing preexisting olivine: (1) an earlier phase of composite, skeletal platy crystals of clinochlore, about 10 × 10 × 0.5 mm in size, which have a preferred orientation in the rock and show pronounced parallel growth development in the plane of the blades. The clinochlore is crystallographically related to the host olivine with c* and [100] parallel to a and b axis of olivine, respectively; (2) sheafs of oriented skeletal plates about 0.1 mm in shortest dimension which are completely altered to chlorite, calcite, magnetite and amphibole. The appearance of the composite blade megacrysts varies markedly with thin section orientation and this seems to account for the various types of blade (or platey) crystals reported in the literature. The interblade areas are largely of acicular and spherulitic pyroxene and interstitial groundmass. The acicular pyroxene is augite. Its composition varies considerably, especially with the area analysed, the greatest variations being in Cr, Ti and Na. The augite is characterized by high Al contents—preferentially accommodated in tetrahedral sites—and this leads to a distinctive field in Ti, Al plots compared to those for lunar and other terrestrial pyroxene. The rock also contains a few relict rounded olivine phenocrysts, amygdules, accessory chromite octahedra with magnetite rims, pentlandite and pyrrhotite.The Mg–Fe ratios for the clinochlore, augite and interstitial groundmass do not vary greatly from that of the whole rock value in contrast to the situation in a quenched plateau basalt.

Calc-aluminous insets in olivine of the Sharps chondrite

SummaryA 250 µm olivine crystal in Sharps contains 1 to 5 µm insets identified by microprobe analysis as ferroan monticellite, spinel, and fassaite with average compositions: olivine (host), (Fe0·44Mg1·51Ca0·05) (Si0·99Al0·01)O4; ferroan monticellite, (Ca0·89Fe0·41Mg0·66) (Si1·00Al0·02)O4; spinel, (Fe0·41Mg0·59)(Fe0·063+Cr0·23Al1·69Si0·01Ti0·01)O4; and fassaite, Ca0.96(Fe0·01Mg0·59)(Al0·18Ti0·07Fe0·163+)(Si1·53Al0·47)O6. Textural and experimental data suggest early crystallization of spinel from a calcic olivine melt, exsolution of ferroan monticellite from the host olivine, and reaction of spinel and ferroan monticellite to form fassaite. The severe depletion of alkalies and silica in this crystal suggests it is a residue from vapour fractionation.