Raman random lasing in Ba(NO3)2 powder

Random lasing in Raman active material – barium nitrate powder – has been registered in two temporal regimes: nanosecond and picosecond. Stimulated Raman scattering (SRS) in Ba(NO3)2 for picosecond excitation has been shown to have much lower threshold and spectrum containing more components than for nanosecond excitation opposite to the case of a bulk medium. In picosecond regime SRS intensity increased with temperature decreasing and redistributed in favor of the higher order components. SRS pulse duration in picosecond regime was estimated to be in the range 16.5-22 ps. High conversion efficiency of SRS in barium nitrate powder in picosecond regime and its larger stability under laser impact than for bulk samples gives possibility to use it as an active material in Raman converters.

Long-living nonlinear behavior in CsPbBr3 carrier recombination dynamics

By means of time-resolved photoluminescence (TR-PL) spectroscopy, we present a detailed investigation of the carrier relaxation dynamics in a CsPbBr3 bulk sample and microcrystal ensemble at cryogenic temperature on a picosecond time scale. We provide evidence of a long temperature-dependent cooling rate for the excitons and free carriers population, with an initial cooling time constant of a few tens of picoseconds. A relaxation bottleneck in the thermalization process was found that cannot be explained by the Auger effect or hot phonon population, since we address a very low excitation regime, not commonly investigated in literature, where such processes are not effective. Adding a continuous wave optical bias to the picosecond excitation, we probed the photoinduced PL decrease of the localized states and the photoinduced PL increase of the population in the high energy states. A long recovery time from the photoinduced PL decrease was found for localized states and quite significant differences were detected, depending on the resonance/off resonance bias used in the experiment.