Lithofacies and petrochemical characterization of volcano-sedimentary sequence of Chandil Formation around Kharidih-Bareda area, Seraikela-Kharsawan District, Jharkhand: implications for uranium mineralization

Mesoproterozoic Chandil Formation (ca. 1600 Ma) of North Singhbhum Mobile Belt record numerous features of felsic volcaniclastics and felsic to intermediate volcanics preserved in the central sector of the fold belt around Kharidih-Bareda area, Seraikela-Kharsawan district, Jharkhand. The felsic volcanic rocks exhibit flow bands, autoclasts and layering of crystal mushes revealing viscous nature of eruptives. The volcaniclastic sediments comprise of significant proportion of volcanic epiclasts and accidental lithic fragments. These volcaniclastics have been categorized into five prominent lithofacies viz, stratified lapilli tuff, banded tuff, tuff with penecontemporaneous deformation, welded lapilli stones, vitric tuff and volcanic bombs by field and petrographic studies of outcrops and subsurface borehole cores. The welded lapilli tuffs display fiamme and eutaxitic texture. Interlayering of the volcaniclastics, which are most often pyrite-rich, with psamo-pelitic lithology like carbonaceous phyllite, variegated phyllite, quartzite and minor limestone is suggestive of marine euxenic depositional environment. Petrographic study of the volcaniclastics indicated presence of glass shards, garnet phenocrysts, spherules of tremolite, ovoid to lenticular accretionary lapilli along with devitrified glassy material. Compositionally these felsic volcanics and volcaniclastics are rhyodacitic to andesitic in nature with peraluminous to meta aluminous in character. A/CNK values vary from 0.52 to 2.42 in felsic volcanics and from 0.12 to 1.63 in volcaniclastics. Signatures of arc magmatism is indicated by low concentration of HFS elements such as Nb (5-17 ppm), Ga (11-17 ppm) and Y (5-28 ppm). Elevated intrinsic content of uranium (3-8 ppm), Th/U ratio ranging from 1.2 to 13.2, presence of metamict allanite and zircon in volcanics and volcaniclastics reveal their suitability as a prospective source for search of uranium mineralization. The volcanic-volcaniclastic-clastic association of the Chandil Formation provides an ideal situation where provenance and province both are available. Thus, suitable litho-structural locales such as the concealed shear zones sympathetic to the Dalma thrust and South Purulia Shear Zone within the volcano-sedimentary package of Chandil Formation may be targeted as preferable sites for locating concealed uranium mineralization.

Mineral formation conditions in acid magmatic systems related to the formation of massive sulfide deposits of the Urals and Altai-Sayany area

Studies of melt inclusions in quartz indicate the similarity of acid magmatic systems of massive sulfde deposits in the Urals and Altai-Sayany region. The melts of normal alkalinity corresponding to rhyodacite and rhyolite compositions and related to the tholeiitic series are dominant in all the deposits considered. The magmas are characterized by the same type evolution with a decreasing content of main oxides (TiO2, Al2O3, FeO, MgO, CaO, Na2O, K2O) and an increasing SiO2 content. Our results show the accumulation of Cu in relatively low-H2O acidic melts of ancient (Cambrian) deposits of the Altai-Sayany region and low metal contents in the intermediate (Silurian–Devonian) and H2O-saturated magmas of the Urals. The youngest (Devonian) magmas of Siberia evolve simultaneously along these two directions. The analysis of melt inclusions in quartz suggests that the minimum contents of trace and rare earth elements are characteristic of the Silurian-Devonian acid melts of the Urals, with their maximum contents in the youngest (Devonian) magmas and the intermediate contents of ancient (Cambrian) magmatic systems of the Altai-Sayany region. The features of rare and rare earth element patterns in melt inclusions in quartz indicate the similarity of acid magmatic systems of massive sulfde deposits in the Urals and Altai-Sayany region with present-day suprasubduction melts in the ocean-continent transition zones. Computational modeling using data on melt inclusions in quartz confrms our previous conclusions (Simonov, Maslennikov, 2020) that the occurrence of contrasting (basic and felsic) volcanic complexes with massive sulfde deposits in the Urals and Altai-Sayany region is a result of evolution of basaltoid magmas. Keywords: conditions of mineral crystallization, basaltic-rhyolitic complexes, massive sulfde deposits, melt inclusions, quartz, acidic melts.

Petrological Composition of the Last Coal Seam in the Longmendong Section before the End-Permian Mass Extinction

Late Permian coal deposits are widely distributed throughout southwestern China. This paper describes the petrological composition of the last coal seam in the Longmendong section of the Emeishan area during the latest Changhsingian (Permian) and records important information regarding the evolution of the mass extinction event that occurred at the end of the Permian. The results show that the dominant coal maceral group is vitrinite, followed by liptinite and inertinite macerals, and the coal minerals include quartz, chamosite and pyrite. The pyrofusinite and carbon microparticles occurrence modes could have been formed during wildfires in the adjacent areas. The β-tridymite occurrence modes and the high proportions and occurrence modes of magmatic quartz indicate that synchronous felsic volcanic activity occurred during the peat mire accumulation period. The chamosite and quartz occurrence modes suggest that they primarily precipitated from Fe-Mg-rich siliceous solutions that was derived from the weathering of nearby Emeishan basalt. The pyritic coal balls occurrence modes in the C1 coal seam are likely the result of coal-forming plants and Fe-Mg-rich siliceous solutions in neutral to weak alkaline conditions during late syngenetic stages or early epigenetic stages within paleomires.

Textural analysis and emplacement conditions of well-preserved Orosirian felsic volcanic rocks of Northern Amazon Craton, Brazil

Located in the Amazon Craton, the Uatumã magmatism (1.89-1.87 Ga) consists in one of the oldest Silicic Large Igneous Provinces (SLIPs) on Earth. For a long time, the access to these deposits in the northern Amazon Craton (Erepecuru–Trombetas Domain) has been set back for volcanological studies due to dense vegetation cover and the absence of roads. Recent studies identify two Orosirian volcanic units in the region: the Iricoumé Group (1.89-1.87 Ga) related to the Uatumã magmatism, and the Igarapé Paboca Formation (1.99-1.94 Ga), associated to an older magmatism. Both units are widespread in the Erepecuru–Trombetas Domain and include effusive and explosive deposits. In this paper, we apply textural analyses and rheological estimations to determine the eruption and emplacement conditions of these two volcanic sequences. Textural analyses were carried out through fieldwork and petrography, including a systematic classification of lavas and volcaniclastic rocks. Rheological parameters were determined using geochemistry data to obtain melt viscosity (η) and temperature, zircon saturation (TZr), liquidus (TL), and glass transition temperatures (TG), for anhydrous and hydrous compositions. Textural analyses indicate the predominance of volcaniclastic facies with abundant eutaxitic and parataxitic textures. Rheological estimations reveal TL of 1020ºC, TZr 650-905ºC, and TG 640-753ºC for anhydrous Iricoumé Group melts. Eruptive viscosity estimations range from 8.4 to 11.7 log η (Pa.s). Igarapé Paboca melts present higher temperatures, with TL of 1050ºC, TZr 710-880ºC, and TG 670-740 ºC. Modeling using hydrous compositions indicate that minute amounts of water can strongly affect the rheology of the studied melts, reducing η, TL, TZr, and TG. The petrographic features indicative of hydrous magma reinforces the role of H2O as a controlling agent in the fragmentation of Iricoumé and Igarapé Paboca melts. The pyroclastic samples are marked by elevated ∆TZr - TG relationships indicative of high emplacement temperatures above the TG. Our results indicate that the high temperatures and the presence of network-modifier cations in the studied melts favored the development of extensive welded ignimbrites associated with low-eruption columns, likely developed in fissural and/or caldera systems.

Geochemistry and Isotope Composition of Paleoproterozoic Granites and Felsic Volcanics of the Elash Graben: Evidence of the Heterogeneity of the Early Precambrian Crust

—The paper presents results of a petrogeochemical and isotope–geochronological study of the granite–leucogranite association of the Pavlov massif and felsic volcanics from the Elash graben (Biryusa block, southwest of the Siberian craton). A characteristic feature of the granite–leucogranites is their spatial and temporal association with vein aplites and pegmatites of the East Sayan rare-metal province. The U–Pb age of zircon from granites of the Pavlov massif (1852 ± 5 Ma) is close to the age of the pegmatites of the Vishnyakovskoe rare-metal deposit (1838 ± 3 Ma). The predominant biotite porphyritic granites and leucogranites of the Pavlov massif show variable alkali ratios (K2O/Na2O = 1.1–2.3) and ferroan (Fe*) index and a peraluminous composition; they are comparable with S-granites. The studied rhyolites of the Tagul River (SiO2 = 71–76%) show a low ferroan index, a high K2O/Na2O ratio (1.6–4.0), low (La/Yb)n values (4.3–10.5), and a clear Eu minimum (Eu/Eu* = 0.3–0.5); they are similar to highly fractionated I-granites. All coeval late Paleoproterozoic (1.88–1.85 Ga) granites and felsic volcanics of the Elash graben have distinct differences in composition, especially in the ferroan index and HREE contents, owing to variations in the source composition and melting conditions during their formation at postcollisions extension. The wide range of the isotope parameters of granites and felsic volcanic rocks (εNd from +2.0 to –3.7) and zircons (εHf from +3.0 to +0.8, granites of the Toporok massif) indicates the heterogeneity of the crustal basement of the Elash graben, which formed both in the Archean and in the Paleoproterozoic.

Geochemistry and Petrography of the Sediments From the Marginal Areas of Qinghai Lake, Northern Tibet Plateau, China: Implications for Weathering and Provenance

The provenance study of the sediments from Qinghai Lake is of great significance for the understanding of geological and climatic evolution processes of the Tibet Plateau on the one hand and for evaluating the controlling factors of the sediment components on the other hand. The samples were collected from five rivers, foreshore, beach, beach bar, and aeolian sand dune in the Qinghai Lake. The bulk geochemical composition, petrography, and mineralogy features of the samples are analyzed. The results show that: 1) Qinghai Lake sediments experienced low-intensity chemical weathering from the source areas to the deposition sites and were affected by some recycled detrital materials and 2) the source rocks for the sediments include felsic rocks (granite, granodiorite, and felsic volcanic rocks), carbonate, metamorphic rocks (marble and meta-volcanic rocks), and clastic rocks with the felsic source rocks to have the most important impact on the chemical compositions of the sediments. The geochemical indicator of Al2O3/TiO2 reflects that the provenance of fine-grained sediments from the center of Qinghai Lake is more mafic than the coarse-grained sediments from the margin of the Qinghai Lake, suggesting that the hydraulic sorting of grain size probably plays an important role in the geochemical compositions of the sediments. The mafic elements were probably preferentially enriched in muds.

Progressive accretion recorded in sedimentary rocks of the 3.28−3.23 Ga Fig Tree Group, Barberton Greenstone Belt

One of the major challenges in early Earth geology is the interpretation of the nature of the crust and tectonic processes due to the limited exposures of Archean rocks. This question is predominantly addressed by numerical modeling, structural geology, geochemical analyses, and petrological approaches. Here we report on the reconstruction of one of the oldest, well-preserved volcano-sedimentary sequences on Earth, the 3.28−3.22 Ga Fig Tree Group in the Barberton Greenstone Belt, South Africa, based on geochronology, provenance, and stratigraphy to provide new constraints on the nature of tectonic processes in the Archean. The Fig Tree basin was asymmetric and the onset of deposition varied across the greenstone belt. The Fig Tree Group is now preserved in east-west oriented bands of fault-bounded structural belts with those preserved in the southern parts of the greenstone belt showing an onset of deposition at 3.28 Ga, those in the center at 3.26 Ga, and those in the north at 3.24 Ga. Stratigraphically, the rocks display a general up-section trend from deeper to shallower-water deposition and/or from finer- to coarser-grained sedimentary rocks. Associated with this up-section stratigraphic trend, the sedimentary rocks show a change in provenance from more regionally similar to more locally variable, and an increase in felsic volcanic activity, especially toward the closure of Fig Tree deposition. The data is consistent with formation of the Fig Tree Group in a compressional tectonic setting by deposition in a foreland basin that experienced progressive accretion of crustal terranes onto a northward prograding fold-and-thrust belt.