Lithofacies and petrochemical characterization of volcano-sedimentary sequence of Chandil Formation around Kharidih-Bareda area, Seraikela-Kharsawan District, Jharkhand: implications for uranium mineralization

Mesoproterozoic Chandil Formation (ca. 1600 Ma) of North Singhbhum Mobile Belt record numerous features of felsic volcaniclastics and felsic to intermediate volcanics preserved in the central sector of the fold belt around Kharidih-Bareda area, Seraikela-Kharsawan district, Jharkhand. The felsic volcanic rocks exhibit flow bands, autoclasts and layering of crystal mushes revealing viscous nature of eruptives. The volcaniclastic sediments comprise of significant proportion of volcanic epiclasts and accidental lithic fragments. These volcaniclastics have been categorized into five prominent lithofacies viz, stratified lapilli tuff, banded tuff, tuff with penecontemporaneous deformation, welded lapilli stones, vitric tuff and volcanic bombs by field and petrographic studies of outcrops and subsurface borehole cores. The welded lapilli tuffs display fiamme and eutaxitic texture. Interlayering of the volcaniclastics, which are most often pyrite-rich, with psamo-pelitic lithology like carbonaceous phyllite, variegated phyllite, quartzite and minor limestone is suggestive of marine euxenic depositional environment. Petrographic study of the volcaniclastics indicated presence of glass shards, garnet phenocrysts, spherules of tremolite, ovoid to lenticular accretionary lapilli along with devitrified glassy material. Compositionally these felsic volcanics and volcaniclastics are rhyodacitic to andesitic in nature with peraluminous to meta aluminous in character. A/CNK values vary from 0.52 to 2.42 in felsic volcanics and from 0.12 to 1.63 in volcaniclastics. Signatures of arc magmatism is indicated by low concentration of HFS elements such as Nb (5-17 ppm), Ga (11-17 ppm) and Y (5-28 ppm). Elevated intrinsic content of uranium (3-8 ppm), Th/U ratio ranging from 1.2 to 13.2, presence of metamict allanite and zircon in volcanics and volcaniclastics reveal their suitability as a prospective source for search of uranium mineralization. The volcanic-volcaniclastic-clastic association of the Chandil Formation provides an ideal situation where provenance and province both are available. Thus, suitable litho-structural locales such as the concealed shear zones sympathetic to the Dalma thrust and South Purulia Shear Zone within the volcano-sedimentary package of Chandil Formation may be targeted as preferable sites for locating concealed uranium mineralization.

Iron-Rich Spherules of Taihu Lake: Origin Hypothesis of Taihu Lake Basin in China

In this paper, a detailed mineralogical study on iron-rich spherules in Taihu Lake was carried out, and we present a proposed impact-related origin for these iron-rich spherules. The iron-rich spherical concretions in Taihu Lake occur in a specific silty layer formed around ~7 ka B.P., sandwiched between an upper lacustrine deposit layer and a lower hard loess layer, and they are widely distributed and are the most abundant iron-rich concretions in that specific layer in the vicinity of Taihu Lake. The spherules are typically ~0.5 to 3 mm in diameter with a shape very similar to a spherical shape but not exactly rounded and have various apparent aerodynamic shapes, such as spherical, cone, spindle, ellipsoidal, elongated and pear-shaped morphologies. SEM imaging shows that there is no central core and no concentric layers in the spherules. Iron-rich spherical concretions are similar to accretionary lapilli and have a typical colloidal structure with abundant angular quartz grains and trace fragments of clays wrapped in fine cements that are mainly goethite with minor clays and carbon particles. The typical nodule-forming mechanism in aqueous sediments does not sufficiently explain the morphology and internal features of the iron-rich spherules of Taihu Lake, whereas the aerosol formation mechanism under the airburst impact origin hypothesis of the Taihu Lake basin may be a better explanation of the unique mineralogy of the spherules. Specifically, airburst impact plumes could be the reaction chambers of the aerosol to form the accretionary lapilli with a colloidal texture for the interior, while a dense shell and semi-plastic morphological features can form in the falling processes from higher altitudes in the plume.

Supplemental Material: Petrographic and chemical studies of the Cretaceous-Paleogene boundary sequence at El Guayal, Tabasco, Mexico: Implications for ejecta plume evolution from the Chicxulub impact crater

Transmitted light and back-scattered electron (BSE) micrographs of silicate melt-coated calcite aggregates and silicate melt particles, high-resolution energy-dispersive spectrometry elemental map, high-resolution BSE mosaic of accretionary lapillus, X-ray fluorescence analyses of bulk rock and accretionary lapilli, electron microprobe analyses of silicate melt particles, and modal composition calculations.

Supplemental Material: Petrographic and chemical studies of the Cretaceous-Paleogene boundary sequence at El Guayal, Tabasco, Mexico: Implications for ejecta plume evolution from the Chicxulub impact crater

Transmitted light and back-scattered electron (BSE) micrographs of silicate melt-coated calcite aggregates and silicate melt particles, high-resolution energy-dispersive spectrometry elemental map, high-resolution BSE mosaic of accretionary lapillus, X-ray fluorescence analyses of bulk rock and accretionary lapilli, electron microprobe analyses of silicate melt particles, and modal composition calculations.

A reworked isolated deposit of the Kos Plateau Tuff and its significance for dating raised marine terraces, Kos, Greece

The 161-ka Kos Plateau Tuff (KPT) eruption deposited widespread unwelded ignimbrites, but the Dikeos and Sympetro mountains on the SE of Kos Island blocked all but the most energetic pyroclastic flows. KPT remnants north of Sympetro mountain comprise reworked tuffite containing pumice and lithic clasts that petrologically and geochemically resemble those found in KPT unit E tephra, and reworked accretionary lapilli similar to those in KPT unit F. Tuffite is found only downslope from a 375-m-high pass between the Dikeos and Sympetro mountains, which was breached at the eruption climax by pyroclastic flows that then accelerated down the 10° north slope of Sympetro. The tuffite crops out in the palaeocliffs of a prominent terrace at an elevation of 75 m, interpreted as the transgressive ravinement surface of the first interglacial marine highstand after the KPT eruption during marine isotope stage (MIS) 5e. A similar ravinement surface cuts KPT deposits in central Kos at elevations of up to 135 m and implies post-MIS 5e uplift rates of 0.7–1.0 m ka−1, confirmed by the elevation of a previously reported raised beach beneath the KPT. A Holocene raised beach on the east coast of Kos contains pumice clasts from the Yali-4 eruption at 4–3 ka. Its elevation of 2 m above sea level is consistent with the elevation of the local MIS 5e terrace. Its present erosion results from the blocking of discharge from ephemeral streams by human infrastructure. Our study provides the first integrated chronologic and neotectonic interpretation of the prominent plateau and terrace surfaces on Kos Island.