electrical dipole moment
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2011 ◽  
Vol 56 (3) ◽  
pp. 386-394
Author(s):  
S. Yu. Semenikhin ◽  
Yu. P. Braginets ◽  
V. V. Voronin ◽  
I. A. Kuznetsov ◽  
E. G. Lapin ◽  
...  

1982 ◽  
Vol 37 (12) ◽  
pp. 1449-1453 ◽  
Author(s):  
M. Andolfatto ◽  
B. Kleibömer ◽  
A. Guarnieri

AbstractThe microwave and millimeterwave spectra of Bromofluoroacetylene 79Br-C ≡ C-F and 81Br-C ≡ C-F in natural abundance have been investigated. The molecule has been found to be linear. The rotational constant, the centrifugal distortion constants Do, the Bromine quadrupole coupling constant and the electrical dipole moment have been determined.Some r0-structures have been calculated assuming different values for the C ≡ C distance.


1979 ◽  
Vol 34 (11) ◽  
pp. 1269-1274 ◽  
Author(s):  
Erik Bjarnov

Vinyl ketene (1,3-butadiene-1-one) has been synthesized by vacuum pyrolysis of 3-butenoic 2-butenoic anhydride. The microwave and infrared spectra of vinyl ketene in the gas phase at room temperature have been studied. The trans-rotamer has been identified, and the spectroscopic constants were found to be Ã= 39571(48) MHz, B̃ = 2392.9252(28) MHz, C̃ = 2256.0089(28) MHz, ⊿j = 0.414(31) kHz, and ⊿JK = - 34.694(92) kHz. The electrical dipole moment was found to be 0.987(23) D with μa = 0.865(14) D and μb = 0.475(41) D. A tentative assignment has been made for 17 of the 21 normal modes of vibration


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