Strong violet emission from ultra-stable strontium-doped CsPbCl3 superlattices

Among the lead halide perovskites, photoluminescence quantum yields (PLQYs) of perovskite quantum dots (PQDs) in the violet are very lowest. This is an obstacle to the optical application of the...

A 35-million-year record of seawater stable Sr isotopes reveals a fluctuating global carbon cycle

Changes in the concentration and isotopic composition of the major constituents in seawater reflect changes in their sources and sinks. Because many of the processes controlling these sources and sinks are tied to the cycling of carbon, such records can provide insights into what drives past changes in atmospheric carbon dioxide and climate. Here, we present a stable strontium (Sr) isotope record derived from pelagic marine barite. Our δ88/86Sr record exhibits a complex pattern, first declining between 35 and 15 million years ago (Ma), then increasing from 15 to 5 Ma, before declining again from ~5 Ma to the present. Numerical modeling reveals that the associated fluctuations in seawater Sr concentrations are about ±25% relative to present-day seawater. We interpret the δ88/86Sr data as reflecting changes in the mineralogy and burial location of biogenic carbonates.

Stable Strontium Isotopic Compositions of River Water, Groundwater and Sediments From the Ganges–Brahmaputra–Meghna River System in Bangladesh

The Sr isotopic composition of rivers and groundwaters in the Bengal Plain is a major contributor to the global oceanic Sr inventory. The stable strontium isotope ratios (δ88Sr) provide a new tool to identify chemical weathering reactions in terrestrial water. In this study, we investigated the spatiotemporal variations of δ88Sr in samples of river water, bedload sediment, and groundwater collected from the Ganges–Brahmaputra–Meghna drainage basin in Bangladesh, which is known to strongly influence the 87Sr/86Sr ratio in seawater. The average δ88Sr values of waters of the Ganges, Brahmaputra, and Meghna rivers were 0.269, 0.316, and 0.278‰, respectively. Our data showed little difference between seasons of high and low discharge. The δ88Sr values measured in sequential leaching fractions of sediments varied from –0.258 to 0.516‰ and were highest in the silicate fraction, followed in turn by the carbonate fraction and the exchangeable fraction. Both 87Sr/86Sr and δ88Sr of these waters are primarily controlled by the inputs of Sr in weathering products from the Bengal Plain and Sr from the Himalayan rivers (Ganges and Brahmaputra). Values of δ88Sr and Sr/Ca were higher in the Brahmaputra River than in the Ganges River, a difference we attribute to greater input from silicate weathering. The variations of δ88Sr and 87Sr/86Sr were greater in groundwater than in river waters. Mineral sorting effects and dissolution kinetics can account for the large scatter in 87Sr/86Sr and δ88Sr values. The depth profile of δ88Sr showed wide variation at shallow depths and convergence to a narrow range of about 0.31‰ at depths greater than 70 m, which reflects more complete equilibration of chemical interactions between groundwater and ambient sediments owing to the longer residence time of deeper groundwater. We found that δ88Sr values in the groundwater of Bangladesh were almost identical to those of river water from the lower Meghna River downstream of its confluence with the Ganges–Brahmaputra river system, thus confirming that the δ88Sr composition of the groundwater discharge to the Bay of Bengal is very similar to that of the river discharge.