ДОЦІЛЬНІСТЬ ЗАСТОСУВАННЯ СТЕРИЧНО УСКЛАДНЕНИХ АЦЕНАФТЕНОВИХ СПОЛУК У СКЛАДІ ПРОТИКОРОЗІЙНОЇ КОМПОЗИЦІЇ

Goal. Synthesis and study of the effect of the inhibitory component – sterically complicated acenaphthene compounds – on the effectiveness of the protective composition to prevent corrosion of metal products during the period of temporary preservation.Method. Coke-chemical acenaphthylene was isolated from the absorbing and anthracene fractions of coal tar, the bromination of which led to 1,2-dibromocenaphthene. Subsequent alkylation of azine bases with 1,2-dibromacenaphthene yielded a number of sterically complex acenaphthene compounds. In the conditions of simulation aggressiveness of NSS environment the influence of synthesized additives on efficiency of anticorrosive composition is investigated (ISO 9227:2017). Research methods: chromatography, synthesis, elemental analysis, IR spectroscopy, corrosion tests.Results. On the basis of low-demand, available and inexpensive components of coke production, a number of substances with high anti-corrosion properties were synthesized – Quaternary azine salts with acenaphthene fragment. It was determined that the greatest resistance to the destructive effects of corrosive NSS environment according to the results of accelerated atmospheric corrosion tests was demonstrated by a composite coating containing an inhibitory additive – 1-(2-bromo-1,2-dihydroacenaphthylen-1-yl) quinoline bromide. The dominant role of the structure of the inhibitory additive on the manifestation of anticorrosive properties of the protective composition is shown. The influence of the ratio of components of paints and varnishes on their technological and anti-corrosion properties has been studied. The obtained results allow to create a new formulation of the domestic competitive protective composition to prevent corrosion of the metal for the period of temporary preservation.Scientific novelty. The role of 1,2-dibromacenaphthene as a promising alkylating agent in the synthesis of inhibitory additives - sterically complicated acenaphthene compounds has been determined.Practical significance. The optimal content of inhibitory components – Quaternary azine salts with acenaphthene fragment – for the development of a formulation of an effective anti-corrosion composition for the period of temporary preservation of metal products.

Forecasting of industrial coke quality at JSC EVRAZ NTMK based on data of passive industrial experiment. Report 1. Forecasting of CSR and CRI of industrial coke

A forecast of coke quality takes a special place in the coke production, since it enables to increase efficiency of management of batching process of various by composition and properties coals and production of coke of stably high and required quality with minimal costs. Description of a methodological approach to processing of passive industrial experiment data of blends coking at Coke production department of JSC EVRAZ NTMK presented by application selective (general) matrix. The matrix accounts various multilevel values of influence factor CSR and CRI of coke - a complex index of coking ability of blends K.п.к.Vo. It was shown that the proposed approach provides wide variations of response function (CSR/CRI) at symmetrical enough matrix, excluding predominance of any particular area of values of indices K.п.к.Vo and CSR/CRI. By applying the passive industrial experiment, based on processing of actual report data of industrial blends coking at the coke batteries No. 5-6 (wet quenching) and No. 9-10 (dry quenching) by selective matrix, mathematical models of forecast of quality of industrial coke by wet and dry quenching (CSR/CRI) were elaborated depending on coal charges properties (K.п.к.Vo) at the existing modes of their preparation and coking at the coke batteries No. 5-6 and 9-10. Verification of accuracy of the mathematical models of coke quality forecast at wet and dry quenching (CSR/CRI) processing a large actual material of industrial coking (62 coking operations in the coke batteries No. 5-6 and 58 coking operations in the coke batteries No. 9-10 showed accuracy good enough for practical application of forecasting indices CSR and CRI of industrial coke of wet and dry quenching.

Research and Application of a Novel Nonlinear Grey Bernoulli Simpson Model for Short-Term Coke Production Forecasting

Aims: As a basic energy source, coal occupies a leading position in the production and consumption of energy. If a reasonable coal energy production policy is to be formulated, effective forecasting is essential. Due to the lack of data, effective prediction with small samples has become the key to research. Study Design: A nonlinear grey Bernoulli Simpson model based on new information priority accumulation method is developed in this work to forecast the coke production in the Anhui China. The introduction of non-linear parameters makes the new model constructed with universality Place and Duration of Study: School of Science, Southwest University of Science and Technology, Mianyang, between April 2021 and June 2021. Methodology: This paper has established the nonlinear grey Bernoulli Simpson model with new information priority accumulation. Based on the grid search optimization, the data is divided by the leave-out method to construct a nonlinear problem to solve the nonlinear parameters of the model. Finally, the new model established was applied to the forecast of coke production in Anhui Province, China. Results: The MAPE and RMSPE of the nonlinear grey Bernoulli Simpson model based on new information priority accumulation method are 1.86% and 2.58%, which are lower than other comparative models. Conclusion: The application research of coke production shows that the new model proposed in this paper has the advantage of high prediction accuracy, which indicates that this method has great potential in the short-term prediction of energy production.

Stamp-Charged Coke-Making Technology—The Effect of Charge Density and the Addition of Semi-Soft Coals on the Structural, Textural and Quality Parameters of Coke

Coke is an integral component of the blast furnace charge; therefore, it plays an important role in the integrated steelmaking process. Achieving the required coke quality parameters by producers requires the use of a high proportion of the highest quality coking coals (hard coking coals) in the coking blends, which significantly increases the unit production costs. Approximately 75% of these costs are constituted by the cost of the coal blend’s preparation. There is a deficit in the best quality coking coals on the world market and their supply are characterized by large fluctuations in quality parameters. Therefore, from the point of view of the economics of coke production, it is advantageous to produce high-quality coke from a coke blend with the highest possible content of cheaper coals. The paper presents the results of the influence of coal charge bulk density and semi-soft coking coal content in the coking blend on the textural and structural parameters of coke, which determine its quality. Research has shown that the application of increased density influences the parameters of the texture and structure of the coke, which shape its quality parameters. The use of stamp-charging technology contributes to the improvement of the coke quality or enables the production of coke of a predetermined quality from blends containing cheaper semi-soft coals.

Analysis of the Influence of Biomass Addition in Coal Mixture for Metallurgical Coke Production

Metallurgical coke is a common material used for hot metal production in blast furnaces. In addition to the fuel function, it has a physical assignment, supporting the load inside the reactor, and chemical, supplying carbon to hot metal. However, due to growing discourse on environmental issues, the production of hot metal via coke blast furnace has been in evidence. This process is responsible for about 70% of CO2 emissions in steelmaking. On the other hand, biomasses are materials that are available in different ways in nature and considered neutral in CO2 emissions since they absorb this gas and release oxygen in the photosynthesis process. Thus, a viable alternative in the short term is the partial replacement of the coal used in coke production with biomass, which would generate environmental gains, and guarantee the sustainable production. Therefore, this work aims to show several published researches using biomass in coke production. The effects that biomass has on the properties of coke will be emphasized, and at the end, an environmental analysis will be shown with the possible use of biomass. It will be possible to see that it is possible to substitute between 2 and 10% of the coal for biomass, producing coke with the characteristics required in the blast furnace.

Sulfide Technology Based on Sulfur Waste Product of Coke Production

A technology has been developed for the processing recycling of waste - sulfuric cake into building materials with high physical and mechanical characteristics. Sulfur activator (zinc chloride) contributed to the chemical bonding of the components.